专利摘要:
COMPOSITIONS, USE OF A COMPOSITION, METHOD FOR COMBATING PHYTOPATHOGENIC FUNGI AND USE OF COMPONENTS. The present invention relates to compositions that comprise a triazole compound and a biopesticide.
公开号:BR112016000299B1
申请号:R112016000299-7
申请日:2014-06-25
公开日:2021-02-17
发明作者:Frederik Menges;Martin Semar;Nadine Riediger;Lutz Brahm;Kristin KLAPPACH;Murat Mertoglu;Winfried Mayer;Egon Haden;Jan Klaas Lohmann;Nadege Boudet;Annette Schuster
申请人:BASF Agro B.V.;
IPC主号:
专利说明:

[0001] - composto I.1: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1- il)pent-3-in-2-ol; - composto I.2: 1-[2-cloro-4-(4-clorofenoxi)fenil]-1-ciclopropil-2- (1,2,4-triazol-1-il)etanol; - composto I.3: 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4- triazol-1-il)propan-2-ol; - composto I.4: 1-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1- ciclopropil-2-(1,2,4-triazol-1-il)etanol; - composto I.5: 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-3-metil-1- (1,2,4-triazol-1-il)butan-2-ol; - composto I.6: 1-[2-[2-cloro-4-(4-clorofenoxi)fenil]-2-metoxi-pent3-inil]-1,2,4-triazol; - composto I.7: 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4- triazol-1-il)butan-2-ol; - composto I.8: 1-[2-[2-cloro-4-(4-clorofenoxi)fenil]-2-ciclopropil-2- metoxi-etil]-1,2,4-triazol; - composto I.9: 1-[2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-2- metoxi-propil]-1,2,4-triazol; - composto I.10: 2-[2-cloro-4-(4-clorofenoxi)fenil]-3,3-dimetil-1-(1- il-1,2,4-triazol)butan-2-ol, - composto I.11: 1-[2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-2-ciclopropil-2-metoxi-etil]-1,2,4-triazol; - composto I.12: 1-[2-[2-cloro-4-(4-clorofenoxi)fenil]-2-metoxi-3,3- dimetil-butil]-1,2,4-triazol; - composto I.13: 1-[2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-2- metoxi-butil] 1,2,4-triazol; - composto I.14: 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4- triazol-1-il)pent-3-in-2-ol; - composto I.15: 1-[2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-2- metoxi-pent-3-inil]-1,2,4-triazol; - composto I.16: 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4- triazol-1-il) but-3-in-2-ol; - composto I.17: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1- il)propan-2-ol; e - composto I.18: 2-[2-cloro-4-(4-fluorofenoxi)fenil]-1-(1,2,4-triazol1-il)propan-2-ol. - composto I.19: 2-[2-cloro-4-(4-clorofenoxi)fenil]-3-metil-1-(1,2,4- triazol-1-il)butan-2-ol; - composto I.20: 1-[2-[2-cloro-4-(4-clorofenoxi)fenil]-2-metoxipropil]-1,2,4-triazol; - composto I.21: 1-[2-[2-cloro-4-(4-clorofenoxi)fenil]-2-metoxi-butil]- 1,2,4-riazol; - composto I.22: 1-[2-[2-cloro-4-(4-clorofenoxi)fenil]-2-metoxipentil]-1,2,4-triazol; - composto I.23: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1,1,1-trifluoro-3- (1,2,4-triazol-1-il)propan-2-ol; - composto I.24: cloridrato de 2-[2-cloro-4-(4-clorofenoxi)fenil]-3- fluoro-1-(1,2,4-triazol-1-il)butan-2-ol; - composto I.25: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1-il)pent-4-in-2-ol; - composto I.26: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-metoxi-3- (1,2,4-triazol-1-il)propan-2-ol; - composto I.27: 2-[2-cloro-4-(4-fluorofenoxi)fenil]-1-metoxi-3- (1,2,4-triazol-1-il)propan-2-ol; - composto I.28: 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4- triazol-1-il)pentan-2-ol; - composto I.29: 2-[4-(4-fluorofenoxi)-2-(trifluorometil)fenil]-1- (1,2,4-triazol-1-il)propan-2-ol; - composto I.30: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1- il)butan-2-ol; e - composto I.31: 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1- il)pentan-2-ol. - e (2) como componente II, um biopesticida selecionado a partir dos grupos de (L1) a (L6):(L1) Pesticidas microbianos com atividade fungicida, bactericida, viricida e/ou ativadora de defesa do vegetal: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriófagos), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, Clonostachys rosea f. catenulate (também denominada Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa, Pantoea vagans, Penicillium bilaiae, Phlebiopsis gigantea, Pseudomonas sp., Pseudomonas chloraphis, Pseudozyma flocculosa, Pichia anomala, Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. atroviride, T. fertile, T. gamsii, T. harmatum, T. harzianum, T. polysporum, T. stromaticum, T. virens, T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, vírus da abobrinha do mosaico amarelo (cepa não virulenta);(L2) Pesticidas bioquímicos com atividade fungicida, bactericida, viricida e/ou ativadora de defesa do vegetal: quitosana (hidrólise), proteína harpina, laminarina, óleo de peixe Menhaden, natamicina, proteína revestida do vírus Plum pox, bicarbonato de potássio ou de sódio, extrato de Reynoutria sachalinensis, ácido salicílico, óleo da árvore do chá;(L3) Pesticidas microbianos com atividade inseticida, acaricida, moluscidal e/ou nematicida: Agrobacterium radiobacter, Bacillus cereus, B. firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bassiana, B. brongniartii, Burkholderia spp., Chromobacterium subtsugae, Cydia pomonella granulovirus (CpGV), Cryptophlebia leucotreta granulovirus (CrleGV), Flavobacterium spp., nucleopolihedrovírus Helicoverpa armigera (HearNPV), Heterorhabditis bacteriophora, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium, Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. penetrans, P. ramosa, P. thornea, P. usgae, Pseudomonas fluorescens, nucleopolihedrovírus Spodoptera littoralis (SpliNPV), Steinernema carpocapsae, S. feltiae, S. kraussei, Streptomyces galbus, S. microflavus;(L4) Pesticidas bioquímicos com atividade inseticida, acaricida, moluscidal, feromona e/ou nematicida: L-carvona, citral, acetato (E,Z)-7,9 dodecadien-1-il, formato de etila, decadienoato (E,Z)-2,4-etila (éster pêra), (Z,Z,E)-7,11,13-hexadecatrienal, butirato de heptila, miristato de isopropila, cisjasmona, senecioato de lavanulil, 2-metil-1-butanol, eugenol de metila, jasmonato de metila, (E,Z)-2,13-octadecadien-1-ol, acetado de (E,Z)-2,13- octadecadien-1-ol, (E,Z)-3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanona, silicato de potássio, actanoato de sorbitol, acetato de (E,Z,Z)- 3,8,11-tetradecatrienila, acetato de (Z,E)-9,12-tetradecadien-1-il, Z-7- tetradecen-2-ona, acetato de Z-9-tetradecen-1-il, Z-11-tetradecenal, Z-11- tetradecen-1-ol, extrato de acácia negra, extrato de sementes de toranja e celulose, extrato de Chenopodium ambrosiodes, óleo catnip, óleo de Neem, extrato Quillay, óleo Tagetes;(L5) Pesticidas microbianos com a atividade de redução da tensão do vegetal, reguladora de crescimento, promotora do crescimento e/ou de intensificação do rendimento vegetal: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium spp, B. elkanii, B. japonicum, B. liaoningense, B. Lupini, Delftia acidovorans, Glomus intraradices, Mesorhizo-bium spp., Rhizobium leguminosarum bv. phaseoli, R. l. bv. trifolii, R. l. bv. viciae, R. tropici, Sinorhizobium meliloti;(L6) Pesticidas bioquímicos com a atividade de redução da tensão do vegetal, reguladora de crescimento e/ou de intensificação do rendimento: ácido abscísico, silicato de alumínio (caulino), 3-decen-2-ona, formononetina, genisteína, hesperetina, homobrassinolídeo, humates, ácido jasmônico e seus sais ou seus derivados, etanolamina de lisofosfatidila, naringenina, ácido poliidróxi polimérico, extrato de Ascophyllum nodosum (alga marinha norueguesa, alga marinha marrom) e extrato de Ecklonia maxima (alga).[001] The present invention relates to compositions that comprise, (1) as component I a compound selected from: - compound I.1: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pent-3-in-2-ol; - compound I.2: 1- [2-chloro-4- (4-chlorophenoxy) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol; - compound I.3: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; - compound I.4: 1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol; - compound I.5: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol; - compound I.6: 1- [2- [2-chloro-4- (4-chlorophenoxy) phenyl] -2-methoxy-pent3-ynyl] -1,2,4-triazole; - compound I.7: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol; - compound I.8: 1- [2- [2-chloro-4- (4-chlorophenoxy) phenyl] -2-cyclopropyl-2-methoxy-ethyl] -1,2,4-triazole; - compound I.9: 1- [2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -2-methoxy-propyl] -1,2,4-triazole; - compound I.10: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3,3-dimethyl-1- (1-yl-1,2,4-triazole) butan-2-ol, - compound I.11: 1- [2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -2-cyclopropyl-2-methoxy-ethyl] -1,2,4-triazole; - compound I.12: 1- [2- [2-chloro-4- (4-chlorophenoxy) phenyl] -2-methoxy-3,3-dimethyl-butyl] -1,2,4-triazole; - compound I.13: 1- [2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -2-methoxy-butyl] 1,2,4-triazole; - compound I.14: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pent-3-in-2-ol; - compound I.15: 1- [2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -2-methoxy-pent-3-ynyl] -1,2,4-triazole; - compound I.16: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) but-3-in-2-ol; - compound I.17: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; and - compound I.18: 2- [2-chloro-4- (4-fluorophenoxy) phenyl] -1- (1,2,4-triazol1-yl) propan-2-ol. - compound I.19: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol; - compound I.20: 1- [2- [2-chloro-4- (4-chlorophenoxy) phenyl] -2-methoxypropyl] -1,2,4-triazole; - compound I.21: 1- [2- [2-chloro-4- (4-chlorophenoxy) phenyl] -2-methoxy-butyl] - 1,2,4-riazole; - compound I.22: 1- [2- [2-chloro-4- (4-chlorophenoxy) phenyl] -2-methoxypentyl] -1,2,4-triazole; - compound I.23: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1,1,1-trifluoro-3- (1,2,4-triazol-1-yl) propan-2- ol; - compound I.24: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-fluoro-1- (1,2,4-triazol-1-yl) butan-2-ol hydrochloride; - compound I.25: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pent-4-in-2-ol; - compound I.26: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1-methoxy-3- (1,2,4-triazol-1-yl) propan-2-ol; - compound I.27: 2- [2-chloro-4- (4-fluorophenoxy) phenyl] -1-methoxy-3- (1,2,4-triazol-1-yl) propan-2-ol; - compound I.28: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pentan-2-ol; - compound I.29: 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol; - compound I.30: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol; and - compound I.31: 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) pentan-2-ol. - and (2) as component II, a biopesticide selected from the groups (L1) to (L6): (L1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus altitudinis, B. amyloliquefaciens, B. megaterium, B. mojavensis, B. mycoides, B pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Dilophosphora alopecuri, Fusarium oxysporum, Clonostachys rosea f. catenulate (also known as Gliocladium catenulatum), Gliocladium roseum, Lysobacter antibioticus, L. enzymogenes, Metschnikowia fructicola, Microdochium dimerum, Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyia, Peninsula, Pmyea, Pantoea, Panto. chloraphis, Pseudozyma flocculosa, Pichia anomala, Pythium oligandrum, Sphaerodes mycoparasitica, Streptomyces griseoviridis, S. lydicus, S. violaceusniger, Talaromyces flavus, Trichoderma asperellum, T. haroviride, T. fertilemat T. T. gum , T. polysporum, T. stromaticum, T. virens, T. viride, Typhula phacorrhiza, Ulocladium oudemansii, Verticillium dahlia, yellow mosaic zucchini virus (non-virulent strain); (L2) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or vegetable defense activating activity: chitosan (hydrolysis), harpine protein, laminarin, Menhaden fish oil, natamycin, Plum pox virus coated protein, potassium or bicarbonate sodium, Reynoutria sachalinensis extract, salicylic acid, tea tree oil; (L3) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity: Agrobacterium radiobacter, Bacillus cereus, B. firmus, B. thuringiensis, B. thuringiensis ssp. aizawai, B. t. ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, B. t. ssp. tenebrionis, Beauveria bassiana, B. brongniartii, Burkholderia spp., Chromobacterium subtsugae, Cydia pomonella granulovirus (CpGV), Cryptophlebia leucotreta granulovirus (CrleGV), Flavobacterium spp. L. muscarium, Metarhizium anisopliae, Metarhizium anisopliae var. anisopliae, M. anisopliae var. acridum, Nomuraea rileyi, Paecilomyces lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. penetrans, P. ramosa, P. thornea, P. usgae, Pseudomonas fluorescens, nucleopolihedrovirus Spodoptera littoralis (SpliNPV, Ste. feltiae, S. kraussei, Streptomyces galbus, S. microflavus; (L4) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity: L-carvone, citral, acetate (E, Z) -7.9 dodecadien-1-yl, ethyl format, decadienoate (E, Z ) -2,4-ethyl (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, cisjasmone, lavanulil senecioate, 2-methyl-1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, acetate (E, Z) -2,13-octadecadien-1-ol, (E, Z) -3, 13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) - 3,8,11-tetradecatrienyl acetate, (Z , E) -9,12-tetradecadien-1-yl, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11- tetradecen-1- ol, black wattle extract, grapefruit and cellulose seed extract, Chenopodium ambrosiodes extract, catnip oil, Neem oil, Quillay extract, Tagetes oil; (L5) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting growth and / or intensifying plant yield: Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium spp, B. elkanii, B. japonicum, B. liaoningense, B. Lupini, Delftia acidovorans, Glomus intraradices, Mesorhizo-bium spp., Rhizobium leguminosarum bv. phaseoli, R. l. bv. trifolii, R. l. bv. viciae, R. tropici, Sinorhizobium meliloti; (L6) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or enhancing yield: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, formononetine, genistein, hesperetin, homobrassinolide, humates, jasmonic acid and its salts or derivatives, lysophosphatidyl ethanolamine, naringenin, polymeric polyhydroxy acid, Ascophyllum nodosum extract (Norwegian kelp, brown kelp) and Ecklonia maxima extract (alga).
[0002] [002] In particular, from (L1) to (L6) are defined as follows from (L1.1) to L.6.1)): (L1.1) Microbial pesticides with: Ampelomyces quisqualis, Aspergillus flavus, Aureobasidium pullulans, Bacillus amyloliquefaciens, B. mojavensis, B. pumilus, B. simplex, B. solisalsi, B. subtilis, B. subtilis var. amyloliquefaciens, Candida oleophila, C. saitoana, Clavibacter michiganensis (bacteriophages), Coniothyrium minitans, Cryphonectria parasitica, Cryptococcus albidus, Fusarium oxysporum, Clonostachys rosea f. catenulate (also known as Gliocladium catenulatum), Gliocladium roseum, Metschnikowia fructicola, Microdochium dimerum, Paenibacillus polymyxa, Pantoea agglomerans, Phlebiopsis gigantea, Pseudozyma flocculosa, Pythium oligandor, Sphaerodesycic, Mythic, Mythic ., T. fertil, T. gamsii, T. harmatum; composition of T. viride and T. harziaem one; composition of T. harzianum and T. polysporum; T. stromaticum, T. virens (also called Gliocladium virens), T. viride, Typhula phacorrhiza, Ulocladium oudema, U. oudemansii, Verticillium dahlia, yellow mosaic zucchini virus (non-virulent strain); (L2.1) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity: chitosan (hydrolysis), jasmonic acid or salts or their derivatives, laminarin, Menhaden fish oil, natamycin, Plum virus coated protein , Reynoutria sachlinensis extract, salicylic acid, tea tree oil; (L3.1) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity: Bacillus firmus, B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana, Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulose virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (formerly Verticillium lecanii), Metarhizium anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus poppiliae, Pasteuria spp, P. nishizawae, P. reneformis, P. usagae, Pseudomonas fluorescens, Steinernema feltiae, Streptomces galbus .; (L4.1) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity: L-carvone, citral, acetate (E, Z) -7,9-dodecadien-1-yl, ethyl format, (E, Z) -2,4-ethyl (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulil senecioate, 2-methyl-1- butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, acetate (E, Z) -2,13 octadecadien-1-ol, (E, Z) -3, 13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) actanoate -3,8,11-tetradecatrienyl, (Z , E) -9,12-tetradecadien-1-yl, Z-7-tetradecen-2-one, Z9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11-tetradecen-1-ol, Black wattle extract, grapefruit and cellulose seed extract, Chenopodium ambrosiodae extract, catnip oil, Neem oil, Quillay extract, Tagetes oil; (L5.1) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting plant growth and / or enhancing yield: Azospirillum amazonense A. brasilense, A. lipoferum, A. irakense, A. halopraeferens , Bradyrhizobium sp, B. japonicum, Glomus intraradices, Mesorhizobium sp., Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseolii, R. l. trifolii, R. l. bv. viciae, Sinorhizobium meliloti; (L6.1) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or enhancing yield: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, homobrassinlide, humumes, ethanolamine of lysophosphatidyl, polymeric polyhydroxy acid, extract of Ascophyllum nodosum (Norwegian kelp, brown kelp) and Ecklonia maxima extract (alga).
[0003] [003] The present invention also relates to the use of the compositions of the present invention for the control of phytopathogenic fungi, as detailed in the present, and preparations or compositions that comprise them. In addition, the present invention also relates to seeds that comprise the compositions. In addition, the present invention also relates to methods for the control of phytopathogenic fungi, as detailed herein, in which the fungi or the materials, vegetables, soil or seeds to be protected from fungal attack are treated with an effective amount of a composition according to the present invention. In addition, the present invention also relates to processes for preparing the compositions according to the present invention.
[0004] [004] Practical agricultural experience has shown that repeated and exclusive application of an individual active substance in the control of harmful fungi, in many cases, leads to a rapid selection of those strains of fungi that have developed natural or adapted resistance against the active compound in question. The effective control of these fungi with the active compound in question, therefore, is no longer possible.
[0005] [005] To reduce the risk of selection of resistant fungal strains, mixtures of different active components are conventionally used today to combat harmful fungi. Through the combination of active compounds that have different mechanisms of action, it is possible to ensure successful control over a relatively long period of time. BRIEF DESCRIPTION OF THE INVENTION
[0006] [006] It is an object of the present invention to provide, in order to effectively manage the resistance and the effective control of harmful phytopathogenic fungi, with application rates that are as low as possible, the compositions that, in a total amount reduced number of active compounds applied, applied, improved the activity against harmful fungi (synergistic compositions) and a broader spectrum of activity, especially for certain indications.
[0007] [007] Consequently it was discovered that this object is achieved by the compositions, defined in the present, which comprise a compound I and a compound II. In addition, it was discovered that simultaneously, that is, together or separately, the application of a compound I and a compound I or a successive application of a compound I and a compound II enables better control of harmful fungi than it is possible with the individual compounds alone (synergistic compositions).
[0008] [008] In accordance with the present invention, the compositions may comprise, in addition to a compound I and a biopesticide II, as component III, an additional active compound. The compositions of the present invention may, in the form of use as fungicides, also be present together with other active substances, for example, with herbicides, insecticides, growth regulators, fungicides or also with fertilizers, as a premix or, if appropriate, not until immediately before use (tank mix).
[0009] [009] Consequently, the compositions and uses defined at the beginning and in the following description were discovered. In particular, the present invention relates to compositions comprising component I and component II and compositions comprising component I, component II and compositions comprising component I, component II and component III, wherein the component III is selected from other active substances, for example, with herbicides, insecticides, growth regulators, fungicides or also with fertilizers. In addition to the mentioned components I, II and III, the compositions according to the present invention can also comprise other components (for example, component IV or components IV and V).
[0010] [010] In the compositions of the present invention, compounds I and / or the other active compounds comprised in the respective composition may be present in different crystalline modifications, which may differ in biological activity.
[0011] [011] Compounds I can be obtained through several routes, in analogy with the known prior art processes (cf. J.Agric Food Chem (2009) 57, 4,854-4,860; EP patents 0,275,955 A1; DE 4,003. 180 A1, EP 0.113.640 A2, EP 0.126.430 A2) US 4,940,720; EP 354,183 A2). In addition, compounds of Formula I or similar compounds from the class of triazole, their preparation and use in crop protection are described in publications WO 2013/024076, WO 2013/024075, WO 2013/024077, WO 2013/024080 , WO 2013/024083, WO 2013/007767 and WO 2013/010862 which also describe certain compositions with other active compounds. Some of the compounds of Formula I are described in J. Agric. Food Chem. (2009) 57, 4854-4860, and in EP patents 0.126.430 A2, US 4,940,720; EP 354,183 A2 and EP 0.113.640 A2 OF 4,003.80 A1.
[0012] [012] Due to the basic character of its nitrogen atoms, component I, that is, in particular, compounds I-1, I-2, I-3, I-4, I-5, I-6, I -7 I-8, I-9, I-10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21, I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and I-31 or any group of the compounds I detailed in the present, it is capable of forming salts or adducts with inorganic or organic acids or with metal ions, in particular, salts with inorganic acids.
[0013] [013] Examples of inorganic acids are hydrogenated acids, such as hydrogen fluoride, hydrogen chloride, hydrogen bromide and hydrogen iodide, carbonic acid, sulfuric acid, phosphoric acid and nitric acid.
[0014] [014] Suitable organic acids, for example, are formic acid and alkanoic acids, such as acetic acid, trifluoroacetic acid, trichloroacetic acid and propionic acid, as well as glycolic acid, thiocyanic acid, lactic acid, succinic acid, citric acid, benzoic acid and other arylcarboxylic acids, cinnamic acid, oxalic acid, alkylsulfonic acids (sulfonic acids with a linear chain or branched alkyl radicals with 1 to 20 carbon atoms), arylsulfonic acids or arildisulfonic acids (aromatic radicals, such as phenyl and naphthyl, that carry one or two groups of sulfonic acid), alkylphosphonic acids (phosphonic acids that have a linear chain or branched alkyl radicals with 1 to 20 carbon atoms), arylphosphonic acids or aryldiphosphonic acids (aromatic radicals, such as phenyl and naphthyl, which carry one or two phosphoric acid radicals), where the alkyl or aryl radicals can carry other substituents, for example, p-toluenesulfonic acid, salicylic acid, p-aminosalicylic acid, 2-phenoxybenzoic acid, 2-acetoxybenzoic acid, and the like. Suitable metal ions, in particular, are the ions of the elements of the second main group, in particular calcium and magnesium, of the third and fourth main group, in particular aluminum, tin and lead, and also the elements of the groups of transition from 1 to 8, in particular, chromium, manganese, iron, cobalt, nickel, copper, zinc, and others. Special preference is given to the metal ions of the elements of the transition groups of the fourth period. Metals can be present in the different valences they can assume.
[0015] [015] Components I comprise the chiral centers and which, in general, are obtained in the form of racemates. The R and S enantiomers of the compounds according to the present invention can be separated and isolated in pure form with the methods known to the person skilled in the art, for example, using chiral HPLC. Suitable for use as antimicrobial agents are enantiomers and their compositions. This correspondingly applies to the compositions. In addition, the components that may be present in different crystalline modifications, which may differ in biological activity.
[0016] [016] In particular, in each case, a racemic composition is present. In addition, any other proportions of the (R) and (S) -enantiomer enantiomer may be present, according to the present invention. This applies to all the compositions detailed at present.
[0017] [017] In accordance with an embodiment of the present invention, component I is compound I-1. The compound I-1 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-1.
[0018] [018] According to a specific embodiment, compound I-1 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0019] [019] According to an even more specific embodiment, compound I-1 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0020] [020] According to another embodiment of the present invention, component I is compound I-2. The compound I-2 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-2.
[0021] [021] According to a specific embodiment, compound I-2 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0022] [022] According to an even more specific embodiment, compound I-2 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0023] [023] According to yet another embodiment of the present invention, component I is compound I-3. The compound I-3 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-3.
[0024] [024] According to a specific embodiment, compound I-3 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0025] [025] According to an even more specific embodiment, compound I-3 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0026] [026] According to yet another embodiment of the present invention, component I is compound I-4. The compound I-4 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-4.
[0027] [027] According to a specific embodiment, compound I-4 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0028] [028] According to an even more specific embodiment, compound I-4 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0029] [029] According to yet another embodiment of the present invention, component I is compound I-5. The compound I-5 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-5.
[0030] [030] According to a specific embodiment, compound I-5 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0031] [031] According to an even more specific embodiment, compound I-5 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0032] [032] According to yet another embodiment of the present invention, component I is compound I-6. The compound I-6 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-6.
[0033] [033] According to a specific embodiment, compound I-6 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0034] [034] According to an even more specific embodiment, compound I-6 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0035] [035] According to yet another embodiment of the present invention, component I is compound I-7. The compound I-7 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-7.
[0036] [036] According to a specific embodiment, compound I-7 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0037] [037] According to an even more specific embodiment, compound I-7 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0038] [038] According to yet another embodiment of the present invention, component I is compound I-8. The compound I-8 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-8.
[0039] [039] According to a specific embodiment, compound I-8 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0040] [040] According to an even more specific embodiment, compound I-8 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0041] [041] According to yet another embodiment of the present invention, component I is compound I-9. The compound I-9 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-9.
[0042] [042] According to a specific embodiment, compound I-9 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0043] [043] According to an even more specific embodiment, compound I-9 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0044] [044] According to yet another embodiment of the present invention, component I is compound I-10. The compound I-10 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-10.
[0045] [045] According to a specific embodiment, compound I-10 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0046] [046] According to an even more specific embodiment, compound I-10 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0047] [047] According to yet another embodiment of the present invention, component I is compound I-11. The compound I-11 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-11.
[0048] [048] According to a specific embodiment, compound I-11 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0049] [049] According to an even more specific embodiment, compound I-11 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0050] [050] According to yet another embodiment of the present invention, component I is compound I-12. The compound I-12 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-12.
[0051] [051] According to a specific embodiment, compound I-12 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0052] [052] According to an even more specific embodiment, compound I-12 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0053] [053] In accordance with yet another embodiment of the present invention, component I is compound I-13. The compound I-13 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-13.
[0054] [054] According to a specific embodiment, compound I-13 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0055] [055] According to an even more specific embodiment, compound I-13 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0056] [056] According to yet another embodiment of the present invention, component I is compound I-14. The compound I-14 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-14.
[0057] [057] According to a specific embodiment, compound I-14 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0058] [058] According to an even more specific embodiment, compound I-14 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0059] [059] According to yet another embodiment of the present invention, component I is compound I-15. The compound I-15 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-15.
[0060] [060] According to a specific embodiment, compound I-15 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0061] [061] According to an even more specific embodiment, compound I-15 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0062] [062] According to yet another embodiment of the present invention, component I is compound I-16. The compound I-16 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-16.
[0063] [063] According to a specific embodiment, compound I-16 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0064] [064] According to an even more specific embodiment, compound I-16 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0065] [065] According to yet another embodiment of the present invention, component I is compound I-17. The compound I-17 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-17.
[0066] [066] According to a specific embodiment, compound I-17 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0067] [067] According to an even more specific embodiment, compound I-17 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0068] [068] According to yet another embodiment of the present invention, component I is compound I-18. The compound I-18 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-18.
[0069] [069] According to a specific embodiment, compound I-18 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0070] [070] According to an even more specific embodiment, compound I-18 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0071] [071] According to yet another embodiment of the present invention, component I is compound I-19. The compound I-19 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-19.
[0072] [072] According to a specific embodiment, compound I-19 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0073] [073] According to an even more specific embodiment, compound I-19 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0074] [074] In accordance with yet another embodiment of the present invention, component I is compound I-20. The compound I-20 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-20.
[0075] [075] According to a specific embodiment, compound I-20 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0076] [076] According to an even more specific embodiment, compound I-20 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0077] [077] According to yet another embodiment of the present invention, component I is compound I-21. The compound I-21 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-21.
[0078] [078] According to a specific embodiment, compound I-21 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0079] [079] According to an even more specific embodiment, compound I-21 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0080] [080] According to yet another embodiment of the present invention, component I is compound I-22. The compound I-22 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-22.
[0081] [081] According to a specific embodiment, compound I-22 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0082] [082] According to an even more specific embodiment, compound I-22 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0083] [083] According to yet another embodiment of the present invention, component I is compound I-23. The compound I-23 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-23.
[0084] [084] According to a specific embodiment, compound I-23 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0085] [085] According to an even more specific embodiment, compound I-23 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0086] [086] According to yet another embodiment of the present invention, component I is compound I-24. The compound I-24 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-24.
[0087] [087] According to a specific embodiment, compound I-24 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0088] [088] According to an even more specific embodiment, compound I-24 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0089] [089] According to yet another embodiment of the present invention, component I is compound I-25. The compound I-25 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-25.
[0090] [090] According to a specific embodiment, compound I-25 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0091] [091] According to an even more specific embodiment, compound I-25 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0092] [092] According to yet another embodiment of the present invention, component I is compound I-26. The compound I-26 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-26.
[0093] [093] According to a specific embodiment, compound I-26 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0094] [094] According to an even more specific embodiment, compound I-26 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0095] [095] According to yet another embodiment of the present invention, component I is compound I-27. The compound I-27 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-27.
[0096] [096] According to a specific embodiment, compound I-27 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0097] [097] According to an even more specific embodiment, compound I-27 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0098] [098] According to yet another embodiment of the present invention, component I is compound I-28. The compound I-28 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-28.
[0099] [099] According to a specific embodiment, compound I-28 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0100] [0100] According to an even more specific embodiment, compound I-28 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0101] [0101] According to yet another embodiment of the present invention, component I is compound I-29. The compound I-29 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-29.
[0102] [0102] According to a specific embodiment, compound I-29 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0103] [0103] According to an even more specific embodiment, compound I-29 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0104] [0104] According to yet another embodiment of the present invention, component I is compound I-30. The compound I-30 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-30.
[0105] [0105] According to a specific embodiment, compound I-30 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0106] [0106] According to an even more specific embodiment, compound I-30 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0107] [0107] According to yet another embodiment of the present invention, component I is compound I-31. The compound I-31 can be present as a racemic composition of the enantiomer (R) and enantiomer (S), but the enantiomer (R) and the enantiomer (S), can also be present in any other proportion, for example, the pure enantiomer (R) or the pure (S) enantiomer of I-31.
[0108] [0108] According to a specific embodiment, compound I-31 is supplied and used as an enantiomer (R) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60% , 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably at least 98% and even more preferably at least 99%.
[0109] [0109] According to an even more specific embodiment, compound I-31 is supplied and used as an enantiomer (S) with an enantiomeric excess (ee) of at least 40%, for example, at least 50%, 60%, 70% or 80%, preferably at least 90%, most preferably at least 95%, most preferably still at least 98% and even more preferably at least 99% .
[0110] [0110] In accordance with an embodiment of the present invention, component I is selected from compounds I-17, I-18, I-19, I-23, I-25 and I-29. According to another embodiment of the present invention, component I is selected from compounds I-19, I-23, I-25, I-28, I-29, I-30 and I-31. In accordance with yet another embodiment of the present invention, component I is selected from compounds I-17, I-18, I-26 and I-27. In accordance with yet another embodiment of the present invention, component I is selected from compounds I-20, I-21, I-22 and I-24.
[0111] [0111] According to another embodiment of the present invention, component I is selected from compounds I-1, I-2, I-3, I-4, I-5, I-6, 7-I, I-8, I-9, I-10, I-11, I-12, I-13, I-14, I-15 and I-16. In accordance with a more special embodiment of the present invention, component I is selected from compounds I-1, I-2, I-6, 8-I and I-12. In accordance with yet another special embodiment of the present invention, component I is selected from compounds I-3, I-4, I-5, I-7, I-9, I-11, I-13, I -14, I -15 and I-16.
[0112] [0112] In accordance with yet another embodiment of the present invention, component I is selected from compounds I-1, I-2, I-3, I-4, I-5 and I-17.
[0113] [0113] In accordance with yet another embodiment of the present invention, component I is selected from compounds I-1, I-2, I-3, I-4 and I-5.
[0114] [0114] In accordance with yet another embodiment of the present invention, component I is selected from compounds I-17 and I-18.
[0115] [0115] A pesticide, in general, is a chemical or biological agent (such as the active pesticide ingredient, compound, composition, virus, bacteria, antimicrobial or disinfectant), which through its deterrent, incapacitates, kills or does not discourage pests. Target pests can include insects, plant pathogens, weeds, mollusks, birds, mammals, fish, nematodes (worms), and microbes that destroy properties, cause discomfort, spread disease or are vectors of diseases. The term "pesticides" also includes plant growth regulators that alter the expected growth, flowering, or rate of reproduction of the plants; defoliants that cause leaves or other foliage to come loose from a vegetable, in general, to facilitate harvesting; desiccants that promote the drying of living tissues, such as the tops of unwanted vegetables; plant activators that activate plant physiology to defend against certain pests; protective agents that reduce the unwanted herbicidal action of pesticides in vegetable crops; and plant growth promoters that affect plant physiology to increase plant growth, biomass, yield or any other quality parameter of the cultivable commodities of the crop vegetables.
[0116] [0116] Biopesticides are normally created through the growth and concentration of naturally occurring organisms and / or their metabolites, including bacteria and other microbes, fungi, viruses, nematodes, proteins, and the like. They are often considered to be important components of integrated pest protection programs (IPM), and have received much practical attention as a substitute for synthetic chemical plant protection products (PPPs).
[0117] (1) os pesticidas microbianos consistem em bactérias, fungos ou vírus (e muitas vezes incluem os metabolitos que as bactérias e os fungos produzem). Esses nematoides endopatogênicos também são classificados como pesticidas microbianos, embora eles sejam multicelulares. (2) os pesticidas bioquímicos são substâncias de ocorrência natural que controlam as pragas ou fornecem outras utilizações na proteção das culturas, conforme definido abaixo, mas são relativamente não tóxicos para os mamíferos. [0117] Biopesticides are found in two main classes of microbial and biochemical pesticides: (1) microbial pesticides consist of bacteria, fungi or viruses (and often include the metabolites that bacteria and fungi produce). These endopathogenic nematodes are also classified as microbial pesticides, although they are multicellular. (2) biochemical pesticides are naturally occurring substances that control pests or provide other uses for crop protection, as defined below, but are relatively non-toxic to mammals.
[0118] [0118] The user applies the composition, according to the process of the present invention, from a pre-dosing device, a backpack sprayer, a spray tank or an irrigation system. Usually, the agrochemical composition is made with water, buffer, and / or other auxiliary agents for the desired application concentration and the ready-to-use spray solution or agrochemical composition, according to the present invention, is therefore obtained . Normally, from 20 to 2,000 liters, preferably from 50 to 400 liters, of the ready-to-use spray solution are applied per hectare of the useful agricultural area.
[0119] [0119] According to one embodiment, the individual components of the composition according to the present invention, such as parts of an assembly or parts of a binary or ternary mixture can be mixed by the user himself, in a spray tank or any other type of container used for applications (for example, seed treatment drums, seed pelletizing machines, backpack sprayer) and other auxiliaries can be added, if appropriate.
[0120] [0120] When live microorganisms, such as pesticides in groups (L1), (L3) and (L5), are part of this set, care must be taken that the selection and quantities of the components (for example, agents chemical pesticides) and other auxiliaries do not influence the viability of microbial pesticides in the composition mixed by the user. Especially for bactericides and solvents, compatibility with the respective microbial pesticide needs to be taken into account.
[0121] [0121] Consequently, an embodiment of the present invention is a kit for the preparation of a useful pesticidal composition, the kit comprises (a) a composition comprising a component I as defined herein and at least one auxiliary; and (b) a composition comprising component II as defined herein and at least one auxiliary; and optionally, (c) a composition comprising at least one auxiliary and optionally, another active component III, as defined herein.
[0122] [0122] Many of these biopesticides that were deposited under the deposition numbers mentioned in the present (the prefixes refer to the acronym of the respective culture collection), are referred to in the literature, are registered and / or commercially available: aluminum silicate (ScreenTM Duo of Certis LLC, USA), Agrobacterium radiobacter K1026 (e.g., NoGall® by Becker Underwood Pty Ltd., Australia), A. radiobacter K84 (Nature 280, 697-699, 1979; for example, by GallTroll® AG Biochem, Inc., C, USA), Ampelomyces quisqualis, M-10 (for example, AQ 10® from Intrachem Bio GmbH & Co. KG, Germany), Ascophyllum nodosum (Norwegian kelp, Brown kelp) extract or filtered (for example , ORKA Gold of BASF Agricultural Specialties (Pty) Ltd., South Africa, or Goemar® de Laboratoires Goemar, France), Aspergillus flavus NRRL 21882 isolated from a peanut in Georgia, in 1991, by USDA, National Peanut Research Laboratory (for example, in Afla-Guard® by Syngenta, CH), c omissions of Aureobasidium pullulans DSM14940 and DSM 14941 (for example, blastospores in BlossomProtect® by bio-ferm GmbH, Germany), Azospirillum amazonense BR 11140 (SpY2T) (Proc. 9 Int. And first meeting of Latin America PGPR, Quimara, Medellín, Colombia 2012, 60 p., ISBN 978-958-46- 0908-3), A. brasilense AZ39 (also called Az 39; INTA Az-39; Eur J. Biol Soil 45 (1), 28-35, 2009), A. brasilense XOH (for example, AZOS from Xtreme Gardening, USA or RTI International Reforestation Techniques; USA), A brasilense BR 11002 (Proc 9 Int. and first Latin America meeting PGPR, Quimara, Medellín, Colombia 2012, page 60, ISBN 978-958-46-0908-3), A. brasilense BR 11005 (SP245; for example, on BASF Agricultural Specialties Ltd GELFIX grasses ., Brazil), A. brasilense strains Ab-V5 and AbV6 (for example, in AzoMax from Novozymes BioAg Produtos papra Agricultura Ltda, Quattro Barras, Brazil or SimbioseMaíz® from Simbiose-Agro, Cruz Alta, RS, Brazil; Plant Soil 331, 413-425, 2010), A. lipoferum BR 11646 (Sp31) (Proc. 9 Int. And first meeting of Latin America PGPR, Quimara, Medellin 2012, page 60), Bacillus altitudinis 41KF2b (DSM 21631; Int J. Syst. Evol. Microbiol. 56 (7), 1.465-1.473, 2006), Bacillus amyloliquefaciens strains AP-136 (NRRL B50614 and B-50330), AP-188 (NRRL B-50615 and B-50331), AP-218 (NRRL B50618), AP -219 (NRRL B-50619 and B-50332), and AP-295 (NRRL B-50620 and B50333), all known from US patent 8,445,255; B. amyloliquefaciens TI-45 (CNCM I 3800) (for example, from Rhizocell C ITHEC, France), B. amyloliquefaciens IN937a (J. Microbiol Biotechnol 17 (2), 280-286, 2007; for example, from Gustafson LLC BioYield ®, TX, USA), B. amyloliquefaciens spp. plantarum D747 (US patent 2013 / 0.236,522 A1; FERM BP 8234; for example, Double Nickel ™ 55 WDG or Double Nickel ™ LC of Certis LLC, USA), B. amyloliquefaciens spp. plantarum FZB24 isolated from the plant pathogen infested soil of a sugar beet field in Brandenburg, Germany (also called SB3615; DSM ID 96-2; J. Planta Dis Prot 105, 181-197, 1998; for example, Taegro® of Novozyme Biologicals, Inc., USA)), B. amyloliquefaciens spp. plantarum SB3615vPPI being a phage-resistant variant of FZB24 (MRRL B-50349, US patent 2011 / 023,045 A1, from Novozyme Biologicals, Inc., USA), B. amyloliquefaciens ssp. plantarum FZB42 isolated from the plant-infested soil of a sugar beet field in Brandenburg, Germany (J. Planta Dis Prot 105, 181-197, 1998; DSM 23117; for example, RhizoVital® 42 from AbiTEP GmbH, Berlin, Germany ), B. amyloliquefaciens ssp. plantarum GB03 (also called GBO3; ATCC SD-1397; Phytopathol 86 (11), S36, 1996; for example, Kodiak® or BioYield® by Gustafson, Inc., USA; or Companion® by Produts Growing, Ltd., White Plains , NY 10603, USA), B. amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430 (NRRL B-50595; Int. J. Microbiol Res 3 (2) (2011), 120-130; US patent 2012/0149571 A1, for example, Integral®, Subtilex® NG at BASF Corp. , USA), B. amyloliquefaciens spp. plantarum TJ1000 (also called 1BE; CA 2,471,555 A1; ATCC BAA-390, for example, from TJ QuickRoots ™ Technologies, Watertown, SD, USA), B. cereus CNCM I-1562 (US 6,406,690), B. chitinosporus AQ746 isolated from roots in Saskatchewan, Canada (NRRL B-21618; US 5,733,544; AgraQuest now Bayer CropScience LP, USA), B. firmus CNCM I-1582 (WO 2009/126473, WO 2009/124707, US 6,406,690, for example, Votivo® from Bayer Crop Sciencie LP, USA), strains of B. megaterium H491 (NRRL B-50769), M018 (NRRL B-50770) and J142 (NRRL B-50771) all known from US Patent 2014/0051571 A1 to Marrone Bio Innovations, Inc., USA; B. mojavensis AP-209 (NRRL B-50616, US 8,445,255), B. mycoides AQ726 (NRRL B-21664, US 5,906,818, from Bayer Crop Science, Germany), strain B. mycoides J (for example, BMJ GT from Certis, USA against potato Y virus), B. pumilus GB34 (ATCC 700814; for example, YieldShield® by Gustafson LLC, TX, USA), B. pumilus GHA 180 isolated from apple rhizosphere in Mexico (IDAC 260707 -01; for example, in PRO-Mix® BX by Premier Horticulture, 1, avenue Premier, Rivie`re-du-Loup, Quebec, Canada G5R6C1), B. pumilus KFP9F (NRRL B-50754; WO 2014/029697, for example, BAC-UP or FUSION-P from BASF Agricultural Specialties (Pty) Ltd., South Africa), B. pumilus INR-7 otherwise referred to as BU-F22 and BU-F33 (NRRL B-50185, NRRL B-50153, US 8,445,255), B. pumilus QST 2808 (NRRL B 30087; for example, Sonata® or Ballad® Plus from AgraQuest Inc., USA), B. solisalsi AP-217 (NRRL B-50617; US 8,445,255), B. subtilis CX-9060 (Federal Register 77 (7), 1,633-1,637; by Certis EUA, LLC), B. subtilis FB17 also called UD 1022 or UD10-22 isolated from red beets in North America (ATCC PTA11857; System Appl. Microbiol 27 (2004) 372-379, 2004; US 2010/0260735; WO 2011/109395); B. subtilis GB07 (Phytopathol 86 (11), S36, 1996; Epic® by Gustafson, Inc., USA), B. subtilis QST-713 isolated from a California peach orchard in 1995 (NRRL B-21661a Rhapsody® , for example, Serenade® MAX or Serenade® ASO from AgraQuest Inc., USA), by B. thuringiensis ssp. aizawai ABTS-1857 (also called ABG-6346; ATCC SD-1372; for example, XenTari® from BioFa AG, Münsingen, Germany), B. t. ssp. aizawai SAN 401 I, ABG-6305 (WO 2013/087709); Bacillus t. ssp. israelensis AM65-52 from Serotype H-14 (ATCC SD-1276; for example, VectoBac® by Valent BioSciences, IL, USA), Bacillus thuringiensis ssp. kurstaki SB4 (NRRL B-50753; for example, Beta Pro® from BASF Agricultural Specialties (Pty) Ltd., South Africa), B. t. ssp. kurstaki ABTS-351 identical to HD-1 (ATCC SD-1275; for example, Dipel® DF from Valent BioSciences, IL, USA), B. t. ssp. kurstaki EG 2348 (NRRL B-18208; for example, Lepinox® or Rapax® from CBC (Europe) Srl, Italy), B. t. ssp. tenebrionis DSM 2803 from Serotype H 8a, 8b (identical to NRRL B-15939; EP 0.585.215 B1; Mycogen Corp.), B. t. ssp. tenebrionis NB-125 (also referred to as SAN 418 I or ABG-6479; EP.585.215 B1; DSM 5526; previous production strain of Novo-Nordisk), B. t. ssp. tenebrionis NB-176 (or NB-176-1; an irrigated high-throughput gamma mutant, induced from the NB-125 strain; EP 585.215 B1; DSM 5480, for example, Novodor® by Valent BioSciences, Switzerland), Beauveria bassiana JW- 1 (ATCC 74040; for example, Naturalis® from CBC (Europe) Srl, Italy), B. bassiana DSM 12256 (US 200,020,031,495, for example, BioExpert® SC of Live Sytems Technology SA, Colombia), B. bassiana GHA (ATCC 74250; for example, BotaniGard® 22WGP by Laverlam Int. Corp., USA), B. bassiana PPRI 5339. (ARSEF 5339; NRRL 50757, for example, BroadBand® by BASF Agricultural Specialties (Pty) Ltd., South Africa Sul), B. brongniartii for the control of beetle (J. Appl. Microbiol 100 (5), 1.063-1.072, 2006; for example, Melocont® from Agrifutur, Agrianello, Italy), Bradyrhizobium sp. (for example, Vault® by BASF Corp., USA), B. sp. (Arachis) CB1015 presumably originally collected in India (IITA 1006, USDA 3446, Autralian Inoculant Research Group; http://www.qaseeds.com.au/inoculant_applic.php). B. sp. (Arachis) deposited in SEMIA and known to FEMS Microbiol. Letters 303 (2), 123- 131, 2010a Brazilian Journal of Soil Science 35 (3), 739-742, 2011, ISSN 0.100-0.683: SEMIA 6144, SEMIA 6462 (BR 3267) and SEMIA 6464 (BR 3262); B. sp. (Vigna) PNL01 (Bisson and Mason, April 29, 2010, Project Report, Worcester Polytechnic Institute, Worcester, MA, USA: http://www.wpi.edu/Pubs/E-project/Available/E-project -042810-163614 /; for example, Vault® Peanut Liquid from BASF Corp., USA), B. elkanii SEMIA 587 (Appl Environ Microbiol 73 (8), 2.635, 2007; for example, from BASF GELFIX 5 Agricultural Specialties Ltd. , Brazil), B. elkanii SEMIA 5019 (= 29W ;. Appl Environ Microbiol 73 (8.), 2635, 2007; for example, GELFIX 5 from BASF Agricultural Specialties Ltd., Brazil), B. elkanii USDA 76, B. elkanii USDA 94B. elkanii USDA 3254, B. elkanii L-1301 and L-1302 (for example, Nitragin® Optimize from Novozymes Bio As SA, Brazil, or Nitrasec for soy from LAGE y Cia, Brazil), B. japonicum (for example, Vault ® from BASF Corp., USA), B. japonicum 532c isolated from the Wisconsin field (Nitragin 61A152; Can J. Plant Sci 70, 661-666, 1990; for example, in Rhizoflo®, Histick®, Hicoat® Super from BASF Agricultural Specialties Ltd., Canada), B. japonicum E-109 variant of the USDA 138 strain (INTA E109, SEMIA 5085; Eur. J. Soil Biol 45, 28-35, 2009; Biol Fertil Soils 47, 81-89 , 2011), B. japonicum G49 (MSDJ G49; CR Acad. Agric. Fr. 73, 163-171, 1987); B. japonicum strains deposited in SEMIA known from Appl. Environ. Microbiol. 73 (8), 2,635, 2007: SEMIA 566 isolated from North American inoculant in 1966 and used in Brazilian commercial inoculants from 1966 to 1978, SEMIA 586 originally isolated in Maryland, USA, in 1961, but received from Australia in 1966 and was used in Brazilian inoculants in 1977 (CB 1809, USDA 136, Nitragin 61A136, RCR 3407), SEMIA 5079 a natural variant of SEMIA 566 used in commercial inoculants since 1992 (CPAC 15, for example, BASF GELFIX 5 or ADHERE 60 Agricultural Specialties Ltd., Brazil), B. japonicum SEMIA 5080 a natural variant of SEMIA 586 used in commercial inoculants since 1992 (CPAC 7; for example, GELFIX 5 or ADHERE 60 from BASF Agricultural Specialties Ltd., Brazil); B. japonicum TA-11 (TA11 NOD +) (NRRL B-18466; US 5,021,076; Appl. Environ. Microbiol. 56, 2.399-2.403, 1990; for example, Vault® NP from BASF Corp., USA), strain B. japonicum filed in US patent known to US 7,262,151 and Appl. Environ. Microbiol. 60, 940- 94, 1994: USDA 3 isolated from Glycine max in Virginia (USA) in 1914, USDA 31 (= Nitragin 61A164) od Serogrup 31 isolated from Glycine max in Wisconsin (USA) in 1941, USDA 76 isolated plant passage of the strain USDA 74 (Serogrup 76), which was isolated from G. max, in California (USA), in 1956, USDA 110 (= IITA 2121, SEMIA 5032, RCR 3427, ARS I-110 and Nitragin 61A89; Serogroup 110) isolated from G. max, Florida, in 1959, USDA 121 isolated from G. max in Ohio (USA), in 1965 (Crop Science 26 (5), 911-916, 1986); B. japonicum WB74 (for example, Eco-Rhiz Soya from Plant Health Products (Pty) Ltd, South Africa, or Soybean inoculant from Stimuplant CC, South Africa), BB Lupini LL13 isolated from Lupinus iuteus nodules from French soils ( deposited with INRA, France; http://agriculture.gouv.fr/IMG/pdf/ch20060216.pdf), B. Lupini strains from Australia and known from Palta JA, Berger JB (eds), Proceed. 12th International Lupine Conference, 14-18 September 2008, Fremantle, Western Australia, Lupine International Association, Canterbury, New Zealand, 47-50, http: //www.lupins.org/pdf/conference/2008/Agronomy%20and % 20Production / John% 20Howieson% 20and% 20G% 20OHara.pdf; Appl. Environ. Microbiol. 71, 7,041- 7,052, 2005; Australian J. Exp. Agricult. 36 (1), 63-70, 1996: isolated WU425 strains in Esperance, Western Australia from a non-Australian vegetable Ornithopus compressus, WSM471 isolated from Ornithopus pinnatus in Oyster Harbor, Western Australia, and WSM4024 isolated from lupins in Australia, by CRS during a 2005 survey; Burkholderia sp. A396 (NRRL B-50319; WO 2013/032693; Marrone Bio Innovations, Inc., USA), Candida oleophila I182 (NRRL Y-18846; Phytoparasitica 23 (3), 231-234, 1995; for example, Aspire® from Ecogen Inc., USA;), strain C. oleophila O (NRRL Y 2317; Biological Control 51, 403-408, 2009), Candida saitoana (e.g. Biocure® [in mixture with lysozyme] and BioCoat® from Micro Flo Company, USA (BASF SE) and Arysta), chitosan (for example, Armor-Zen® by BotriZen Ltd., NZ), Clonostachys rosea f. catenulate (also called Gliocladium catenulatum) J1446 isolated from Finnish field soil (NJF Seminar No. 389: Pest, disease and weed management in strawberry; Finland from 8 to 9 November 2006 in NJF Report 2 (10), 15-15, 2006; DSM 9212, for example, Primastop® or Prestop® from Verdera Oy, Finland), Chromobacterium subtsugae PRAA4-1 isolated from the soil under an eastern hemlock (Tsuga canadensis) from Catoctin Mountain, in central Maryland (NRRL B30655; by Grandevo® from Marrone Bio Innovations, USA), Coniothyrium minitans CON / M / 91-08 (WO 1996/021358; DSM 9660, for example, Contans® WG, Intercept® WG from Prophyta Biologischer Pflanzenschutz GmbH, Germany), Cryphonectria parasitic (hypovirulent strains; Microbiol. Reviews 56 (4), 561-576, 1992; for example, product Endothia parasitica from CNICM, France), Cryptococcus albidus (for example, YIELD PLUS® from Anchor Bio-Technologies, South Africa) , Cryptophlebia leucotreta granulovirus (CrleGV) (for example, CRYPTEX from A ndermatt Biocontrol, Switzerland), Cydia pomonella granulovirus (CpGV) V03 (DSM GV-0006; for example, Madex® Max from Andermatt Biocontrol, Switzerland), CpGV V22 (DSM GV-0014, for example, Madex® Twin from Andermatt Biocontrol, Switzerland), Delftia acidovorans RAY209 (ATCC PTA-4249; WO 2003/57861, for example , BioBoost® by Brett Young, Winnipeg, Canada), Dilophosphora alopecuri (FarmNote 396, February 2010, Department of Agriculture and Food, Government of Western Australia, for example, Twist Fungus from BASF Agricultural Specialties Pty Ltd, Australia), extract Ecklonia maxima (alga) (J. Ecological Engineering 14 (1), 48-52, 2013; for example, KELPAK SL from Kelp Products Ltd, South Africa), Flavobacterium sp. H492 (ATCC B-505,584; WO 2013/138398, for example, MBI-302 from Marrone Bio Innovations, USA for the control of soy cyst nematode), formononetine (US 5,002,603, for example, Myconate® from Plant Health Care plc, United Kingdom), Fusarium oxysporum Fo47 (non-pathogenic isolated strain of a suppressive soil located in Châteaurenard, France; Appl. Environ. Microbiol 68 (8), 4.044- 4.060, 2002; Fusaclean® by Natural Plant Protection, NPP ( société anonyme) Route d'Artix F-64,150 Nogueres, France), F. oxysporum 251 / 2RB (Preventio Today Vol 2, n 1-2, 47-62, 2006; for example, Biofox® C from SIAPA, Italy); Glomus intraradices (for example, Myc® 4000 from ITHEC, France), Glomus intraradices RTI-801 (for example, MYKOS from Xtreme Jardinagem, USA or RTI Reforestation Technologies International; USA), pomelo seed and pulp extract (for example, BC-1000 from Chemie SA, Chile), harpin protein (alpha-beta) (Science 257, 85-88, 1992; for example, Messenger ™ or HARP-N-Tek from Plant Health Care plc, United Kingdom), nucleopolihedrovirus Helicoverpa armigera (HearNPV) (J. Invertebrate Pathol. 107, 112-126, 2011; for example, Helicovex® by Andermatt Biocontrol, Switzerland), Heterorhabditis bacteriophora (for example, Nemasys® G of BASF Agricultural Specialties Limited, United Kingdom), Isaria fumosorosea Apopka-97 (ATCC 20874; Biocontrol Science Technol. 22 (7), 747-761, 2012; for example, PFR-97 ™ or PreFeRal® from Certis LLC, USA), I. fumosorosea FE 9901 (ARSEF 4490; Biocontrol Science Technol. 22 (7), 747-761, 2012; for example, blastospores at NoFly ™ WP from Natural Industries, Inc., Houston, TX, USA or from Novozymes, USA), cisjasmona (US 6,890,525, US 8,221,736; Plant Bioscience Limited, Norwich, United Kingdom), laminarin (for example, in Vacciplant® by Laboratoires Goemar, St. Malo, France or Stähler SA, Switzerland), Lecanicillium longisporum KV42 and KV71 (for example, Vertalec® from Koppert BV, Netherlands ), L. muscarium Ve6 (also called KV01; IMI 19-79, CABI 268.317, CBS 102071, ARSEF 5128, for example, Mycotal® from Koppert BV, Netherlands), Lysobacter antibioticus 13-1 (Biological Control 45, 288-296 , 2008), L. antibioticus HS124 (Curr. Microbiol. 59 (6), 608-615, 2009), L. enzymogenes 3.1T8 (Microbiol. Res. 158, 107-115, 2003; Biological Control 31 (2), 145-154, 2004); strains Mesorhizobium spp. known from Soil Biol. Biochem. 36 (8), 1,309-1,317, 2004; Plant and Soil 348 (1-2), 231-243, 2011: M. sp. WSM1271 collected in Sardinia, Italy, from the host vegetable Biserrula pelecinus, M. sp. WSM 1497 collected in Mykonos, Greece, from Biserrula pelecinus, Mesorhizobium ciceri CC1192 collected in Israel from Cicer arietinum nodules (UPM 848, CECT 5549; Can. J. Microbiol. 48, 279-284, 2002; from Horticultural Research Station, Gosford, Australia), M. huakuii HN3015 isolated from Astralagus sinicus in a rice field in South China (World J. Microbiol. Biotechn. 23 (6), 845-851, 2007, ISSN 0.959-3.993) , M. loti CC829 isolated from L. ulginosus nodules in the USA (NZP 2012; commercial inoculant for Lotus pedunculatus and L. ulginosus in Australia), and M. loti SU343 isolated from host nodules in the USA (commercial inoculant for Lotus corniculatus in Australia); Metarhizium anisopliae FI-1045 (AGAL V10 / 0.104.285; WO 2012/018266, for example, Biocane® from BASF Agricultural Specialties Pty Ltd, Australia), M. anisopliae var. anisopliae F52 also called 275 or V275 (DSM 3884, ATCC 90448; for example, Met52® Novozymes Biologicals BioAg Group, Canada), M. anisopliae ICIPE 69 isolated from a soil sample obtained from the Democratic Republic of Congo (DRC) and using the Galleria bait method in 1990 (for example, ICIPE Metathripol, Nairobe, Kenya), M. anisopliae var. acridum IMI 330189 isolated from Ornithacris cavroisi in Niger (NRRL 50758, for example, Green Muscle® from BASF Agricultural Specialties (Pty) Ltd., South Africa), M. a. var. acridum FI985 isolated from a spur-throated locust, Austracris guttulosa (Walker), near Rockhampton, Queensland, Australia, in 1979 (ARSEF 324; Memoirs of the Entomological Society of Canada 171, 287-300, 1997; for example, Green Guard® SC from BASF Agricultural Specialties Pty Ltd, Australia), Metschnikowia fructicola 277 isolated from the surface of grape berries (Superior cv) grown in central Israel (US 6,994,849; NRRL Y30752; for example, from Shemer ® Agrogreen, Israel, currently distributed by Bayer CropSciences, Germany), Microdochium dimerum L13 (CNCM I-3141, for example, Antibot® from Agrauxine, France), Microsphaeropsis ochracea P130A isolated from apple leaves an abandoned orchard, StJoseph- du-Lac, Quebec, Canada in 1993 (ATCC 74.412; Mycologia 94 (2), 297-301, 2002), Muscodor albus QST 20799 also called 620 originally isolated from the bark of a cinnamon tree in Honduras (NRRL 30547; for example, Muscudor ™ or QRD300 from Agra-Que st, USA), Muscodor albus SA-13 (NRRL B-50774; US 2014/0086879 A1; for example, MBI-601-EP by Marrone BioInnovations, Inc., USA), Neem oil (eg, Trilogy®, Triact® 70 CE, Certis LLC, USA), Nomuraea rileyi SA86101, GU87401, SR86151, CG128 and VA9101 (Braz. Arch. Biol Technol. 46 (1), 13-19, 2003; WO 2013/110594), Paecilomyces lilacinus 251 isolated from infected nematode eggs in the Philippines (AGAL 89/030550; WO1991 / 02051; Crop. Protection. 27, 352-361, 2008; for example, BioAct® / MeloCon® of Prophyta, Germany), P. lilacinus DSM 15169 (for example, Nemata® SC of Live Systems Technology SA, Colombia), P. lilacinus BCP2 (NRRL 50756 ; Acta agriculturee Slovenica, 101-2, 263-275, 2013; for example, PL Gold from BASF Agricultural Specialties (Pty) Ltd., South Africa), Paenibacillus alvei NAS6G6 (WO 2014/029697; NRRL B-50755; by example, BAC-UP from BASF Agricultural Specialties (Pty) Ltd., South Africa in mixture with Bacillus pumilus KFP9F), P. polymyxa PKB1 (ATCC 202127; Can. J. Microbiol 48 (2), 159-169, 2002) , Pantoea agglomerans E325 (NRRL B-21856; Phytopathol 101 (10), 1,234-1,241, 2011; Trees 26, 227-238, 2012; Bloomtime Biological ™ from Northwest Agricultural Products, Inc., USA), Pantoea vagans (formerly agglomerans) C9-1 originally isolated in 1994 from apple stem tissue to control bacterial fire in the apple (J. Bacteriol. 192 ( 24), 6,486-6,487, 2010; for example, BlightBan C9-1 ® from NuFrams America Inc., USA), Pasteuria sp. ATCC PTA-9643 (WO 2010/085795), Pasteuria sp. Ph3 isolated from soil samples collected on the DeBary Golf Course lawn in central Florida (ATCC SD-5832; WO 2012/064527; for the control of Hoplolaimus galeatus nematode from Pasteuria Bioscience, Inc. at the time Syngenta Crop Protection, LLC, USA), Pasteuria sp. Pr3 isolated from soil samples collected in the southeastern United States (ATCC SD-5834; for the donematoid control Rotylenchulus reniformis potentially of P. ramosa species; Naviva® ST of Syngenta Crop Protection, LLC, USA), P. nishizawae ( WO 2010/80619), P. nishizawae PN1 (Federal Register 76 (22), 5808, February 2, 2011; ATCC SD 5833; for example, Clariva ™ PN from Syngenta Crop Protection, LLC, USA), P. penetrans ( US 5,248,500; Del Monte Corp), P. ramosa (WO 2010/080619), P. thornea (WO 2010/080619), P. usgae BL1 (ATCC SD-5835; J. Nematol 42 (2.): 87 -90, 2010; ibid. 43 (2), 101-109, 2011; for example, Econem ™ for the control of Belonolaimus longicaudatus from Pasteuria BioScience at the time Syngenta marketed by Harell`s LLC, Florida, USA, for use in lawn for the management of Belonolaimus longicaudatus), Penicillium bilaiae (also called P. bilaii) strains ATCC 18309 (ATCC = 74,319), ATCC 20851 and / or ATCC 22348 (ATCC = 74,318) originally isolated soil in southern Alberta (Res 39 fertilizers, 97-103, 1994; Can. J. Plant Sci. 78 (1), 91-102, 1998; US 5,026,417, WO 1995/017806; for example, Go Start®, Provide® from Novozymes Biologicals BioAg Group, Canada), P. bilaiae NRRL 50162 and NRRL 50169 (WO 2010/037228), Phlebiopsis gigantea (e.g. RotStop® from Verdera Oy, Finland), Pichia anomala WRL-076 (NRRL Y-30842; US 8,206,972), potassium bicarbonate (eg Amicarb® from Stähler AS, Switzerland), potassium silicate (eg Sil-MATRIZ ™ from Certis LLC, USA), Pseudozyma flocculosa PF-A22 UL (e.g., Sporodex® L from Plant Products Co. Ltd., Canada), Pseudomonas sp. Proradix (DSM 13134; WO 2001/40441, for example, PRORADIX by Sourcon Padena GmbH & Co. KG, Hechinger Str 262, 72072 Tübingen, Germany), P. chloraphis MA 342 (Microbiology Monographs 18, 21-43, 2011; by for example, Cerall® or Cedemon® from Bioagri AB, Uppsala, Sweden or Intrachem Bio Deutschland GmbH & Co. KG, Bad Camberg, Germany), P. fluorescens (for example, in Bio Cure-B by T. Stanes & Company Limited, India; or at the Blight-End of Agri Naturals, Mumbai, India), P. fluorescens A506 (Phytopathol 97 (2), 244-249, 2007; ATCC 31948; for example, BlightBan® by Nufarm Americas, Inc., Morrisville, NC, USA), P. fluorescens ATCC 13525 of biovar I = biotype A; originally isolated from pre-filter tanks in England (DSM 50090; registered for use in Canada), P. fluorescens CHA0 (Mol. Planta Microbe Interact. 5 (1), 4-13, 1992.), P. fluorescens CL 145A (J. Invertebr. Pathol. 113 (1), 104-14, 2013; for example, Zequanox® by Marrone BioInnovations, Davis, CA, USA), P. fluorescens NCIB 12089 (EP 0.210.734 A1; Victus® by Mauri Laboratories, 9 Moorebank Ave., Moorebank, NSW 2170, Australia), P. fluorescens Pf-5 isolated from the cotton root surface (ATCC BAA477), P. putida ATCC 202153 (EMBRAPA 63/88 4 B; WO 2004/0245865), Pythium oligandrum DV 74 (US 2013/0035230; ATCC 38472; for example, Poyversum® by Remeslo SSRO, Biopreparaty, Czech and Gowan Rep., USA), extract Reynoutria sachalinensis (EP 0.307.510 B1; por example, Regalia® SC by Marrone BioInnovations, Davis, CA, USA or Milsana® by Biofa AG, Germany), Rhizobium leguminosarum bv. phaseoli (for example, RHIZOSTICK from BASF Corp., USA), R. leguminosarum bv. phaseoli RG-B10 (USDA 9041; from Int. J. Syst. Bacteriol. 46 (1), 240-244, 1996; Int. J. Syst. Evol. Microbiol. 50, 159-170, 2000; for example, Nodulator ® Dry Bean in Africa, HiStick NT Dry Bean in the USA, and Nodulator® Dry Bean in Canada by BASF Corp., USA, or BASF Agriculture Specialties Ltd., Canada), R. l. bv. trifolii CB782 (Nodulaid® peat for Kenya's white clover from BASF Agricultural Specialties Pty Ltd, Australia), R. l. bv. trifolii CC275e (peat Nodulaid® for NZ white clover from BASF Agricultural Specialties Pty Ltd, Australia), R. l. bv. trifolii CC283b (ICMP 4073b; Proc. New Zealand Grassland Assoc. 56, 101-105, 1994; Microbiol. 153, 3,184-3,195 2007; Nodulaid® peat for the European clover of BASF Agricultural Specialties Pty Ltd, Australia), R. l. bv. trifolii CC1099 (Inoculating Vegetables: A Pratctical Guide, ed Grain Reasearch and Development Corporation, 2012, ISBN 978-1-921779-45-9; for example, the Nodulaid® peat for the accordion of BASF Agricultural Specialties Pty Ltd, Australia), R. l. bv. trifolii RP113-7 (Appl. Environ. Microbiol. 44 (5), 1096-1101, 1982; for example, Dormal® from BASF Corp., USA), R. L. bv. trifolii TA1 (Appl Environ. Microbiol. 49 (1), 127-131, 1985; for example, the Nodulaid® peat for the white clover of BASF Agricultural Specialties Pty Ltd, Australia), strain R. l. bv. trifolii WSM1325 isolated in 1993 from the Greek island of Serifos (Stand Genomic Sci. 2 (3), 347-356, 2010; Inoculating Legumes: A Practical Legumes, ed. Grain Research and Development Corporation, 2012, ISBN 978-1 -921779- 45-9; Nodulaid® peat for the sub-clover and Nodulator® granules for the sub-clover, both from BASF Agricultural Specialties Pty Ltd, Australia, for a wide range of annual clovers of Mediterranean origin), strain R. l. bv. trifolii WSM2304 isolated from Trifolium polymorphum in Uruguay in 1998 (Stand. Genomic Sci. 2 (1), 66-76, 2010), R. l. bv. viciae P1NP3Cst a mutant resistant to P1NP3C streptomycin isolated from pea root nodules in Bretenière, France (also referred to as 1435; Nova Fitol 176, 680-690, 2007; ibid. 179 (1), 224-235, 2008; por for example, Nodulator® PL Peat Granule by BASF Corp., USA; or Nodulator® XL PL by BASF Agriculture Specialties Ltd., Canada), RL bv. viciae RG-P2 also called P2 isolated from pea root nodules in Sakatchewan, Canada (e.g., RhizUP peat for peas and lentils in Canada from BASF Agriculture Specialties Ltd., Canada), R. l. bv. viciae SU303 (for example, Nodulaid® Group E of BASF Agriculture Specialties Pty Ltd, Australia), R. l. bv. viciae WSM1455 (for example, Nodulaid® Group F from BASF Agriculture Specialties Pty Ltd, Australia), R. tropici CC511 (Agronomy, NZ 36, 4-35, 2006; for example, the Nodulaid® peat for BASF Agricultural common beans Specialties Pty Ltd, Australia) R. tropici CIAT 899 isolated in Colombia (SEMIA 4077a Rev. Ciênc Agron 44 (4) Fortaleza October / December 2013; for example, Nitrafix® BEAN peat for beans from BASF Agricultural Specialties Ltd., Brazil in mixed with SEMIA 4080 strain), R. tropici H12 isolated in Planaltina, DF, Cerrados, Brazil (SEMIA 4088; Appl Microbiol Biotechnol 93 (5), 2.035-49, 2012; for example Nitrafix® BEANS from BASF Agricultural Specialties Ltd ., Brazil), R. tropici PRF 81 isolated in Paraná, Brazil (SEMIA 4080; Soil Biology & Biochemistry 39, 867-876, 2007; BMC Microbiol 12, 84, 2012; Nitrafix® BEAN peat for BASF Agricultural Specialties beans Ltd., Brazil mixed with the SEMIA 4077 strain), Sinorhizobium meliloti RCR2011 also known as 201 1 or SU47 (MSDJ0848; Mol Gen. Genomics 272, 1-17, 2004 ;. for example, Dormal® Alfalfa & Luzerne from BASF Corp., USA; Nitragin® Gold from Novozymes Biologicals BioAg Group, Canada), Sphaerodes mycoparasitica SMCD2220 also called SMCD2220-01 (IDAC 301008-01; WO 2011/022809), nucleopolihedrovirus Spodoptera littoralis (SpliNPV) (for example, in LITTOVIR by Andermatt Bi, , Steinernema carpocapsae (e.g., Millenium® from BASF Agricultural), S. feltiae (Nemashield® from BioWorks, Inc., USA; Nemasys® from BASF Agricultural Specialties Limited, United Kingdom), S. kraussei L137 (Nemasys® L from BASF Agricultural Specialties Limited, United Kingdom), Streptomyces galbus AQ6047 (NRRL 30232; WO 2012/135763; AgraQuest at the moment Bayer CropScience LP, USA); S. galbus M1064 (NRRL 50334; WO 2012/135763; AgraQuest at the moment Bayer CropScience LP, USA); S. griseoviridis K61 (Crop Protection 25, 468-475, 2006; for example, Mycostop® by Verdera Oy, Espoo, Finland), S. lydicus WYEC 108 (US 5403584; for example, Actinovate® by Natural Industries, Inc., USA), S violaceusniger YCED-9 (USA 5,968,503; for example, DT-9 ® from Natural Industries, Inc., USA), Talaromyces flavus V117b isolated from the ground (for example, Protus® WG from Prophyta, Germany ), Trichoderma asperellum SKT-1 isolated from Japanese lawn rhizosphere (FERM P16510 ;. J. Gen. Plant Pathol 71 (5), 351-356, 2005; for example, Eco-Hope® from Kumiai Chemical Industry Co. , Ltd., Japan), T. asperellum ICC 012 isolated from a soil in central Italy, which has been found to suppress plant disease (IMI 392716, for example, Tenet WP, WP or Bioten Remdier from WP Isagro NC, USA, Bio-Tam ™ from AgraQuest, USA), T. asperellum TV1 formerly T. viride (MUCL 43093; for example, T. viride TV1 from Agribiotec srl, Italy or Xedavir from Xeda Italia, Italy), T. atroviride LC52 (for example o, Sentinel® by Agrimm Technologies Ltd, NZ), T. atroviride CNCM I-1237 (e.g. Esquive® WG from Agrauxine SA, France, for example, against pruning diseases on the vine and roots of pathogenic vegetables), T. fertil JM41R (NRRL 50759, for example, Trichoplus ™ from BASF Agricultural Specialties (Pty) Ltd., South Africa), T. gamsii ICC 080 (IMI 392151, for example, Tenet WP, Remdier WP, WP Bioten from Isagro NC, USA, Bio-Tam ™ by AgraQuest, USA), T. harzianum T-22 also known as KRL-AG2 (ATCC 20847; BioControl 57, 687-696, 2012; for example, Plantshield® by BioWorks Inc., USA or SabrEx ™ by Advanced Biological Marketing Inc., Van Wert, OH, USA), T. harzianum T-35 and T-315 (ATCC 20691; EP 0133878 B1; for example, Root Pro® from myControl Ltd., Israel), T. harzianum T-39 (CNCM I-952; EP 0466133 B2, for example, Trichodex® or Trichoderma 2000® from myControl Ltd., Israel and Makhteshim Ltd., Israel), mixture of T. harzianum and T. viride (for example, from Trichopel® Agrimm Technologies Ltd, New Zealand), mixture of Trichoderma harzianum and T. viride ICC012 ICC080 (for example, Remedier® WP from Isagro Ricerca, Italy), T. polysporum and T. harzianum (for example, BINAB® from BINAB BioInnovation AB, Sweden, mixed with T. atroviride IMI 206040), T. stromaticum (for example, TRICOVAB® from CEPLAC, Brazil), T. virens G1-3 (also called GL-3; ATCC 58678; for example, QuickRoots ™ from TJ Technologies, Watertown, SD, USA, mixed with B. amyloliquefaciens TJ1000), T. virens GL-21 also called G1-21 isolated from a sclerotio of Sclerotinia minor (US 7429477; for example, Soilguard® 12G from Certis LLC, USA; EPA Registration Number: 70051-3 and EPA Establishment Number: 067250-IL-001), T. virens G-41, also called 041, # 41x or ABM 127; isolate from soil suppressor samples taken from Aphanomyces bean fields in Livingston County, New York (ATCC 20906; US 4,996,157; for example, Rootshield® Plus from BioWorks, Inc., USA), T. viride (J. Biological Control 23 (1), 31-36, 2009; for example, from Trieco® by EcoSense Labs. (India) Pvt. Ltd., India, or Bio-Cure® F by T. Stanes & Co. Ltd., India), and Ulocladium oudemansii HRU3 (Agronomy 3, 632-647, 2013, for example, in Botry-Zen® by Botry-Zen Ltd, New Zealand).
[0123] [0123] (3) Strains can be obtained from culture collections and deposition centers (listed by their acronym prefix = strain, at present: http://www.wfcc.info/ccinfo/collection/by_acronym/) , such as strains with AGAL or NMI prefixes from: National Measurement Institute, 1/153 Bertie Street, Port Melbourne, Victoria, Australia 3207; ATCC: American Type Culture Collection, 10801 University Blvd., Manassas, VA 20110-2209, USA; BR: Embrapa Agrobiology Diazothrophic Microbial Culture Collection, POBox 74,505, Seropédica, Rio de Janeiro, 23,851-970, Brazil; CABI or IMI: CABI Europa - International Institute of Mycology, Bakeham Lane, Egham, Surrey, TW20 9TYNRRL, United Kingdom; CB: The Rhizobium Collection CB, School of Environment and Agriculture, University of Western Sydney, Hawkesbury, Locked Bag 1797, South Penrith Distribution Center, NSW 1797, Australia; CBS: Centraalbureau voor Schimmel-cultures, Fungal Biodiversity Center, Uppsalaan 8, PO Box 85167, 3508 AD Utrecht, Nether-lands; CC: Flora Industry Division, CSIRO, Canberra, Australia; CNCM: Collection Nationale de Cultures de Microorganismes, Pasteur Institute, 25 rue du Docteur Roux, F75724 Paris Cedex 15; CPAC: Embrapa-Cerrados, CX.Postal 08223, Planaltina, DF, 73301-970, Brazil; DSM: Leibniz-Institut DSMZ-Deutsche Sammlung von und Mikroorganismen Zellkulturen GmbH, Inhoffenstraße 7 B, 38124 Braun-Schweig, Germany; IDAC: International Depositary of Canada Collection, Canada; ICMP: International Collection of Microorgnisms from Plants, Landcare Research, Private Bag 92170, Auckland Mail Center, Auckland 1142, New Zealand; IITA: IITA, PMB 5320, Ibadan, Nigeria; INTA: Agriculture Collection Laboratory of the Institute of Agricultural Microbiology and Zoology (IMYZA), National Institute of Agricultural Technology (INTA), Castelar, Argentina; MSDJ: Laboratoire de Microbiologia des Sols, INRA, Dijon, France; MUCL: Mycothèque de l'Université Catholique de Louvain, Croix du Sud 2, box L7.05.06, 1348 Louvain-la-Neuve, Belgium; NCIMB or NICB: the National Collection of Industrial and Marine Bacteria Ltd., Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland; Nitragin: Nitragin strain Collection, The Nitragin Company, Milwaukee, Wisconsin, USA, NRRL or ARSEF (collection of entomopathogenic fungi): ARS Culture Collection of National Center for Agricultural Utilization Research, Agricultural Research Service, United States Department of Agriculture, 1815 North University Street, Peoria, Illinois 61604, USA; NZP: Department of Scientific and Industrial Research Culture Collection, Applied Biochemistry Division, Palmerston North, New Zealand; PPRI: ARC-Plant Protection Research Institute, Private Bag x134, Queenswood Pretoria, Gauteng, 0121, South Africa; SEMIA: FEPAGRO-State Foundation for Agricultural Research, Rua Gonçalves Dias, 570, Bairro Menino Deus, Porto Alegre / RS, Brazil; SRDI: SARDI, Adelaide, South Australia; USDA: US Department of Agriculture, Agricultural Research Service, Soybean and Alfalfa Research Laboratory, BARC-West, 10300 Baltimore Boulevard, Building 011, Room 19-9, Beltsville, MD 20705, USA (Beltsville Rhizobium Culture Collection Catalog, March 1987 USDA-ARS ARS-30: http://pdf.usaid.gov/pdf_docs/PNAAW891.pdf); and Murdoch University, Perth, Western Australia. Other strains can be found at: http://www.landcareresearch.co.nz/resources/collections/icmp.
[0124] [0124] Jasmine acid, its salts (jasmonates) or derivatives include, without limitation, potassium, sodium, lithium, ammonium, dimethylammonium, isopropylammonium, diolammonium and dietriethanolammonium; and also the methyl ester of jasmonic acid, amide of jasmonic acid, methylamide of jasmonic acid, jasmonic acid of L-amino acid (with amide bond) conjugates (for example, conjugated with L-isoleucine, L-valine, L-leucine or L-phenylalanine), 12-oxo-phytodienic acid, coronatine, coronafacoyl-L-serine, coronafacoyl-L-threonine, 1-oxo-indanoyl-isoleucine methyl esters, 1-oxo-indanoyl-leucine methyl esters , cis-jasmine, linoleic acid or its derivatives, and combinations of any of the above.
[0125] [0125] Bacillus amyloliquefaciens subsp. plantarum MBI600 which has accession number NRRL B-50595 is deposited with the United States Department of Agriculture on November 10, 2011 under the name of the strain Bacillus subtilis 1430. It was also deposited in the National Collections of Industry and Marine Bacteria Ltd. (NCIB), Torry Research Station, PO Box 31, 135 Abbey Road, Aberdeen, AB9 8DG, Scotland under accession number 1237, on December 22, 1986. Bacillus amyloliquefaciens MBI600 is known as seed treatment of the growth promoter of rice vegetable from Int. J. Microbiol. Res. ISSN 0975-5276, 3 (2) (2011), 120-130 and further described, for example, in US patent 2012/0149571 A1. This MBI600 strain, for example, is commercially available as a liquid product of Integral® formulation (Becker Underwood-Inc., USA). Metarhizium anisopliae IMI33 is commercially available from Becker Underwood as a Green Guard product. The M. anisopliae var Acridium IMI 330189 (NRRL-50758) strain is commercially available from Becker Underwood as a Green Muscle product.
[0126] [0126] According to one embodiment, microbial pesticides selected from groups (L1), (L3) and (L5), cover not only pure cultures isolated from the respective microorganism, as defined in the present, but also its extract free of cells, their suspensions in the total culture broth or as a culture medium containing the metabolite or a purified metabolite obtained from a total culture broth of the micro-organism or strain of the micro-organism.
[0127] [0127] According to another embodiment, microbial pesticides selected from groups (L1), (L3) and (L5)), cover not only pure cultures isolated from the respective microorganism, as defined in the present, but also a its cell-free extract or at least one of its metabolites, and / or a mutant of the respective micro-organism that has all its identifying characteristics and also a cell-free extract or at least one metabolite of the mutant;
[0128] [0128] The term "total culture broth" refers to a liquid culture that contains cells and media.
[0129] [0129] The term "supernatant" refers to the liquid broth remaining when cells grown in broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art.
[0130] [0130] The term "metabolite" refers to any compound, substance or by-product produced by a microorganism (such as fungi and bacteria) that has the improved growth of vegetables, the efficiency of using vegetable water, the health of the vegetable, appearance of the plant, or population of beneficial soil microorganisms surrounding plant activity.
[0131] [0131] The term "mutant" refers to a mutant microorganism obtained by direct selection, but it also includes microorganisms that have still been mutagenized or otherwise manipulated (for example, by introducing a plasmid). Consequently, the achievements include mutants, variants or and derivatives of the respective microorganism, naturally occurring and artificially induced mutants.
[0132] [0132] According to an embodiment of the compositions of the present invention, the biopesticidal component II is selected from the groups (L1a) to (L6a): (L1a) Microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity selected from: Ampelomyces quisqualis M-10 (L.1.1), Aspergillus flavus NRRL 21882 (L1.2), Aureobasidium pullulans DSM 14940 (L1.3), A. pullulans DSM 14941 (L.1.4), Bacillus altitudinis 41KF2b (L.1.5), Bacillus amyloliquefaciens AP-136 (L.1.6), B. amyloliquefaciens AP-188 (L.1.7), B amyloliquefaciens AP-218 (L.1.8), B. amyloliquefaciens AP-219 (L.1.9), B. amyloliquefaciens AP-295 (L.1.10), B. amyloliquefaciens IN937a (L.1.11), B. amyloliquefaciens TI- 45 (G.1.12), B. amyloliquefaciens ssp. plantarum D747 (L.1.13), B. amyloliquefaciens ssp. plantarum FZB24 (L.1.14), B. amyloliquefaciens ssp. plantarum FZB42 (L.1.15), B. amyloliquefaciens ssp. plantarum GB03 (L.1.16), B. amyloliquefaciens ssp. plantarum MBI600 (NRRL B-50595) (L.1.17), B. amyloliquefaciens ssp. plantarum QST-713 (L.1.18), B. amyloliquefaciens ssp. plantarum TJ1000 (L.1.19), B. mojavensis AP 209 (L.1.20), B. mycoides AQ726 (L.1.21), B. mycoides J (L.1.22), B. pumilus INR-7 (L.1.23) ), B. pumilus KFP9F (L.1.24), B. pumilus QST 2808 (L.1.25), B. pumilus GHA 180 (L.1.26), B. simplex ABU 288 (L.1.27), B. solisalsi AP 217 (L.1.28), B. subtilis CX-9060 (L.1.29), B. subtilis FB17 (L.1.30), B. subtilis GB07 (L.1.31), Candida oleophila I-82 (L.1.32), C oleophila O (L.1.33), C. saitoana (L.1.34), Clavibacter michiganensis (bacteria) (L.1.35), Coniothyrium minitans CON / M / 91-08 (L.1.36), Cryphonectria parasitica (L.1.37 ), Cryptococcus albidus (L.1.38), Dilophosphora alopecuri (L.1.39), Fusarium oxysporum (L.1.40), Clonostachys rosea f. catenulata J1446 (L.1.41), Gliocladium roseum 321U (L.1.42), Metschnikowia fructicola NRRL Y30752 (L.1.43), Microdochium dimerum (L.1.44), Microsphaeropsis ochracea P130A (L.1.45), Muscodor albus QST 20799 (L .1.46), Muscodor albus SA-13 (L.1.47), Paenibacillus alvei NAS6G6 (L.1.48), Paenibacillus polimyxa PKB1 (L.1.49), Pantoea agglomerans E325 (L.1.90), Pantoea vagans C9-1 (L. 1.50), Penicillium bilaiae ATCC 22348 (L.1.51), P. bilaiae ATCC 20851 (L.1.52), Penicillium bilaiae ATCC 18309 (L.1.53), Phlebiopsis gigantea (L.1.54), Pichia anomala WRL-76 (L. 1.55), Pseudomonas sp. Proradix (L.1.56), Pseudomonas chloraphis MA 342 (L.1.57), P. fluorescens A506 (L.1.58), P. fluorescens CL 145A (L.1.91), P. fluorescens NCIB 12089 (L.1.92), P fluorescens Pf-5 (L.1.93), P. fluorescens WCS 374 (L.1.94), P. fluorescens ATCC 13525 (L.1.95), P. fluorescens CHA0 (L.1.96), P. putida ATCC 202153 (L .1.97), Pseudozyma flocculosa PF-A22 UL (L.1.59), Pythium oligandrum DV 74 (L.1.60), Sphaerodes mycoparasitica SMCD2220 (L.1.61), Streptomyces griseoviridis K61 (L.1.62), S. lydicus WYEC 108 ( L.1.63), S. violaceusniger XL-2 (L.1.64), S. violaceusniger YCED-9 (L.1.65), Talaromyces flavus V117b (L.1.66), Trichoderma asperellum T34 (L.1.67), T. asperellum SKT-1 (L.1.68), T. asperellum ICC 012 (L.1.69), T. atroviride LC52 (L.1.70), T. atroviride CNCM I1237 (L.1.71), T. fertil JM41R (L.1.72) , T. gamsii ICC 080 (L.1.73), T. harmatum TH 382 (L.1.74), T. harzianum T-35 (L.1.75), T. harzianum T-22 (L.1.76), T. harzianum T 39 (L.1.77); mixture of T. harzianum and T. viride ICC012 ICC080 (L.1.78); T. polysporum (L.1.79); T. stromaticum (L.1.80), T. virens GI-3 (L.1.81), T. virens G-41 (L.1.82), T. virens GL-21 (L.1.83), T. virens G- 41 (L.1.84), T. viride TV1 (L.1.85), Typhula phacorrhiza 94671 (L.1.86), Ulocladium oudemansii HRU3 (L.1.87), Verticillium dalia (L.1.88), yellow mosaic zucchini virus ( non-virulent strain) (L.1.89); (L2a) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity selected from chitosan (hydrolysis) (L.2.1), harpine protein (L.2.2), laminarin (L.2.3), Menhaden fish oil (L.2.4), natamycin (L.2.5), Plum pox virus coated protein (L.2.6), potassium bicarbonate (L.2.7), Reynoutria sachalinensis extract (L.2.8), salicylic acid ( L.2.9), potassium or sodium bicarbonate (L.2.10), tea tree oil (L.2.11); (L3a) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity selected from: Agrobacterium radiobacter K1026 (L.3.1), K84 A. radiobacter (L.3.2), Bacillus firmus I 1582 (L.3.3); B. thuringiensis ssp. aizawai strains ABTS-: 1857 (L.3.4), SAN 401 I (L.3.5), ABG6305 (L.3.6) and ABG-6346 (L.3.7); B. t. ssp. israelensis AM65-52 (L.3.8), B. t. ssp. israelensis SUM-6218 (L.3.9), B. t. ssp. galleriae SDS-502 (L.3.10), B. t. ssp. kurstaki EG 2348 (L.3.11), B. t. ssp. kurstaki SB4 (L.3.12), B. t. ssp. kurstaki ABTS-351 (HD-1) (L.3.13), Beauveria bassiana ATCC 74040 (L.3.14), B. bassiana GHA (L.3.15), B. bassiana H123 (L.3.16), B. bassiana DSM 12256 (L.3.17), B. bassiana PPRI 5339 (L.3.18), B. brongniartii (L.3.19), Burkholderia sp. A396 (L.3.20), Chromobacterium subtsugae PRAA4-1 (L.3.21), Cydia pomonella granulose virus V22 (L.3.22), Cydia pomonella granulose virus V1 (L.3.23), Cryptophlebia leucotreta granulovirus (CrleGV) (L.3.57 ), Flavobacterium sp. H492 (L.3.60), Helicoverpa armigera nucleopolyhedrovirus (HearNPV) (L.3.58), Isaria fumosorosea Apopka-97 (L.3.24), Lecanicillium longisporum KV42 (L.3.25), L. longisporum KV71 (L.3.26), L muscarium KV01 (L.3.27), Metarhizium anisopliae FI-985 (L.3.28), M. anisopliae FI-1045 (L.3.29), M. anisopliae F52 (L.3.30), M. anisopliae ICIPE 69 (L. 3.31), M. anisopliae var. acridum IMI 330189 (L.3.32); Nomuraea rileyi strains: SA86101 (L.3.33), GU87401 (L.3.34), SR86151 (L.3.35), CG128 (L.3.36) and VA9101 (L.3.37); Paecilomyces fumosroseus FE 9901 (L.3.38), P. lilacinus 251 (L.3.39), P. lilacinus DSM 15169 (L.3.40), P. lilacinus BCP2 (L.3.41), Paenibacillus popilliae Dutky-1940 (NRRL B- 2309 = ATCC 14706) (L.3.42), P. popilliae Dutky 1 (L.3.43), P. popilliae KLN 3 (L.3.56), Pasteuria sp. Ph3 (L.3.44), Pasteuria sp. ATCC PTA-9643 (L.3.45), Pasteuria sp. ATCC SD-5832 (L.3.46), P. nishizawae PN1 (L.3.46), P. penetrans (L.3.47), P. ramosa (L.3.48), P. sp. Pr-3 (L.3.49), P. thornea (L.3.50), P. usgae (L.3.51), Pseudomonas fluorescens CL 145A (L.3.52), Spodoptera littoralis nucleopolyhedrovirus (SpliNPV) (L.3.59), Steinernema carpocapsae (L.3.53), S. feltiae (L.3.54), S. kraussei L137 (L.3.55); (L4a) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity selected from: L-carvone (L.4.1), citral (L.4.2), acetate (E, Z) -7.9 dodecadien -1-yl (L.4.3), ethyl format (L.4.4), acetate (E, Z) -2,4-decadienoate (pear ester) (L.4.5), (Z, Z, E) -7 , 11,13- hexadecatrienal (L.4.6), heptyl butyrate (L.4.7), isopropyl myristate (L.4.8), cis-jasmine (L.4.9), lavanulil senecioate (L.4.10), 2- methyl-1-butanol (L.4.11), methyl eugenol (L.4.12), methyl jasmonate (L.4.13), ((E, Z) -2,13- octadecadien-1-ol (L.4.14) , (E, Z) -2,13-octadecadien-1-ol (L.4.15), (E, Z) -3,13-octadecadien-1-ol (L.4.16), R-1-octen -3-ol, pentatermanone (L.4.17), pentatermanone (L.4.18), potassium silicate (L.4.19), sorbitol actanoate (L.4.20), (E, Z, Z) acetate -3.8 , 11-tetradecatrienyl (L.4.21), (Z, E) - 9,12-tetradecadien-1-yl acetate (L.4.22), Z-7-tetradecen-2-one (L.4.23), Z- 9-tetradecen1-yl (L.4.24), Z-11-tetra-decennial (L.4.25), Z-11-tetradecen -1-ol (L.4.26), black wattle extract (L.4.27), grapefruit and pulp seed extract (L.4.28), Chenopodium ambrosiodes extract (L.4.29), Catnip oil (L.4.30) , Neem oil (L.4.31), Quillay extract (L.4.32), Tagetes oil (L.4.33); (L5a) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting plant growth and / or enhancing yield: Azospirillum amazonense BR 11140 (SpY2) (L.5.1), A. brasilense Ab-V5 (L.5.74), A. brasilense Ab-V6 (L.5.75), A. brasilense AZ39 (L.5.2), A. brasilense XOH (L.5.3), A. brasilense Sp245 (BR 11.005) (L.5.4 ), A. brasilense BR 11002 (L.5.5), A. lipoferum BR 11646 (Sp31) (L.5.6), A. irakense (L.5.7), A. halopraeferens (L.5.8), Bradyrhizobium sp. PNL01 (L.5.9), B. sp. (Arachis) CB1015 (L.5.10), B. sp. (Arachis) USDA 3446 (L.5.11), B. sp. (Arachis) SEMIA 6144 (L.5.12), B. sp. (Arachis) SEMIA 6462 (L.5.13), B. sp. (Arachis) SEMIA 6464 (L.5.14), B. sp. (Vigna) (L.5.15), B. elkanii SEMIA 587 (L.5.16), B. elkanii SEMIA 5019 (L.5.17), B. elkanii U-1301 (L.5.18), B. elkanii U-1302 ( L.5.19), B. elkanii USDA 74 (L.5.20), B. elkanii USDA 76 (L.5.21), B. elkanii USDA 94 (L.5.22), B. elkanii USDA 3254 (L.5.23), B japonicum 532c (L.5.24), B. japonicum CPAC 15 (L.5.25), B. japonicum E-109 (L.5.26), B. japonicum G49 (L.5.27), B. japonicum TA-11 (L .5.28), B. japonicum USDA 3 (L.5.29), B. japonicum USDA 31 (L.5.30), B. japonicum USDA 76 (L.5.31), B. japonicum USDA 110 (L.5.32), B. japonicum USDA 121 (L.5.33), B. japonicum USDA 123 (L.5.34), B. japonicum USDA 136 (L.5.35), B. japonicum SEMIA 566 (L.5.36), B. japonicum SEMIA 5079 (L. 5.37), B. japonicum SEMIA 5080 (L.5.38), B. japonicum WB74 (L.5.39), B. liaoningense (L.5.40), B. Lupini LL13 (L.5.41), B. Lupini WU425 ( L. 5.42), B. Lupini WSM471 (L.5.43), B. Lupini WSM4024 (L.5.44), Glomus intraradices RTI-801 (L.5.45), Mesorhizobium sp. WSM1271 (L.5.46), M. sp. WSM1497 (L.5.47), M. ciceri CC1192 (L.5.48), M. huakii (L.5.49), M. loti CC829 (L.5.50), M. loti SU343 (L.5.51), Rhizobium leguminosarum bv. phaseoli RG-B10 (L.5.52), R. l. bv. trifolii RP113-7 (L.5.53), R. l. bv. trifolii 095 (L.5.57), R. l. bv. trifolii TA1 (L.5.58), R. l. bv. trifolii CC283b (L.5.59), R. l. bv. trifolii CC275e (L.5.60), R. l. bv. trifolii CB782 (L.5.61), R. l. bv. trifolii CC1099 (L.5.62), R. l. bv. trifolii WSM1325 (L.5.63), R. l. bv. viciae SU303 (L.5.64), R. l. bv. viciae WSM1455 (L.5.65), R. l. bv. viciae P1NP3Cst (L.5.66), R. l. bv. viciae RG-P2 (L.5.67), R. tropici PRF 81 (L.5.68), R. tropici SEMIA 4077 (L.5.69), R. tropici CC511 (L.5.70), Sinorhizobium meliloti RCR2011 (L. 5, 71), S. meliloti NRG185 (L.5.72), S. meliloti RRI128 (L.5.73); (L6a) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or increasing the yield selected from: abscisic acid (L.6.1), aluminum silicate (kaolin) (L.6.2), 3 -decen-2-one (L.6.3), formononectin (L.6.4), genistein (L.6.5), hesperetin (L.6.6), homobrassinolide (L.6.7), humates (L.6.8), methyl jasmonate (L.6.9), cis-jasmine (L.6.10), lysophosphatidyl ethanlamine (L.6.11), naringenin (L.6.12), polymeric polyhydroxy acid (L.6.13), salicylic acid (L.6.14), extract of Ascophyllum nodosum (Norwegian kelp, Brown kelp) (L.6.15) and Ecklonia maxima extract (seaweed) (L.6.16).
[0133] [0133] According to another embodiment of the compositions of the present invention, the biopesticidal component II is Bacillus amyloliquefaciens subsp. plantarum MBI600. These compositions are especially suitable for soy vegetables.
[0134] [0134] According to another embodiment of the compositions of the present invention, the biopesticidal component II is the B. pumilus INR-7 strain (also referred to as BU-F22 (NRRL B-50153) and BU-F33 (NRRL B-50185 ; see publication WO 2012/079073). These compositions are especially suitable in soy and corn vegetables.
[0135] [0135] According to another embodiment of the compositions of the present invention, the biopesticidal component II is Bacillus simplex, preferably strain B. simplex ABU 288 (NRRL B-50340). These compositions are especially suitable for soy and corn vegetables.
[0136] [0136] According to another embodiment of the compositions of the present invention, the biopesticidal component II is selected from Trichoderma asperellum, T. atroviride, T. fertil, T. gamsii, T. harmatum; composition of T. viride and T. harziaem; composition of T. harzianum and T. polysporum; T. stromaticum, T. virens (also named Gliocladium virens) and T. viride; preferably Trichoderma fertil, in particular the T. fertil JM41R strain. These compositions are especially suitable for soy and corn vegetables.
[0137] [0137] According to another embodiment of the compositions of the present invention, the biopesticidal component II is Sphaerodes mycoparasitica, preferably the strain Sphaerodes mycoparasitica IDAC 301.008-01 (also referred to as SMCD2220-01 strain). These compositions are especially suitable for soy and corn vegetables.
[0138] [0138] According to another embodiment of the compositions of the present invention, the biopesticidal component II is Beauveria bassiana, preferably the Beauveria bassiana strain PPRI5339. These compositions are especially suitable for soy and corn vegetables.
[0139] [0139] According to another embodiment of the compositions of the present invention, the biopesticidal component II is Metarhizium anisopliae or M. anisopliae var. acridium, preferably selected from the M. anisolpiae IMI33 strain and M. anisopliae var. acridium IMI 330189. These compositions are especially suitable for soy and corn vegetables.
[0140] [0140] According to another embodiment of the compositions of the present invention, the biopesticidal component II is Bacillus firmus, preferably strain I-1592. This isolate was deposited at the Collection Nationale de Cultures de Microorganismes (CNCM), Pasteur Institute, France, on May 29, 1995 under the number CNCMI-1582.
[0141] [0141] According to another embodiment of the compositions of the present invention, Bradyrhizobium sp. (ie, all species and / or strains of Bradyrhizobium) as biopesticide II is Bradyrhizobium japonicum (B. japonicum). These compositions are especially suitable for soy vegetables. Preferably, B. japonicum is not one of the TA-11 or 532c strains. B. japonicum strains were grown using the fermentation methods and techniques known in the art, for example, in yeast extract-mannitol broth (YEM) at 27 ° C for about 5 days.
[0142] [0142] References for several strains of B. japonicum are provided, for example, in US patent 7,262,151 (strains B. japonicum USDA 110 (= IITA 2121, SEMIA 5032, RCR 3427, ARS I-110, Nitragin 61A89; isolated) Glycine max, Florida, 1959, Serogroup 110; Appl Environ Microbiol 60, 940-94, 1994), USDA 31 (= Nitragin 61A164; Glycine max isolate in Wisconsin in 1941, USA, Serogroup 31), USDA 76 ( passage of the vegetable from the USDA 74 strain that was isolated from Glycine max, in California, USA, in 1956, Serogroup 76), USDA 121 (isolated from Glycine max in Ohio, USA, in 1965), USDA 3 (isolated from Glycine max in Virginia, USA, in 1914, Serogroup 6) and USDA 136 (= CB 1809, SEMIA 586, Nitragin 61A136, RCR 3407; Glycine max isolate in Beltsville, Maryland, in 1961; Appl Environ Microbiol 60, 940-94, 1994) USDA refers to the United States Department of Agriculture Culture Collection, Beltsville, Md, USA (see, for example, Beltsville Rhizobium Culture Collection Catalog, March 198 7 ARS-30). In addition, the suitable B. japonicum G49 strain (INRA, Angers, France) is described in Fernandez-Flouret, D. & Cleyet-Marel, JC (1987) CR Acad Agric P. 73, 163-171), especially for soybeans grown in Europe, that is, in France. The most suitable B. japonicum strain TA-11 (TA11 NOD +) (NRRL B-18466) is i.a. described in US patent 5,021,076; Appl Environ Microbiol (1990) 56, 2,399-2,403 and commercially available as the inoculant liquid for soy (Vault® NP, Becker Underwood, USA). Other B. japonicum strains, such as for example, for biopesticide II are described in US patent 2012 / 0252672A. Another suitable strain, especially in commercially available Canada, is strain 532c (A Nitragin Company, Milwaukee, Wisconsin, USA, isolated from Wisconsin field; Nitragin collection No. 61A152; Can J Plant Sci 70 (1990), 661- 666).
[0143] [0143] Other suitable and commercially available B. japonicum strains (see, for example, Appl Environ Microbiol 2007, 73 (8), 2635) are SEMIA 566 (isolated from the North American inoculant in 1966 and used in commercial inoculants Brazilians 1966-1978), SEMIA 586 (= CB 1809; originally isolated in Maryland, USA, but received from Austrailia in 1966 and used in inoculants in Brazil in 1977), CPAC 15 (= SEMIA 5079, a natural variant of SEMIA 566 used in commercial inoculants since 1992) and CPAC 7 (= SEMIA 5080; a natural variant of SEMIA 586 used in commercial inoculants since 1992). These strains are especially suitable for soybeans grown in Australia or South America, especially in Brazil. Some of the strains mentioned above have been reclassified as a new species of Bradyrhizobium elkanii, for example, the strain USDA 76 (Can. J. Microbiol., 1992, 38, 501-505).
[0144] [0144] Another suitable B. japonicum and commercially available strain is E-109 (variant of the USDA 138 strain, for example, see, Eur J. Biol Soil 45 (2009) 28-35; Biol Fertil Soils (2011) 47: 81-89, deposited at the Agriculture Collection Laboratory of the Institute of Agricultural Microbiology and Zoology (IMYZA), National Institute of Agricultural Technology (INTA), Castelar, Argentina). This strain is especially suitable for soybeans grown in South America, especially in Argentina.
[0145] [0145] The present invention also relates to compositions, in which component II biopesticide is selected from Bradyrhizobium elkanii and Bradyrhizobium liaoningense (B. elkanii and B. liaoningense), most preferably from B. elkanii. These compositions are especially suitable for soy vegetables. B. elkanii and liaoningense were cultivated using the fermentation methods and techniques known in the art, for example, in yeast extract-mannitol broth (YEM) at 27º C for about 5 days.
[0146] [0146] Suitable and commercially available B. elkanii strains are SEMIA 587 and SEMIA 5019 (= 29W) (see, for example, Appl Environ Microbiol 2007, 73 (8), 2635) and USDA 3254 and USDA USDA 76 and 94 Other commercially available B. elkanii strains are U-1301 and L-1302 (for example, Nitroagin® Optimize product from Novozymes Bio Como SA, Brazil or Nitrasec for soybeans from LAGE y Cia, Brazil). These strains are especially suitable for soybeans grown in Australia or South America, especially in Brazil.
[0147] [0147] The present invention also relates to compositions, in which the biopesticidal component II is selected from Bradyrhizobium japonicum (B. japonicum) and further comprises a compound III, in which compound III is selected from jasmonic acid or their salts or derivatives including cis-jasmine, preferably methyl jasmonate or cis-jasmine.
[0148] [0148] The present invention also relates to compositions, in which biopesticide II is selected from Bradyrhizobium sp. (Arachis) (B. sp. Arachis), which should describe the miscellaneous cowpea cross-inoculation group that includes, inter alia, the indigenous cowpea nodulating bacteria in cowpea (Vigna unguiculata), sirat (Macroptilium atropurpureum), beans (Phaseolus lunatus) and peanuts (Arachis hypogaea). This mixture that comprises as biopesticide II, B. sp. arachis is especially suitable for use in peanuts, cowpea, Mung beans, Moth beans, Dune beans, rice beans, Snake beans and Creeping vigna, especially from peanuts.
[0149] [0149] The B. sp. (Arachis) suitable and commercially available is CB1015 (= IITA 1006, USDA 3446 presumably originally harvested in India, from Australian Inoculants Research Group; see, for example http://www.qaseeds.com.au/inoculant_applic.php ; Beltsville Rhizobium Culture Collection Catalog, March 1987 USDA-ARS ARS-30). These strains are especially suitable for peanuts grown in Australia, North or South America, especially in Brazil. In addition, the appropriate strain is Bradyrhizobium sp. PNL01 (Becker Underwood; ISO Rep Marita McCreary, QC Manager Padma Somasageran, Identification Of Rhizobia Species That Can Establish Nitrogen-Fixing Nodules In Crotalaria Longirostrata, April 29, 2010, University of Massachusetts Amherst.:http://www.wpi. edu / Pubs / E-project / Available / E-project-042810- 163614 / unrestricted / Bisson.Mason._Identification_of_Rhizobia_Species_That_c an_Establish_Nitrogen-Fixing_Nodules_in_Crotalia_Longirostrata.pdf).
[0150] [0150] The suitable and commercially available strains Bradyrhizobium.sp (Arachis), especially for cowpea and peanuts, but also for soybeans are Bradyrhizobium SEMIA 6144, SEMIA 6462 (= BR 3267) and SEMIA 6464 (= BR 3262) (deposited at FEPAGRO-MIRCEN, R. Gonçalves Dias, 570 Porto Alegre - RS, 90130-060, Brazil; see, for example, FEMS Microbiology Letters (2010) 303 (2), 123-131; Revista Brasileira de Ciência do Solo (2011) 35 (3); 739-742, ISSN 0100-0683).
[0151] [0151] The present invention also relates to compositions in which the biopesticidal component II is selected from Bradyrhizobium sp. (Arachis) and further comprises a compound III, wherein compound III is selected from jasmonic acid or its salts or derivatives including cis-jasmine, preferably methyl jasmonate or cis-jasmine.
[0152] [0152] The present invention also relates to compositions, in which the biopesticidal component II is selected from Bradyrhizobium sp. (Lupine) (also called B. Lupini, B. lupine or Rhizobium Lupini). This mixture is especially suitable for use on dry grains and lupins.
[0153] [0153] The suitable and commercially available B. Lupini strain is LL13 (isolated from Lupinus iuteus Nodules from French soils; deposited at INRA, Dijon and Angers, France; http://agriculture.gouv.fr/IMG/pdf/ch20060216. pdf). This strain is especially suitable for lupins grown in Australia, North America or Europe, especially in Europe.
[0154] [0154] B. Lupini strains also suitable and commercially available WU425 (isolated in Esperance, Western Australia from a non-Australian Ornthopus compressus legume), WSM4024 (isolated from lupins in Australia by CRS during a 2005 survey) and WSM471 ( isolated from Ornithopus pinnatus in Oyster Harbor, Western Australia) are described, for example, in Palta JA Berger and JB (eds), 2008, Proceedings 12th International Lupine Conference, 14-18 September 2008, Fremantle, Western Australia. International Lupine Association, Canterbury, New Zealand, 47-50, ISBN 0-86476-153- 8: http: //www.lupins.org/pdf/conference/2008/Agronomy%20and%20Production/ John% 20Howieson% 20and% 20G% 20OHara.pdf; Appl Environ Microbiol (2005) 71, 7041-7052 and Australian J. Exp. Agricult. (1996) 36 (1), 63-70.
[0155] [0155] The present invention also relates to compositions in which the biopesticidal component II is selected from Bradyrhizobium sp. (Lupine) (B. Lupini) and further comprises a compound III, in which compound III is selected from jasmonic acid or its salts or derivatives thereof including cis-jasmine, preferably methyl jasmonate or cis-jasmine .
[0156] [0156] The present invention also relates to compositions, in which the biopesticidal component II is selected from Mesorhizobium sp. (that is, any Mesorhizobium species and / or strain), most preferably Mesorhizobium Ciceri. These mixtures are particularly suitable for beans.
[0157] [0157] The M. sp. suitable and commercially available, for example, are M. ciceri CC1192 (UPM = 848, CECT 5549; from Horticulture Research Station, Gosford, Australia; harvested in Israel from Cicer arietinum nodules; Can J Microbial (2002) 48, 279-284) and the Mesorhizobium sp. WSM1271 (harvested in Sardinia, Italy, from host vegetable Biserrula pelecinus), WSM 1497 (harvested in Mykonos, Greece, from host vegetable Biserrula pelecinus), strains M. loti CC829 (commercial inoculant of Lotus pedunculatus and L ulginosus in Australia, isolated from L. ulginosus nodules in the USA) and SU343 (commercial inoculant for Lotus corniculatus in Australia; host nodule isolates in the USA) all of which are deposited in the Australian soil of Microbiology (WSM) Western culture collection, Australia and / or CSIRO (CC), Canberra, Australian Capirtal Rerritory collection (see, for example, Soil Biol Biochem (2004) 36 (8), 1,309-1,317; Plant and Soil (2011) 348 (1-2), 231- 243).
[0158] [0158] The appropriate and commercially available M. Loti strains, for example, are M. CC829 Loti for Lotus pedunculatus.
[0159] [0159] The present invention also relates to compositions in which the biopesticidal component II is selected from Bradyrhizobium sp. (Lupine) (B. Lupini) and further comprises a compound III, in which compound III is selected from jasmonic acid or its salts or derivatives thereof including cis-jasmine, preferably methyl jasmonate or cis-jasmine .
[0160] [0160] The present invention also relates to compositions in which the biopesticidal component II is selected from Mesorhizobium huakuii, also referred to as Rhizobium huakuii (see, for example, Appl. Environ. Microbiol. 2011, 77 (15), 5,513 -5,516). These mixtures are particularly suitable in Astralagus, for example, Astalagus sinicus (Chinese milkwetch), Thermopsis, for example, Thermopsis luinoides (Goldenbanner) and the like.
[0161] [0161] The suitable and commercially available M. huakuii strain is HN3015 which was isolated from Astralagus sinicus in a rice growing field in southern China (see, for example, Mundial J. Microbiol. Biotechn. (2007) 23 (6 ), 845-851, ISSN 0959-3993).
[0162] [0162] The present invention also relates to compositions in which the biopesticidal component II is selected from Mesorhizobium huakuii and further comprises a compound III, in which compound III is selected from jasmonic acid or salts or their derivatives including cis-jasmine, preferably methyl jasmonate or cis jasmine.
[0163] [0163] The present invention also relates to compositions, in which the biopesticidal component II is selected from Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, most preferably from A brasilense, in particular, selected from the strains A. brasilense BR 11005 (SP 245) and AZ39 that are used commercially in Brazil and are obtained from EMBRAPA, Brazil. These compositions are especially suitable for soy vegetables.
[0164] [0164] Humates are humic and fulvic acids extracted from a form of lignite coal and clay, known as leonardite. Humic acids are organic acids that occur in humus and other organically derived materials such as peat and certain soft charcoal. They have been shown to increase phosphate fertilizer efficiency and micronutrient absorption by plants, as well as assist in the development of the plant's root system.
[0165] [0165] Jasmine acid, its salts (jasmonates) or derivatives include, without limitation, potassium, sodium, lithium, ammonium, dimethylammonium, isopropylammonium, diolammonium and dietriethanolammonium; and also the methyl ester of jasmonic acid, amide of jasmonic acid, methylamide of jasmonic acid, jasmonic acid of L-amino acid (with amide bond) conjugates (for example, conjugated with L-isoleucine, L-valine, L-leucine or L-phenylalanine), 12-oxo-phytodienic acid, coronatine, coronafacoyl-L-serine, coronafacoyl-L-threonine, 1-oxo-indanoyl-isoleucine methyl esters, 1-oxo-indanoyl-leucine methyl esters , cis-jasmine, linoleic acid or its derivatives, and combinations of any of the above.
[0166] - proteína de harpina, laminarina, ácido jasmônico (II-43) ou seus sais ou seus derivados, laminarina, óleo de peixe Menhaden, natamicina, proteína revestida do vírus Plum pox, bicarbonato de potássio ou de sódio, ácido salicílico, óleo da árvore do chá; (Lc) Pesticidas microbianos com atividade inseticida, acaricida, moluscidal e/ou nematicida selecionados a partir de: - Agrobacterium radiobacter, Bacillus cereus, Bacillus firmus (II44), B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana (II-45), Beauveria brongniartii, Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulosis virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (antigo Verticillium lecanii), Metarhizium anisopliae (II-46), M. anisopliae var. anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. reneformis, P. thornea, P. usagae, Pseudomonas fluorescens, Pseudomonas putida, Steinernema feltiae, Steinernema kraussei, Streptomces galbus, Streptomyces microflavus; (Ld) Pesticidas bioquímicos com atividade inseticida, acaricida, moluscidal, feromona e/ou nematicida selecionados a partir de: - L-carvona, citral, acetato de (E,Z)-7,9 dodecadien-1-il, formato de etila, acetato (E,Z)-2,4-decadienoato (éster pêra), (Z,Z,E)-7,11,13- hexadecatrienal, butirato de heptila, miristato de isopropila, senecioato de lavanulil, 2-metil-1-butanol, eugenol de metila, jasmonato de metila, (E,Z)-2,13- octadecadien-1-ol, acetato (E,Z)-2,13-octadecadien-1-ol, (E,Z)-3,13- octadecadien-1-ol, R-1-octen-3-ol, pentatermanona, silicato de potássio, actanoato de sorbitol, acetato (E,Z,Z)-3,8,11-tetradecatrienila, acetato (Z,E)- 9,12-1-tetradecadien-il, Z-7-tetradecen-2-ona, acetato Z-9-tetradecen-1-il, Z-11- tetradecenal, Z-11-tetradecen-1-ol, extrato de acácia negra, extrato das sementes de toranja e polpa, extrato de Chenopodium ambrosiodae, óleo Catnip, óleo de Neem, extrato de Quillay, óleo Tagetes (II-47); (Le) Pesticidas microbianos com a atividade de redução da tensão do vegetal, reguladora de crescimento, promotora de crescimento dos vegetais e/ou de intensificação do rendimento selecionados a partir de: - Azospirillum amazonense, A. brasilense (II-48), A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp. (II-49), B. japonicum (II-50), B. elkanii, B. lupini, B. liaoningense, Delftia acidovorans, Glomus intraradices, Mesorhizobium sp. (II-51), M. ciceri, M. huakii, M. loti, Paenibacillus alvei, Penicillium bilaiae (II-52), Rhizobium leguminosarum bv. phaseoli (II-53), R. l. trifolii, R. l. bv. viciae (II-54), R. tropici, Sinorhizobium meliloti (II-55); (Lf) Pesticidas bioquímicos com a atividade de redução da tensão do vegetal, reguladora de crescimento e/ou de intensificação do rendimento selecionados a partir de: - ácido abscísico, silicato de alumínio (caulino), 3-decen-2-ona, homobrassinolídeo, humatos, indol-3-acético, etanolamina de lisofosfatidila, ácido poliidróxi polimérico, extrato de Ascophyllum nodosum (alga marinha norueguesa, alga marinha marrom) e extrato de Ecklonia maxima (alga). [0166] According to another embodiment of the present invention, the biopesticidal component II is selected from the groups: (La) Microbial pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity selected from: Bacillus altudinis, Bacillus amyloliquefaciens, Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27), B. amyloliquefaciens ssp. plantarum D747, B. megaterium, B. mojavensis (II-28), B. mycoides, B. pumilus INR-7 (II-29), B. pumilus GHA 180, B. simplex (II-30), B. solisalsi (II-31), Bacillus subtilis, Burkholderia sp., Clavibacter michiganensis (bacteriophages) (II-32), Gliocladium roseum (II-33), Microsphaeropsis ochracea, Muscodor albus, Paenibacillus alvei, Paenibacillus polymyxa (II-34), Panto agglomerans (II-35), Pantoea vagans, Penicillium bilaiae, Pseudomonas sp., Pseudomonas chloraphis, P. fluorescens, Sphaerodes mycoparasitica (II-36), Streptomyces lydicus (II-37), S. violaceusniger (II-38), Trichoderma fertile JM41R (II-39), Typhula phacorrhiza (II-40), Verticillium dahlia (II-42), yellow mosaic zucchini virus (non-virulent strain); (Lb) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or plant defense activating activity selected from: - harpin protein, laminarin, jasmonic acid (II-43) or its salts or derivatives, laminarin, Menhaden fish oil, natamycin, Plum pox virus coated protein, potassium or sodium bicarbonate, salicylic acid, tree oil tea; (Lc) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity selected from: - Agrobacterium radiobacter, Bacillus cereus, Bacillus firmus (II44), B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana (II-45), Beauveria brongniartii, Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulosis virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (former Verticillium lecanii), 46 anisopliae var. anisopliae, M. anisopliae var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus popilliae, Pasteuria spp., P. nishizawae, P. reneformis, P. thornea, P. usagae, Pseudomonas fluorescens, Pseudomonas putida, Steinernema feltiae, Steinernema microfilm, Streptom streustre, (Ld) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity selected from: - L-carvone, citral, (E, Z) -7,9 dodecadien-1-yl acetate, ethyl format, acetate (E, Z) -2,4-decadienoate (pear ester), (Z, Z, E) -7,11,13- hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulyl senecioate, 2-methyl-1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13- octadecadien -1-ol, acetate (E, Z) -2,13-octadecadien-1-ol, (E, Z) -3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, acetate (E, Z, Z) -3,8,11-tetradecatrienyl, acetate (Z, E) - 9,12-1-tetradecadien-il, Z-7-tetradecen-2- one, Z-9-tetradecen-1-yl, Z-11-tetradecenal, Z-11-tetradecen-1-ol acetate, black wattle extract, grapefruit and pulp seed extract, Chenopodium ambrosiodae extract, Catnip oil, Neem oil, Quillay extract, Tagetes oil (II-47); (Le) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth, promoting growth of plants and / or enhancing yield selected from: - Azospirillum amazonense, A. brasilense (II-48), A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp. (II-49), B. japonicum (II-50), B. elkanii, B. lupini, B. liaoningense, Delftia acidovorans, Glomus intraradices, Mesorhizobium sp. (II-51), M. ciceri, M. huakii, M. loti, Paenibacillus alvei, Penicillium bilaiae (II-52), Rhizobium leguminosarum bv. phaseoli (II-53), R. l. trifolii, R. l. bv. viciae (II-54), R. tropici, Sinorhizobium meliloti (II-55); (Lf) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or intensifying the yield selected from: - abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, homobrassinolide, humates, indole-3-acetic, lysophosphatidyl ethanolamine, polymeric polyhydroxy acid, Ascophyllum nodosum extract (Norwegian seaweed, brown seaweed) and extract of Ecklonia maxima (seaweed).
[0167] [0167] In another embodiment, (La) to Lf) are defined as follows from (La.1) to (Lf.1)): (La.1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or activating defense of the selected vegetables from: Bacillus amyloliquefaciens MBI 600 (II-27), B. mojavensis (II-28), B. pumilus INR -7 (II29), B. simplex (II-30), B. solisalsi (II-31), Clavibacter michiganensis (bacteriophages) (II-32), Gliocladium roseum (II-33), Paenibacillus polymyxa (II34), Pantoea agglomerans (II-35), Sphaerodes mycoparasitica (II-36), Streptomyces lydicus (II-37), S. violaceusniger (II-38), Trichoderma fertil JM41R (II-39), Typhula phacorrhiza (II-40), Ulocladium edema (II-41), Verticillium dalia (II-42), yellow mosaic zucchini virus (non-virulent strain); (Lb.1) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or activating defense of the selected vegetables from jasmonic acid (II-43) or salts or derivatives, laminarin, Menhaden fish oil, natamycin, protein coated Plum virus, Reynoutria sachlinensis extract, salicylic acid, tea tree oil; (Lc.1) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematocidal activity selected from: Bacillus firmus (II-44), B. thuringiensis ssp. israelensis, B. t. ssp. galleriae, B. t. ssp. kurstaki, Beauveria bassiana (II-45), Burkholderia sp., Chromobacterium subtsugae, Cydia pomonella granulose virus, Isaria fumosorosea, Lecanicillium longisporum, L. muscarium (formerly Verticillium lecanii), Metarhizium anisopliae (II-46), var. acridum, Paecilomyces fumosoroseus, P. lilacinus, Paenibacillus poppiliae, Pasteuria spp, P. nishizawae, P. reneformis, P. usagae, Pseudomonas fluorescens, Steinernema feltiae, Streptomces galbus; (Ld.1) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity selected from: L-carvone, citral, acetate (E, Z) -7,9-dodecadien-1-il, ethyl, (E, Z) -2,4-ethyl (pear ester) decadienoate, (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, lavanulil senecioate, 2- methyl-1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) -2,13-octadecadien-1-ol, (E, Z ) -3,13-octadecadien-1-ol, octen-1-R-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) -3,8,11-tetradecatrienyl actanoate, (Z, E) -9,12-1-tetradecadien-yl acetate, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z-11- tetradecen-1-ol, Black wattle extract, grapefruit and pulp seed extract, Chenopodium ambrosiodae extract, catnip oil, Neem oil, extract Quillay (II-47), Tagetes oil; (Le.1) Microbial pesticides with the activity of reducing the tension of the plant, regulating growth and / or intensifying the yield selected from: Azospirillum amazonense, A. brasilense (II-48), A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp. (II-49), B. japonicum (II-50), Glomus intraradices, Mesorhizobium sp. (II-1), Paenibacillus alvei, Penicillium bilaiae (II-52), Rhizobium leguminosarum bv. phaseolii (II-53), RL trifolii, R. l. bv. viciae (II-54), Sinorhizobium meliloti (II-55); (Lf.1) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or enhancing the yield of vegetables, selected from: abscisic acid, aluminum silicate (kaolin), 3-decen-2 -one, homobrassinlide, humates, indole-3-acetic acid, lysophosphatidyl ethanlamine, polymeric polyhydroxy acid, Ascophyllum nodosum extract (Norwegian kelp, brown kelp) and Ecklonia maxima extract (seaweed).
[0168] [0168] According to an embodiment of the mixtures of the present invention, component (2) is a biopesticide II from the groups from (D) to (I) selected from: (La-1) Microbial pesticides with fungicidal, bactericidal, viricidal and / or vegetable activating activity: Bacillus altitudinis 41KF2b, Bacillus amyloliquefaciens AP-136, B. amyloliquefaciens AP-188, B. amyloliquefaciens AP-218, B. amyloliquefaciens AP-219, B. amyloliquefaciens AP-295, B. amyloliquefaciens IN937a, B. amyloliquefaciens IT-45, B. amyloliquefaciens ssp. plantarum D747, B. amyloliquefaciens ssp. plantarum MBI600 (NRRL B-50595), B. amyloliquefaciens ssp. plantarum TJ1000, B. mojavensis AP 209, B. mycoides AQ726, strain B. mycoides J, B. pumilus INR7, B. pumilus GHA 180, B. simplex ABU 288, B. solisalsi AP 217, B. subtilis CX9060, B. subtilis FB17, B. subtilis GB07, Clavibacter michiganensis (bacteriophages), Gliocladium roseum 321U, Microsphaeropsis ochracea P130A, Muscodor albus QST 20799, Muscodor albus SA-13, Paenibacillus alvei NAS6Ganto, Paenibacillus Eglea P133 , Penicillium bilaiae ATCC 22348, P. bilaiae ATCC 20851, Penicillium bilaiae ATCC 18309, Phlebiopsis gigantea, Pichia anomala WRL-76, Pseudomonas sp. Proradix, Pseudomonas chloraphis MA 342, P. fluorescens A506, P. fluorescens CL 145A, P. fluorescens NCIB 12089, P. fluorescens Pf-5, P. fluorescens WCS 374, P. fluorescens ATCC 13525, P. fluorescens CHA0, P. putida ATCC 202153, Sphaerodes mycoparasitica SMCD2220, S. lydicus WYEC 108, S. violaceusniger XL-2, S. violaceusniger YCED-9, Trichoderma fertile JM41R, Typhula phacorrhiza 94671, Verticillium dahlia, yellow squash virus (yellow mosaic zucchini) ; (Lb-1) Biochemical pesticides with fungicidal, bactericidal, viricidal and / or vegetable activating activity: harpine protein, laminarin, Menhaden fish oil, natamycin, Plum pox virus coated protein, potassium or sodium bicarbonate, acid salicylic, tea tree oil; (Lc-1) Microbial pesticides with insecticidal, acaricidal, molluscidal and / or nematicidal activity: Agrobacterium radiobacter K1026, A. radiobacter K84, Bacillus firmus I-1582; B. thuringiensis ssp. aizawai: ABTS-1857, SAN 401 I, ABG-6305 and ABG-6346; B. t. ssp. israelensis AM65-52, B. t. ssp. israelensis SUM-6218, B. t. ssp. galleriae SDS-502, B. t. ssp. kurstaki EG 2348, B. t. ssp. kurstaki SB4, B. t. ssp. kurstaki ABTS-351 (HD-1), Beauveria bassiana ATCC 74040, B. bassiana GHA, B. bassiana H123, B. bassiana DSM 12256, B. bassiana PPRI 5339, B. brongniartii, Burkholderia sp. A396, Chromobacterium subtsugae PRAA4-1, Cydia pomonella granulosis virus V22, Cydia pomonella granulosis virus V1, Cryptophlebia leucotreta granulovirus (CrleGV), Flavobacterium sp. H492, Nucopolihedrovirus Helicoverpa armigera (HearNPV), Isaria fumosorosea Apopka-97, Lecanicillium longisporum KV42, L. longisporum KV71, L. muscarium KV01, Metarhizium anisopliae FI-985, M. anisopliae FI-1045ia M. anpl, E. anisopl. ICIPE 69, M. anisopliae var. acridum IMI 330189; Nomuraea rileyi strains: SA86101, GU87401, SR86151, CG128 and VA9101; Paecilomyces fumosoroseus FE 9901, P. lilacinus 251, P. lilacinus DSM 15169, P. lilacinus BCP2, Paenibacillus popilliae Dutky-1940 (NRRL B-2309 = ATCC 14706), P. popilliae Dutky 1, P. popilliae KLN 3, Pasteuria sp . Ph3, Pasteuria sp. ATCC PTA-9643, Pasteuria sp. ATCC SD-5832, P. nishizawae Pn1, P. penetrans, P. ramosa, P. sp. Pr-3, P. thornea, P. usgae, Pseudomonas fluorescens CL 145A, nucleopolyhedrovirus Spodoptera littoralis (SpliNPV), Steinernema carpocapsae, S. feltiae, S. kraussei L137; (Ld-1) Biochemical pesticides with insecticidal, acaricidal, molluscidal, pheromone and / or nematicidal activity: L-carvone, citral, acid (E, Z) -7.9 dodecadien-1-yl-ethyl, ethyl format, ( E, Z) -2,4-ethyl decadienoate (pear ester), (Z, Z, E) -7,11,13-hexadecatrienal, heptyl butyrate, isopropyl myristate, cis-jasmine, lavanulil senecioate, 2 -methyl-1-butanol, methyl eugenol, methyl jasmonate, (E, Z) -2,13-octadecadien-1-ol, (E, Z) acetate - 2,13-octadecadien-1-ol, ( E, Z) -3,13-octadecadien-1-ol, R-1-octen-3-ol, pentatermanone, potassium silicate, sorbitol actanoate, (E, Z, Z) acetate - 3,8,11 -tetradecatrienyl, (Z, E) -9,12-tetradecadien-1-yl, Z-7-tetradecen-2-one, Z-9-tetradecen-1-yl acetate, Z-11-tetradecenal, Z -11- tetradecen-1-ol, black wattle extract, grapefruit and cellulose seed extract, Chenopodium ambrosiodes extract, catnip oil, Neem oil, Quillay extract, Tagetes oil; (Le-1) Microbial pesticides with the activity of reducing plant tension, regulating growth, promoting plant growth and / or enhancing yield: Azospirillum amazonense BR 11140 (SpY2), A. brasilense Ab-V5, A brasilense Ab-V6, A. brasilense AZ39, A. brasilense XOH, A. brasilense Sp245 (BR 11005), A. brasilense BR 11002, A. lipoferum BR 11646 (Sp31), A. irakense, A. halopraeferens, Bradyrhizobium sp . PNL01, B. sp. (Arachis) CB1015, B. sp. (Arachis) USDA 3446, B. sp. (Arachis) SEMIA 6144, B. sp. (Arachis) SEMIA 6462, B. sp. (Arachis) SEMIA 6464, B. sp. (Vigna), B. elkanii SEMIA 587, B. elkanii SEMIA 5019, B. elkanii U1301, B. elkanii U-1302, B. elkanii USDA 74, B. elkanii USDA 76, B. elkanii USDA 94, B. elkanii USDA 3254, B. japonicum 532c, B. japonicum CPAC 15, B. japonicum E-109, B. japonicum G49, B. japonicum TA-11, B. japonicum USDA 3, B. japonicum USDA 31, B. japonicum USDA 76, B. japonicum USDA 110, B. japonicum USDA 121, B. japonicum USDA 123, B. japonicum USDA 136, B. japonicum SEMIA 566, B. japonicum SEMIA 5079, B. japonicum SEMIA 5080, B. japonicum SEMIA 5080, B. japonicum WB74, B. liaoningense , B. lupini LL13, B. lupini WU425, B. lupini WSM471, B. lupini WSM4024, Glomus intraradices RTI-801, Mesorhizobium sp. WSM1271, M. sp. WSM1497, M. ciceri CC1192, M. huakii, M. loti CC829, M. loti SU343, Rhizobium leguminosarum bv. phaseoli RG-B10, R. l. bv. trifolii RP113-7, R. l. bv. trifolii 095, R. l. bv. trifolii TA1, R. l. bv. trifolii CC283b, R. l. bv. trifolii CC275e, R. l. bv. trifolii CB782, R. l. bv. trifolii CC1099, R. l. bv. trifolii WSM1325, R. l. bv. viciae SU303, R. l. bv. viciae WSM1455, R. l. bv. viciae P1NP3Cst, R. l. bv. viciae RG-P2, R. tropici PRF 81, R. tropici SEMIA 4077, R. tropici CC511 (L.5.70), Sinorhizobium meliloti RCR2011, S. meliloti NRG185, S. meliloti RRI128; (Lf-1) Biochemical pesticides with the activity of reducing the tension of the plant, regulating growth and / or intensifying the yield: abscisic acid, aluminum silicate (kaolin), 3-decen-2-one, formononetine, genistein, hesperetin, homobrassinolide, humates, methyl jasmonate, cis-jasmine, lysophosphatidylcholine ethanlamine, naringenin, polymeric polyhydroxy acid, salicylic acid, Ascophyllum nodosum extract (Norwegian seaweed, brown kelp) and Eckonia extract.
[0169] [0169] Preference is also given to compositions comprising as biopesticide component II a group biopesticide (La), preferably selected from Bacillus amyloliquefaciens at present, even more preferably, from strains AP-136, AP- 188, AP-218, AP219, AP-295, IN937a, IT-45; B. amyloliquefaciens ssp. plantarum at present, even more preferably, from strains MBI600, D747 and TJ1000; B. mojavensis AP-209; B. pumilus GHA 180 and INR-7; B. simplex in the present, most preferably, the ABU 288 strain; B. solisalsi in the present, most preferably, the strain AP-217; B. subtilis at present, even more preferably, selected from strains CX-9060, FB17 and GB07; Albus Muscodor at present, most preferably, the strains QST 20799 and SA-13; Paenibacillus alvei in the present, most preferably the strain NAS6G6, Paenibacillus polymyxa in the present, most preferably the strain PKB1, Penicillium bilaiae in the present, even more preferably, the strains ATCC 22348, ATCC 20581 and ATCC 18309; Pseudomonas fluorescens in the present, most preferably, the A506 strain; Sphaerodes mycoparasitica at present, most preferably, the strain SMCD2220; Trichoderma fertil in the present, most preferably, the JM41R strain.
[0170] [0170] Preference is also given to compositions that comprise as biopesticide component II a group biopesticide (La), even more preferably, selected from B. amyloliquefaciens AP188, B. amyloliquefaciens ssp. plantarum MBI600, B. pumilus INR-7, B. simplex ABU 288, B. subtilis FB17, Paenibacillus alvei NAS6G6 and Trichoderma fertil JM41R.
[0171] [0171] According to one embodiment of the compositions of the present invention, at least one biopesticidal component II is Bacillus amyloliquefaciens ssp. plantarum MBI600. These mixtures are especially suitable. These compositions are especially suitable for soy vegetables.
[0172] [0172] According to another embodiment of the compositions of the present invention, at least one biopesticidal component II is B. pumilus INR-7. These compositions are especially suitable for soy and corn vegetables.
[0173] [0173] According to another embodiment, at least one biopesticidal component II is Bacillus simplex, preferably B. simplex ABU 288. These compositions are especially suitable in soy and corn vegetables.
[0174] [0174] According to another embodiment, at least one component II biopesticide is Bacillus subtilis, preferably the strain Bacillus subtilis FB17.
[0175] [0175] According to an embodiment of the compositions of the present invention, at least one biopesticidal component II is selected from Bacillus amyloliquefaciens AP-136, B. amyloliquefaciens AP-188, B. amyloliquefaciens AP-218, B. amyloliquefaciens AP -219, AP B. amyloliquefaciens -295, B. amyloliquefaciens ssp. plantarum TJ1000, B. amyloliquefaciens ssp. plantarum D747, B. amyloliquefaciens ssp. plantarum MBI600, B. mojavensis AP-209, B. pumilus INR-7, B. pumilus GHA 180, B. simplex ABU 288, B. solisalsi AP-217, B. subtilis CX-9060, B. subtilis FB17 and B. subtilis GB07. These compositions are especially suitable for soy and corn vegetables, especially for seed treatment.
[0176] [0176] According to another embodiment, at least one biopesticidal component II is selected from Streptomyces sp., Preferably from S. griseoviridis, S. violaceusniger and S. lydicus, in particular, from strains S. griseoviridis K61, S. lydicus WYEC 108, S. violaceusniger XL-2 and S. violaceusniger YCED-9.
[0177] [0177] According to another embodiment, at least one biopesticidal component II is selected from Pseudomonas spp., Preferably selected from P. chloraphis at present, even more preferably, the strain MA 342 and Pseudomonas sp. DSM 13134; P. fluorescens, most preferably, at present selected from strains A506, WCS 374 and Pf-5; and P. putida, most preferably, in the present strain ATCC 202153.
[0178] [0178] The present invention also relates to compositions in which at least one biopesticidal component II is selected from the fungal species Muscodor albus, preferably from the strains SA-13 and QST 20799, which are especially suitable for the treatment of soil and seeds against pathogens contained in the soil and / or nematodes.
[0179] [0179] Preference is also given to compositions comprising component II biopesticide, a biopesticide from the group (Lb), preferably selected from methyl jasmonate, cis-jasmine, laminarine, Reynoutria sachalinensis extract and tree oil. tea; even more preferably, methyl jasmonate, cis-jasmine and laminarin.
[0180] [0180] Preference is also given to compositions comprising as component II biopesticide a group biopesticide (Lc), preferably selected from Agrobacterium radiobacter, preferably in the present strain K1026, Bacillus firmus, preferably in the present the I-1582 strain, Bacillus thuringiensis ssp. kurstaki, preferably in the present strain SB4, Beauveria bassiana, preferably in the present, selected from strains GHA, H123, DSM 12256 and PPRI 5339; Burkholderia sp. and, preferably, at present the strain A396, Metarhizium anisopliae var. acridum, preferably in the present strain IMI 330189, M. anisopliae, preferably in the present, selected from strains FI-985, FI-1045, F52 and ICIPE 69; Paecilomyces lilacinus, preferably at present a selected from strains 251, DSM 15169 and BCP2, Paenibacillus popilliae, preferably at present a, selected from strains Dutky 1940, KLN 3 and Dutky 1; Pasteuria nishazawa and, preferably, the PN1 strain at present.
[0181] [0181] Preference is also given to compositions that comprise, as component II, biopesticide a group biopesticide (Lc), even more preferably, from Bacillus thuringiensis ssp. kurstaki SB4, B. bassiana DSM 12256, B. bassiana PPRI 5339, Metarhizium anisopliae var. acridum IMI 330189, M. anisopliae FI-985, M. anisopliae FI-1045, Paecilomyces lilacinus DSM 15169, P. lilacinus BCP2, P. lilacinus 251, Paenibacillus popilliae Dutky-1940, P. popilliae KLN 3 and P. popilliae Dutky 1 .
[0182] [0182] According to another embodiment, at least one component II biopesticide is Beauveria brongniartii.
[0183] [0183] According to another embodiment, at least one component II biopesticide is Metarhizium anisopliae or M. anisopliae var. Acridium is preferably selected only from M. anisopliae FI-1045, M. anisopliae F52, M. anisopliae var. acridum strains FI-985 and IMI 330189; in particular, the IMI 330189 strain. These compositions are especially suitable for the control of arthropod pests in soy and corn plants.
[0184] [0184] According to another embodiment, at least one biopesticidal component II is the reference Lecanicillium sp., Selected from Lecanicillium longisporum KV42, L. longisporum KV71 and L. muscarium KV01.
[0185] [0185] According to another embodiment, at least one component II biopesticide is Paecilomyces fumosoroseus, preferably the FE 9901 strain, especially for the control of the whitefly.
[0186] [0186] According to another embodiment, at least one biopesticidal component II is selected from Nomuraea rileyi, preferably to strains SA86101, GU87401, SR86151, CG128 and VA9101; P. lilacinus and, preferably, strains 251, DSM 15169 or BCP2, in particular BCP2, in particular, strains that control the growth of pathogenic plant nematodes.
[0187] [0187] According to another embodiment, at least one component II biopesticide is Bacillus firmus, preferably the spores of the strain CNCM I-1582, preferably useful for the treatment of soybean and corn seeds against nematodes and insects.
[0188] [0188] According to another embodiment, at least one biopesticidal component II is Bacillus cereus, preferably CNCM I-1562 spores, preferably useful for treating soybean and corn seeds against nematodes and insects.
[0189] [0189] According to another embodiment, at least one biopesticidal component II is a spore composition of B. firmus and B. cereus, preferably the spores of the strain compositions mentioned above CNCM I-1582 and CNCM I- 1562, preferably useful for the treatment of soybean and corn seeds against nematodes and insects.
[0190] [0190] According to another embodiment, at least one biopesticidal component II is selected from Bacillus t. ssp. kurstaki, preferably from strains EG 2348, SB4 and ABTS-351 (HD-1), in particular, from B. t. ssp. kurstaki SB4. These strains are used to control lepidopteran larvae, but without noctuidae.
[0191] [0191] According to one embodiment of the compositions of the present invention, at least one biopesticidal component II is selected from Bacillus firmus CNCM I-1582, Paecilomyces lilcinus 251, Pasteuria Nishizawa PN1 and Burkholderia sp. A396 with nematicidal, acaricidal and / or insecticidal activity. These compositions are especially suitable for soy and corn vegetables, especially for seed treatment.
[0192] [0192] Preference is also given to compositions comprising as biopesticide component II a biopesticide from the group (Ld), preferably selected from methyl jasmonate, Black wattle extract, grapefruit and pulp seed extract, Nepenta oil, neem oil, Quillay extract and Tagetes oil, in particular, methyl jasmonate or water-based Quillay extract.
[0193] [0193] Preference is also given to compositions that comprise as biopesticide component II a biopesticide from the group (Le), preferably selected from Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense, A. halopraeferens, Bradyrhizobium sp. (Arachis), Bradyrhizobium sp. (Vigna), B. elkanii, B. japonicum; Paenibacillus alvei, Penicillium bilaiae, Rhizobium leguminosarum bv. phaseoli, R. l. bv. trifolii, R. l. bv. viciae, and Sinorhizobium meliloti.
[0194] [0194] Preference is also given to compositions that comprise as biopesticide component II a biopesticide from the group (Le) selected from Azospirillum amazonense SpY2, A. brasilense XOH, A. brasilense Sp245, A. brasilense Cd, A. brasilense Ab- V5, A. brasilense Ab- V6, A. lipoferum Sp31, Bradyrhizobium sp. (Vigna) PNL1, B. elkanii SEMIA 587, B. elkanii SEMIA 5019, B. japonicum SEMIA 5079, B. japonicum SEMIA 5080, B. japonicum TA-11, B. japonicum 532c, Paenibacillus alvei NAS6G6, Peniciillium bilaiae strains ATCC 18309 , ATCC 20851 and ATCC 22348; Rhizobium leguminosarum bv. phaseoli RG-B10, R. l. bv. viciae P1NP3Cst, R. l. bv. viciae RG-P2, R. l. bv. trifolii RP113-7, R. l. bv. viciae SU303, R. l. bv. viciae WSM1455, R. tropici SEMIA 4077, R. tropici PRF 81 and Sinorhizobium meliloti; even more preferred, selected from Azospirillum brasilense Sp245, Bradyrhizobium sp. (Vigna) PNL1, B B. elkanii SEMIA 587, B. elkanii SEMIA 5019, B. japonicum SEMIA 5079, B. japonicum SEMIA 5080, B. japonicum TA-11 and B. japonicum 532c.
[0195] [0195] The present invention also relates to compositions, in which at least one biopesticide II is selected from Azospirillum amazonense, A. brasilense, A. lipoferum, A. irakense and A. halopraeferens, most preferably, from A. brasilense, in particular, selected from strains A. brasilense Sp245 and AZ39 that are used commercially in Brazil and are obtained from EMBRAPA-Agribiologia, Brazil and the strains Ab-V5 and AbV6; in special compositions of these strains Ab-V5 and Ab-V6. These compositions are especially suitable in soy vegetables, especially in seed treatment.
[0196] [0196] The present invention also relates to compositions in which at least one biopesticidal component II is selected from A. amazonense, A. brasilense, A. lipoferum, A. and A. halopraeferens irakense, most preferably A brasilense, and still comprises a pesticide III, in which pesticide III is selected from jasmonic acid, its salts and derivatives, preferably methyl jasmonate or cis-jasmine.
[0197] [0197] According to another embodiment of the compositions of the present invention, Bradyrhizobium spp. (ie, all species and / or strains of Bradyrhizobium) as component II is biopesticide B. japonicum. These compositions are especially suitable for soy vegetables. Certain B. japonicum strains have been reclassified as a new B. elkanii species, for example, the USDA 76 strain (Can. J. Microbiol. 38, 501- 505, 1992). Bradyrhizobium spp. they are grown using the fermentation methods and techniques known in the art, for example, in yeast extract-mannitol broth (YEM) at 27 ° C for about 5 days.
[0198] [0198] The present invention also relates to compositions, in which at least one biopesticidal component II is selected from Bradyrhizobium spp., Even more preferably, from B. sp. (Arachis), B. elkanii, B. japonicum, B. liaoningense and B. lupini, and also comprises a pesticide III (component 3), in which pesticide III is selected from jasmonic acid, its salts and derivatives, preferably, methyl jasmonate or cis-jasmine.
[0199] [0199] Preferably, B. japonicum is selected from strains E-109, SEMIA 5079, SEMIA 5080, TA-11 and 532c. According to another embodiment, mixtures of B. japonicum TA-11 and 532c or B. japonicum SEMIA 5079 and 5080 strains are used. Strains with a SEMIA prefix are especially suitable for soybeans grown in Australia or South America, especially in Brazil. Most preferably, mixtures of B. japonicum SEMIA 5079 and SEMIA 5080 are used. B. japonicum WB74 is especially suitable for soybeans grown in South America and Africa, especially in South Africa. The E-109 strain is especially suitable for soybeans grown in South America, especially in Argentina.
[0200] [0200] The present invention also relates to compositions, in which at least one component biopesticide II is selected from B. japonicum and further comprises a pesticide III, in which pesticide III is selected from jasmonic acid, their salts and derivatives, preferably methyl-jasmonate or cis-jasmine.
[0201] [0201] The present invention also relates to compositions, in which at least one biopesticidal component II is selected from Bradyrhizobium elkanii and Bradyrhizobium liaoningense, preferably from B. elkanii, more preferably, B. elkanii SEMIA 587 and SEMIA 5019; in particular, mixtures of both. These mixtures are especially suitable for soybeans in Australia or South America, especially in Brazil.
[0202] [0202] The present invention also relates to compositions, in which at least one biopesticidal component II is selected from Bradyrhizobium sp. (Arachis) and B. sp. (Vigna), which should describe the miscellaneous cross-inoculation group of cowpea which, inter alia, includes the nodulating indigenous cowpea bacteria in cowpea (Vigna unguiculata), siratro (Macroptilium atropurpureum), fava bean (Phaseolus lunatus) and peanuts (Arachis hypogaea), especially in the B. sp. (Vigna) NLP1. This mixture comprising B. sp. (Arachis) or B. sp. (Vigna) is especially suitable for use on peanuts, cowpea, Mung beans, Moth beans, Dune beans, rice beans, Snake beans and Creeping vigna, especially from peanuts.
[0203] [0203] The present invention also relates to compositions, in which at least one biopesticidal component II is selected from Bradyrhizobium sp. (Lupine) (also called B. Lupini, B. lupines or Rhizobium Lupini). These mixtures are especially suitable for use in dry grains and lupins. Preferably, B. Lupini is the LL13 strain. This strain is especially suitable for lupins that grow in Australia, North America or Europe, especially in Europe.
[0204] [0204] The present invention also relates to compositions, in which at least one biopesticidal component II is selected from Rhizobium leguminosarum bv. phaseoli especially for common bean legumes (Phaseolus vulgaris), but also for various vegetables, such as alfalfa, clover, peas, beans, lentils, soybeans, peanuts and other crops, such as corn and lettuce, most preferably, its RG-B10a R. l. bv. trifolii, in particular, its strain RP113-7, R. L. bv. viciae, in particular its strains RG-P2, SU303, WSM1455 and P1NP3Cst, in particular, P1NP3Csta R. tropici, in particular, its strains CC511, CIAT 899 and PRF 81; Sinorhizobium meliloti and, in particular, its strain RCR2011. In addition, R. l. bv. phaseoli or R. etli, for example, are known from the references mentioned above and Appl. Environ. Microbiol. 45 (3), 737-742, 1983; ibida 54 (5), 1,280-1,283, 1988.
[0205] [0205] According to another embodiment, in the compositions of the present invention, pesticide II is selected from a compound II from Sinorhizobium meliloti, most preferably from RCR2011, S. meliloti NRG185, S. meliloti RRI128, S. meliloti SU277,
[0206] [0206] R. tropici is useful for a variety of legumes, especially all types of clovers, for example, in tropical regions such as Brazil. Preferably, the mixtures comprise, as R. tropici, at least one strain selected from CC511, CIAT899, H12 and PRF 81.
[0207] [0207] The present invention also relates to compositions, in which at least one component biopesticide II is selected from R. leguminosarum bv. phaseoli, R. l. bv. trifolii, R. l. bv. viciae, R. and Sinorhizobium meliloti tropici, and also comprises a pesticide III, in which pesticide III is selected from jasmonic acid, its salts and derivatives, preferably methyl-jasmonate or cis-jasmine.
[0208] [0208] According to another embodiment, at least one component II biopesticide is selected from Delftia acidovorans, in particular the RAY209 strain, in particular, in soy vegetables and canola oil.
[0209] [0209] The user applies the composition, according to the process of the present invention, from a pre-dosing device, a backpack sprayer, a spray tank or an irrigation system. Usually, the agrochemical composition is made with water, buffer, and / or other auxiliary agents for the desired application concentration and the ready-to-use spray solution or agrochemical composition, according to the present invention, is therefore obtained . Normally, from 20 to 2,000 liters, preferably from 50 to 400 liters, of the ready-to-use spray solution are applied per hectare of the useful agricultural area.
[0210] [0210] According to one embodiment, the individual components of the composition according to the present invention, such as parts of an assembly or parts of a binary or ternary mixture can be mixed by the user himself, in a spray tank or any other type of container used for applications (for example, the seed treatment battery, seed granulating machines, backpack sprayer) and other auxiliaries can be added, if appropriate. Accordingly, an embodiment of the present invention is a kit for the preparation of a useful pesticidal composition, the kit comprises (a) a composition comprising a component I as defined herein and at least one auxiliary; and (b) a composition comprising component II as described herein and at least one auxiliary; and optionally, (c) a composition comprising at least one auxiliary and optionally another component III, as defined herein and at least one auxiliary.
[0211] [0211] The mixture of compounds I or the compositions that comprise them, in the form of use as fungicides, with other fungicides, in many cases, results in the expansion of the spectrum of fungicidal activity to be obtained or in the prevention of the development of resistance to fungicides . In addition, in many cases, synergistic effects are achieved.
[0212] [0212] The compositions of the present invention and their preferred uses are described below. In each case, according to the present invention, the use of the composition for the control of a special phytopathogenic fungus also intends to encompass the respective method for the control of phytopathogenic fungi in particular, in which the fungi or the materials, plants, soil or The seeds to be protected against the attack of fungi are treated with an effective amount of a composition as defined in this special context.
[0213] - Bacillus amyloliquefaciens MBI 600 ssp. plantarum (II-27); - B. mojavensis (II-28), - B. pumilus INR-7 (II-29); - B. simplex (II-30); - B. solisalsi (II-31); - Clavibacter michiganensis (bacteriófagos) (II-32); - Gliocladium roseum (II-33); - Paenibacillus polymyxa (II-34); - Pantoea agglomerans (II-35); - Sphaerodes mycoparasitica (II-36); - Streptomyces lvdicus (II-37); - S. violaceusniger (II-38); - Trichoderma fertil JM41R (II-39); - Typhula phacorrhiza (II-40); - Verticillium dahlia (II-42); - ácido jasmônico (II-43) ou seus sais ou seus derivados; - Bacillus firmus (II-44); - Beauveria bassiana (II-45); - Metarhizium anisopliae (II-46); - extrato de Quillay (II-47); - A. brasilense (II-48); - Bradyrhizobium sp. (II-49); - B. japonicum (II-50); - Mesorhizobium sp. (II-51); - Bilaiae Penicillium (II-52); - Rhizobium leguminosarum bv. phaseoli (II-53); - R. l. bv. viciae (II-54); e - Sinorhizobium meliloti (II-55). [0213] According to another embodiment of the present invention, the biopesticidal component II is selected from - Bacillus amyloliquefaciens MBI 600 ssp. plantarum (II-27); - B. mojavensis (II-28), - B. pumilus INR-7 (II-29); - B. simplex (II-30); - B. solisalsi (II-31); - Clavibacter michiganensis (bacteriophages) (II-32); - Gliocladium roseum (II-33); - Paenibacillus polymyxa (II-34); - Pantoea agglomerans (II-35); - Sphaerodes mycoparasitica (II-36); - Streptomyces lvdicus (II-37); - S. violaceusniger (II-38); - Trichoderma fertil JM41R (II-39); - Typhula phacorrhiza (II-40); - Verticillium dahlia (II-42); - jasmonic acid (II-43) or its salts or derivatives; - Bacillus firmus (II-44); - Beauveria bassiana (II-45); - Metarhizium anisopliae (II-46); - Quillay extract (II-47); - A. brasilense (II-48); - Bradyrhizobium sp. (II-49); - B. japonicum (II-50); - Mesorhizobium sp. (II-51); - Bilaiae Penicillium (II-52); - Rhizobium leguminosarum bv. phaseoli (II-53); - R. l. bv. viciae (II-54); and - Sinorhizobium meliloti (II-55).
[0214] - Bacillus amyloliquefaciens ssp. Plantarum (II-27)) - Bacillus mojavensis (II-28) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Paenibacillus polymyxa (II-34) - ácido jasmônico ou seus sais ou seus derivados (II-43) - Bacillus firmus (II-44) - Azospirillum brasilense (II-48) - Bradyrhizobium spp. (II-49) - Bradyrhizobium japonicum (II-50) - Mesorhizobium spp. (II-51) - Penicillium bilaiae (II-52) - Rhizobium leguminosarum bv. Phaseoli (II-53) - Rhizobium leguminosarum bv. Viciae (II-54) - Sinorhizobium meliloti (II-55) - Azospirillum amazonense (II-56) - Azospirillum lipoferum (II-57) - Azospirillum irakense (II-58) - Azospirillum halopraeferens (II-59) - Bradyrhizobium sp. (Arachis) (II-60) - Bradyrhizobium sp. (Vigna) (II-61) - Bradyrhizobium elkanii (II-62) - Bradyrhizobium liaoningense (II-63) - Bradyrhizobium lupini (II-64) - Delftia acidovorans (II-65) - Glomus intraradices (II-66) - Mesorhizobium ciceri (II-67) - Mesorhizobium huakii (II-68) - Mesorhizobium loti (II-69) - Rhizobium leguminosarum bv. Trifolii (II-70) - Rhizobium tropici (II-71) - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus megaterium (II-74) - Bacillus mycoides (II-75) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - ácido abscísico (II-87) - harpina (alfa-beta) (II-88) - cis-jasmona (II-89) - jasmonato de metila (II-90) [0214] In accordance with yet another embodiment of the present invention, the biopesticidal component II is selected from: - Bacillus amyloliquefaciens ssp. Plantarum (II-27)) - Bacillus mojavensis (II-28) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Paenibacillus polymyxa (II-34) - jasmonic acid or its salts or derivatives (II-43) - Bacillus firmus (II-44) - Azospirillum brasilense (II-48) - Bradyrhizobium spp. (II-49) - Bradyrhizobium japonicum (II-50) - Mesorhizobium spp. (II-51) - Penicillium bilaiae (II-52) - Rhizobium leguminosarum bv. Phaseoli (II-53) - Rhizobium leguminosarum bv. Viciae (II-54) - Sinorhizobium meliloti (II-55) - Azospirillum amazonense (II-56) - Azospirillum lipoferum (II-57) - Azospirillum irakense (II-58) - Azospirillum halopraeferens (II-59) - Bradyrhizobium sp. (Arachis) (II-60) - Bradyrhizobium sp. (Vigna) (II-61) - Bradyrhizobium elkanii (II-62) - Bradyrhizobium liaoningense (II-63) - Bradyrhizobium lupini (II-64) - Delftia acidovorans (II-65) - Glomus intraradices (II-66) - Mesorhizobium ciceri (II-67) - Mesorhizobium huakii (II-68) - Mesorhizobium loti (II-69) - Rhizobium leguminosarum bv. Trifolii (II-70) - Rhizobium tropici (II-71) - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus megaterium (II-74) - Bacillus mycoides (II-75) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - abscisic acid (II-87) - harpine (alpha-beta) (II-88) - cis-jasmine (II-89) - methyl jasmonate (II-90)
[0215] [0215] In accordance with yet another embodiment of the present invention, the biopesticidal component II is selected from (II-27), (II-29), (II-30), (II-44), (II- 48), (II-50), (II-52), (II-62), (II-73), (II-74), (II-76), (II-77), (II-78) , (II-79), (II-80), (II-82), (II-88), (II-89) and (II-90).
[0216] - Azospirillum amazonense SpY2 (II-91) - Azospirillum brasilense AZ39 também denominado Az 39 (II-92) - Azospirillum brasilense Cd (II-93) - Azospirillum brasilense Sp 245 (II-94) - Azospirillum brasilense Ab-V5 (II-95) - Azospirillum brasilense Ab-V6 (II-96) - Azospirillum brasilense XOH (II-97) - Azospirillum lipoferum Sp31 (II-98) - Bradyrhizobium elkanii SEMIA 5019 também denominado 29W (II-99) - Bradyrhizobium elkanii SEMIA 587 (II-100) - Bradyrhizobium elkanii U-1301 (II-101) - Bradyrhizobium elkanii U-1302 (II-102) - Bradyrhizobium elkanii USDA 3254 (II-103) - Bradyrhizobium elkanii USDA 76 (II-104) - Bradyrhizobium elkanii USDA 94 (II-105) - Bradyrhizobium japonicum 532c (II-106) - Bradyrhizobium japonicum E-109 (II-107) - Bradyrhizobium japonicum G49 (II-108) - Bradyrhizobium japonicum SEMIA 5079 (II-109) - Bradyrhizobium japonicum SEMIA 5080 (II-110) - Bradyrhizobium japonicum SEMIA 566 (II-111) - Bradyrhizobium japonicum SEMIA 586 (II-112) - Bradyrhizobium japonicum TA-11 (TA11 NOD +) (II-113) - Bradyrhizobium japonicum USDA 110 (II-114) - Bradyrhizobium japonicum USDA 121 (II-115) - Bradyrhizobium japonicum USDA 3 (II-116) - Bradyrhizobium japonicum USDA 31 (II-117) - Bradyrhizobium japonicum USDA 76 (II-118) - Bradyrhizobium sp. (Arachis) CB1015 (II-119) - Bradyrhizobium sp. (Arachis) SEMIA 6144 (II-120) - Bradyrhizobium sp. (Arachis) SEMIA 6462 (II-121) - Bradyrhizobium sp. (Arachis) SEMIA 6464 (II-122) - Bradyrhizobium sp. (Vigna) PNL1 (II-123) - Mesorhizobium sp. WSM1497 (II-124) - Rhizobium leguminosarum bv. phaseoli RG-B10 (II-125) - Rhizobium leguminosarum bv. phaseoli (II-126) - Rhizobium leguminosarum bv. trifolii 095 (II-127) - Rhizobium leguminosarum bv. trifolii CB782 (II-128) - Rhizobium leguminosarum bv. trifolii CC1099 (II-129) - Rhizobium leguminosarum bv. trifolii CC275e (II-130) - Rhizobium leguminosarum bv. trifolii CC283b (II-131) - Rhizobium leguminosarum bv. trifolii RP113-7 (II-132) - Rhizobium leguminosarum bv. trifolii TA1 (II-133) - Rhizobium leguminosarum bv. trifolii WSM1325 (II-134) - Rhizobium leguminosarum bv. trifolii WSM2304 (II-135) - Rhizobium leguminosarum bv. viciae P1NP3Cst também referido como 1435 (II-136) - Rhizobium leguminosarum bv. viciae RG-P2 também denominado P2 (II-137) - Rhizobium leguminosarum bv. viciae SU303 (II-138) - Rhizobium leguminosarum bv. viciae WSM1455 (II-140) - Rhizobium tropici CC511 (II-141) - Rhizobium tropici CIAT 899 (II-142) - Rhizobium tropici H12 (II-143) - Rhizobium tropici PRF 81 (II-144) - Sinorhizobium meliloti NRG185 (II-145) - Sinorhizobium meliloti RCR2011 também denominado 2011 ou SU47 (II-146) - Sinorhizobium meliloti RRI128 (II-147) - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 também denominado SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 também denominado GBO3 anteriormente B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 também referido como 1430, anteriormente B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, anteriormente B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, também denominado 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J também denominado BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 de outra maneira referido como BU F22 e BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 também denominado K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp. Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (também denominado P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (também denominado P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203) [0216] In accordance with yet another embodiment of the present invention, the biopesticidal component II is selected from: - Azospirillum amazonense SpY2 (II-91) - Azospirillum brasilense AZ39 also called Az 39 (II-92) - Azospirillum brasilense Cd (II-93) - Azospirillum brasilense Sp 245 (II-94) - Azospirillum brasilense Ab-V5 (II-95) - Azospirillum brasilense Ab-V6 (II-96) - Azospirillum brasilense XOH (II-97) - Azospirillum lipoferum Sp31 (II-98) - Bradyrhizobium elkanii SEMIA 5019 also called 29W (II-99) - Bradyrhizobium elkanii SEMIA 587 (II-100) - Bradyrhizobium elkanii U-1301 (II-101) - Bradyrhizobium elkanii U-1302 (II-102) - Bradyrhizobium elkanii USDA 3254 (II-103) - Bradyrhizobium elkanii USDA 76 (II-104) - Bradyrhizobium elkanii USDA 94 (II-105) - Bradyrhizobium japonicum 532c (II-106) - Bradyrhizobium japonicum E-109 (II-107) - Bradyrhizobium japonicum G49 (II-108) - Bradyrhizobium japonicum SEMIA 5079 (II-109) - Bradyrhizobium japonicum SEMIA 5080 (II-110) - Bradyrhizobium japonicum SEMIA 566 (II-111) - Bradyrhizobium japonicum SEMIA 586 (II-112) - Bradyrhizobium japonicum TA-11 (TA11 NOD +) (II-113) - Bradyrhizobium japonicum USDA 110 (II-114) - Bradyrhizobium japonicum USDA 121 (II-115) - Bradyrhizobium japonicum USDA 3 (II-116) - Bradyrhizobium japonicum USDA 31 (II-117) - Bradyrhizobium japonicum USDA 76 (II-118) - Bradyrhizobium sp. (Arachis) CB1015 (II-119) - Bradyrhizobium sp. (Arachis) SEMIA 6144 (II-120) - Bradyrhizobium sp. (Arachis) SEMIA 6462 (II-121) - Bradyrhizobium sp. (Arachis) SEMIA 6464 (II-122) - Bradyrhizobium sp. (Vigna) PNL1 (II-123) - Mesorhizobium sp. WSM1497 (II-124) - Rhizobium leguminosarum bv. phaseoli RG-B10 (II-125) - Rhizobium leguminosarum bv. phaseoli (II-126) - Rhizobium leguminosarum bv. trifolii 095 (II-127) - Rhizobium leguminosarum bv. trifolii CB782 (II-128) - Rhizobium leguminosarum bv. trifolii CC1099 (II-129) - Rhizobium leguminosarum bv. trifolii CC275e (II-130) - Rhizobium leguminosarum bv. trifolii CC283b (II-131) - Rhizobium leguminosarum bv. trifolii RP113-7 (II-132) - Rhizobium leguminosarum bv. trifolii TA1 (II-133) - Rhizobium leguminosarum bv. trifolii WSM1325 (II-134) - Rhizobium leguminosarum bv. trifolii WSM2304 (II-135) - Rhizobium leguminosarum bv. viciae P1NP3Cst also referred to as 1435 (II-136) - Rhizobium leguminosarum bv. viciae RG-P2 also known as P2 (II-137) - Rhizobium leguminosarum bv. viciae SU303 (II-138) - Rhizobium leguminosarum bv. viciae WSM1455 (II-140) - Rhizobium tropici CC511 (II-141) - Rhizobium tropici CIAT 899 (II-142) - Rhizobium tropici H12 (II-143) - Rhizobium tropici PRF 81 (II-144) - Sinorhizobium meliloti NRG185 (II-145) - Sinorhizobium meliloti RCR2011 also known as 2011 or SU47 (II-146) - Sinorhizobium meliloti RRI128 (II-147) - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 also called SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 also called GBO3 formerly B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430, formerly B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, formerly B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, also called 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J also called BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 otherwise referred to as BU F22 and BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 also known as K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp. Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (also called P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (also called P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (also called P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (also called P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (also called P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203)
[0217] [0217] In accordance with yet another embodiment of the present invention, the biopesticidal component II is selected from (II-94), (II-95), (II-96), (II-99), (II- 100), (II-106), (II-107), (II-109), (II-110), (II-154), (II-155), (II-156), (II-158) , (II-159), (II-160), (II-161), (II-170), (II-171), (II-173), (II-174), (II-176), ( II-178), (II-179), (II-180), (II-182), (II-186), (II-193), (II-194) and (II-195).
[0218] [0218] Consequently, the especially preferred two-component compositions are compiled in Table B, in which each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are binary compositions in which only one contains one of these two components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention. TABLE B
[0219] [0219] Two-component compositions comprising a component I and a component II, in particular, binary compositions containing the respective component I and II as the only active ingredients.
[0220] [0220] Especially preferred two-component compositions are compiled in Table B1, in which each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are binary compositions in which only one contains one of these two components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention. TABLE B1
[0221] [0221] Two-component compositions comprising a component I and a component II, in particular, binary compositions containing the respective component I and II as the only active ingredients.
[0222] [0222] Especially preferred two-component compositions are compiled in Table B2, where each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are binary compositions in which only one contains one of these two components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention. TABLE B2
[0223] [0223] Two-component compositions comprising a component I and a component II, in particular, binary compositions containing the respective component I and II as the only active ingredients.
[0224] [0224] As detailed above, components I contain the chirality centers and can therefore be present in the form of racemic compositions, such as pure enantiomers or the two enantiomers of a component I can be present in any proportion of (S) : (R).
[0225] [0225] In accordance with the special embodiments of the present invention, the respective component I is present as an enantiomer (S). The two-component compositions comprising the enantiomer (S) of the respective component I are compiled in Table Bs, in which each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are binary compositions in which only one contains one of these two components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention. BS TABLE
[0226] [0226] Two-component compositions comprising a component I as an (S) enantiomer (abbreviated as (S) -I, for example, (S) -I-1 for the (I-1) enantiomer and a component II, in particular, binary compositions containing the respective component I as enantiomer (S) and II as the only active ingredients.
[0227] [0227] In accordance with the special embodiments of the present invention, the respective component I is present as an (R) enantiomer. The compositions of two specific components that comprise the (R) enantiomer of the respective component I are compiled in Table Br, in which each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are binary compositions in which only one contains one of these two components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention. TABLE BR
[0228] [0228] Two-component compositions comprising a component I as the (R) enantiomer (abbreviated as (R) -I, for example, (R) -I-1 for the (I-1) enantiomer and a component II, in particular, binary compositions containing the respective component I as an enantiomer (R) and II as the only active ingredients.
[0229] [0229] According to another aspect, the present invention relates to three-component compositions, that is, compositions comprising component I, that is, a compound I, in particular a compound selected from compounds I- 1, I-2, I-3, I-4, I-5, I-6, 7-I, I-8, I-9, I-10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21, I-22, I-23, I-24, I-25, I- 26, I-27, I-28, I-29, I-30 and I-31, or any group of compounds I detailed above, a component II, as detailed above and a component III.
[0230] [0230] According to one embodiment, component III is selected from groups (L1) to (L6) or any preferred subgroup of these, as detailed above.
[0231] [0231] According to another embodiment, component III is selected from groups (L1a) to (L6a) or any preferred subgroup of these, as detailed above.
[0232] [0232] According to yet another embodiment, component III is selected from the groups from (La) to (Lf) or any preferred subgroup of these, as detailed above.
[0233] [0233] According to yet another embodiment, component III is selected from the groups from (La-1) to (Lf-1) or any preferred subgroup of these, as detailed above.
[0234] - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus amyloliquefaciens ssp. Plantarum (II-27) - Bacillus firmus (II-44) - Bacillus megaterium (II-74) - Bacillus mojavensis (II-28) - Bacillus mycoides (II-75) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus polymyxa (II-34) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Penicillium bilaiae (II-52) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - ácido abscísico (II-87) - proteína harpina (alfa-beta) (II-88) - ácido jasmônico ou seus sais ou seus derivados (II-43) - cis-jasmona (II-89) - jasmonato de metila (II-90) [0234] In accordance with yet another embodiment, component III is selected from the following compounds: - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus amyloliquefaciens ssp. Plantarum (II-27) - Bacillus firmus (II-44) - Bacillus megaterium (II-74) - Bacillus mojavensis (II-28) - Bacillus mycoides (II-75) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus polymyxa (II-34) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Penicillium bilaiae (II-52) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - abscisic acid (II-87) - harpin protein (alpha-beta) (II-88) - jasmonic acid or its salts or derivatives (II-43) - cis-jasmine (II-89) - methyl jasmonate (II-90)
[0235] [0235] The especially preferred three-component compositions are compiled in Tables T1 to T31, where each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are the ternary compositions in which each one only contains these three components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention.
[0236] - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus amyloliquefaciens ssp. Plantarum (II-27) - Bacillus firmus (II-44) - Bacillus megaterium (II-74) - Bacillus mojavensis (II-28) - Bacillus mycoides (II-75) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus polymyxa (II-34) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Penicillium bilaiae (II-52) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - ácido abscísico (II-87) - proteína harpina (alfa-beta) (II-88) - ácido jasmônico ou seus sais ou seus derivados (II-43) - cis-jasmona (II-89) - jasmonato de metila (II-90) [0236] In these three-component compositions, component I is selected from compounds I-1, I-2, I-3, I-4, I-5, I-6, I-7 I-8, I -9, I -10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and I-31, or any group of compounds I detailed above, component II is selected from: - Azospirillum amazonense (II-56) - Azospirillum brasilense (II-48) - Azospirillum lipoferum (II-57) - Azospirillum irakense (II-58) - Azospirillum halopraeferens (II-59) - Bradyrhizobium spp. (II-49) - Bradyrhizobium sp. (Arachis) (II-60) - Bradyrhizobium sp. (Vigna) (II-61) - Bradyrhizobium elkanii (II-62) - Bradyrhizobium japonicum (II-50) - Bradyrhizobium liaoningense (II-63) - Bradyrhizobium lupini (II-64) - Delftia acidovorans (II-65) - Glomus intraradices (II-66) - Mesorhizobium spp. (II-51) - Mesorhizobium ciceri (II-67) - Mesorhizobium huakii (II-68) - Mesorhizobium loti (II-69) - Rhizobium leguminosarum bv. Phaseoli (II-53) - Rhizobium leguminosarum bv. Trifolii (II-70) - Rhizobium leguminosarum bv. Viciae (II-54) - Rhizobium tropici (II-71) - Sinorhizobium meliloti (II-55) - and component III is selected from: - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus amyloliquefaciens ssp. Plantarum (II-27) - Bacillus firmus (II-44) - Bacillus megaterium (II-74) - Bacillus mojavensis (II-28) - Bacillus mycoides (II-75) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus polymyxa (II-34) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Penicillium bilaiae (II-52) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - abscisic acid (II-87) - harpin protein (alpha-beta) (II-88) - jasmonic acid or its salts or derivatives (II-43) - cis-jasmine (II-89) - methyl jasmonate (II-90)
[0237] [0237] The three-component compositions T1-1 to T1-644 comprising compound I-3, component II and component III, in particular, the ternary compositions containing compound I-3, II and III, as unique active ingredients.
[0238] [0238] The three-component compositions from T2-1 to T2-644 correspond to the respective compositions from T1-1 to T1-644, where component I is I-2 instead of I-3. Consequently, Table T2 contains the compositions from T2-1 to T2-644 which comprise compound I-2, component II and component III, in particular, the ternary compositions containing compound I-2, II and III, as only active ingredients. TABLE T3
[0239] [0239] The three-component compositions from T3-1 to T3-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-1, instead of I-3. Consequently, Table T3 contains compositions from T3-1 to T3-644 which comprise compound I-3, component II and component III, in particular, ternary compositions containing compound I-1, II and III, as only active ingredients. TABLE T4
[0240] [0240] The three-component compositions from T4-1 to T4-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-4, instead of I-3. Consequently, Table T4 contains the compositions T4-1 to T4-644 which comprise compound I-4, component II and component III, in particular, the ternary compositions containing compound I-4, II and III, as only active ingredients. TABLE T5
[0241] [0241] The three-component compositions from T5-1 to T5-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-5 instead of I-3. Consequently, Table T5 contains the compositions T5-1 to T5-644 which comprise compound I-5, component II and component III, in particular, the ternary compositions containing compound I-5, II and III, as only active ingredients. TABLE T6
[0242] [0242] The three-component compositions from T6-1 to T6-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-6, instead of I-3. Consequently, Table T6 contains compositions T6-1 to T6-644 comprising compound I-6, component II and component III, in particular, ternary compositions containing compound I-6, II and III, as only active ingredients. TABLE T7
[0243] [0243] The three-component compositions from T7-1 to T7-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-7, instead of I-3. Consequently, Table T7 contains the compositions T7-1 to T7-644 which comprise compound I-7, component II and component III, in particular, the ternary compositions containing compound I-7, II and III, as only active ingredients. TABLE T8
[0244] [0244] The three-component compositions from T8-1 to T8-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-8 instead of I-3. Consequently, Table T8 contains compositions T8-1 to T8-644 comprising compound I-8, component II and component III, in particular, ternary compositions containing compound I-8, II and III, as only active ingredients. TABLE T9
[0245] [0245] The three-component compositions from T9-1 to T9-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-9, instead of I-3. Consequently, Table T9 contains compositions T9-1 to T9-644 comprising compound I-9, component II and component III, in particular, ternary compositions containing compound I-9, II and III, as only active ingredients. TABLE T10
[0246] [0246] The three-component compositions from T10-1 to T10-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-10, instead of I-3. Consequently, Table T10 contains the compositions T10-1 to T10-644 which comprise compound I-10, component II and component III, in particular, the ternary compositions containing compound I-10, II and III, as only active ingredients. TABLE T11
[0247] [0247] The three-component compositions from T11-1 to T11-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-11, instead of I-3. Consequently, Table T11 contains the compositions T11-1 to T11-644 which comprise compound I-11, component II and component III, in particular, the ternary compositions containing compound I-11, II and III, as only active ingredients. TABLE T12
[0248] [0248] The three-component compositions from T12-1 to T12-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-12, instead of I-3. Consequently, Table T12 contains the compositions T12-1 to T12-644 which comprise compound I-12, component II and component III, in particular, the ternary compositions containing compound I-12, II and III, as only active ingredients. TABLE T13
[0249] [0249] The three-component compositions from T13-1 to T13-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-13, instead of I-3. Consequently, Table T13 contains the compositions T13-1 to T13-644 which comprise compound I-13, component II and component III, in particular, the ternary compositions containing compound I-13, II and III, as only active ingredients. TABLE T14
[0250] [0250] The three-component compositions from T14-1 to T14-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-14, instead of I-3. Consequently, Table T14 contains the compositions T14-1 to T14-644 which comprise compound I-14, component II and component III, in particular, the ternary compositions containing compound I-14, II and III, as only active ingredients. TABLE T15
[0251] [0251] The three-component compositions from T15-1 to T15-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-15, instead of I-3. Consequently, Table T15 contains the compositions T15-1 to T15-644 which comprise compound I-15, component II and component III, in particular, the ternary compositions containing compound I-15, II and III, as only active ingredients. TABLE T16
[0252] [0252] The three-component compositions from T16-1 to T16-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-16, instead of I-3. Consequently, Table T16 contains the compositions T16-1 to T16-644 which comprise compound I-16, component II and component III, in particular, the ternary compositions containing compound I-16, II and III, as only active ingredients. TABLE T17
[0253] [0253] The three-component compositions from T17-1 to T17-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-17, instead of I-3. Consequently, Table T17 contains the compositions T17-1 to T17-644 which comprise compound I-17, component II and component III, in particular, the ternary compositions containing compound I-17, II and III, as only active ingredients. TABLE T18
[0254] [0254] The three-component compositions from T18-1 to T18-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-18, instead of I-3. Consequently, Table T18 contains the compositions from T18-1 to T18-644 which comprise compound I-18, component II and component III, in particular, the ternary compositions containing compound I-18, II and II as unique active ingredients. TABLE T19
[0255] [0255] The three-component compositions from T19-1 to T19-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-19, instead of I-3. Consequently, Table T19 contains the compositions T19-1 to T19-644 which comprise compound I-19, component II and component III, in particular, the ternary compositions containing compound I-19, II and III, as only active ingredients. TABLE T20
[0256] [0256] The three-component compositions from T20-1 to T20-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-20, instead of I-3. Consequently, Table T20 contains the compositions T20-1 to T20-644 which comprise compound I-20, component II and component III, in particular, the ternary compositions containing compound I-20, II and III, as only active ingredients. TABLE T21
[0257] [0257] The three-component compositions from T21-1 to T21-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-21, instead of I-3. Consequently, Table T21 contains the compositions T21-1 to T21-644 which comprise compound I-21, component II and component III, in particular, the ternary compositions containing compound I-21, II and III, as only active ingredients. TABLE T22
[0258] [0258] The three-component compositions from T22-1 to T22-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-22, instead of I-3. Consequently, Table T22 contains the compositions T22-1 to T22-644 which comprise compound I-22, component II and component III, in particular, the ternary compositions containing compound I-22, II and III, as only active ingredients. TABLE T23
[0259] [0259] The three-component compositions from T23-1 to T23-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-23, instead of I-3. Consequently, Table T23 contains the compositions T23-1 to T23-644 which comprise compound I-23, component II and component III, in particular, the ternary compositions containing compound I-23, II and III, as only active ingredients. TABLE T24
[0260] [0260] The three-component compositions from T24-1 to T24-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-24, instead of I-3. Consequently, Table T24 contains the compositions T24-1 to T24-644 which comprise compound I-24, component II and component III, in particular, the ternary compositions containing compound I-24, II and III, as only active ingredients. TABLE T25
[0261] [0261] The three-component compositions from T25-1 to T25-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-25, instead of I-3. Consequently, Table T25 contains the compositions T25-1 to T25-644 which comprise compound I-25, component II and component III, in particular, the ternary compositions containing compound I-25, II and III, as only active ingredients. TABLE T26
[0262] [0262] The three-component compositions from T26-1 to T26-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-26, instead of I-3. Consequently, Table T26 contains the compositions T26-1 to T26-644 which comprise compound I-26, component II and component III, in particular, the ternary compositions containing compound I-26, II and III, as only active ingredients. TABLE T27
[0263] [0263] The three-component compositions from T27-1 to T27-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-27, instead of I-3. Consequently, Table T27 contains the compositions T27-1 to T27-644 which comprise compound I-27, component II and component III, in particular, the ternary compositions containing compound I-27, II and III, as only active ingredients. TABLE T28
[0264] [0264] The three-component compositions from T28-1 to T28-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-28, instead of I-3. Consequently, Table T28 contains the compositions T28-1 to T28-644 which comprise compound I-28, component II and component III, in particular, the ternary compositions containing compound I-28, II and III, as only active ingredients. TABLE T29
[0265] [0265] The three-component compositions from T29-1 to T29-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-29, instead of I-3. Consequently, Table T29 contains the compositions T29-1 to T29-644 which comprise compound I-29, component II and component III, in particular, the ternary compositions containing compound I-29, II and III, as only active ingredients. TABLE T30
[0266] [0266] The three-component compositions from T30-1 to T30-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-30, instead of I-3. Consequently, Table T30 contains the compositions T30-1 to T30-644 which comprise compound I-30, component II and component III, in particular, the ternary compositions containing compound I-30, II and III, as only active ingredients. TABLE T31
[0267] [0267] The three-component compositions from T31-1 to T31-644 corresponding to the respective compositions from T1-1 to T1-644, where component I is I-31, instead of I-3. Consequently, Table T31 contains the compositions T31-1 to T31-644 which comprise compound I-31, component II and component III, in particular, the ternary compositions containing compound I-31, II and III, as only active ingredients.
[0268] - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 também denominado SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 também denominado GBO3 anteriormente B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 também referido como 1430, anteriormente B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, anteriormente B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, também denominado 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J também denominado BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 de outra maneira referido como BU F22 e BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 também denominado K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp, Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (também denominado P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (também denominado P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203) [0268] Other especially preferred III components are selected from: - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 also called SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 also called GBO3 formerly B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430, formerly B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, formerly B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, also called 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J also called BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 otherwise referred to as BU F22 and BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 also known as K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp, Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (also called P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (also called P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (also called P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (also called P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (also called P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203)
[0269] [0269] Consequently, the even more especially preferred three-component compositions are compiled in Table T1a, in which each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are the ternary compositions in which each one only contains these three components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention.
[0270] - Azospirillum amazonense SpY2 (II-91) - Azospirillum brasilense AZ39 também denominado Az 39 (II-92) - Azospirillum brasilense Cd (II-93) - Azospirillum brasilense Sp 245 (II-94) - Azospirillum brasilense Ab-V5 (II-95) - Azospirillum brasilense Ab-V6 (II-96) - Azospirillum brasilense XOH (II-97) - Azospirillum lipoferum Sp31 (II-98) - Bradyrhizobium elkanii SEMIA 5019 também denominado 29W (II-99) - Bradyrhizobium elkanii SEMIA 587 (II-100) - Bradyrhizobium elkanii U-1301 (II-101) - Bradyrhizobium elkanii U-1302 (II-102) - Bradyrhizobium elkanii USDA 3254 (II-103) - Bradyrhizobium elkanii USDA 76 (II-104) - Bradyrhizobium elkanii USDA 94 (II-105) - Bradyrhizobium japonicum 532c (II-106) - Bradyrhizobium japonicum E-109 (II-107) - Bradyrhizobium japonicum G49 (II-108) - Bradyrhizobium japonicum SEMIA 5079 (II-109) - Bradyrhizobium japonicum SEMIA 5080 (II-110) - Bradyrhizobium japonicum SEMIA 566 (II-111) - Bradyrhizobium japonicum SEMIA 586 (II-112) - Bradyrhizobium japonicum TA-11 (TA11 NOD +) (II-113) - Bradyrhizobium japonicum USDA 110 (II-114) - Bradyrhizobium japonicum USDA 121 (II-115) - Bradyrhizobium japonicum USDA 3 (II-116) - Bradyrhizobium japonicum USDA 31 (II-117) - Bradyrhizobium japonicum USDA 76 (II-118) - Bradyrhizobium sp. (Arachis) CB1015 (II-119) - Bradyrhizobium sp. (Arachis) SEMIA 6144 (II-120) - Bradyrhizobium sp. (Arachis) SEMIA 6462 (II-121) - Bradyrhizobium sp. (Arachis) SEMIA 6464 (II-122) - Bradyrhizobium sp. (Vigna) PNL1 (II-123) - Mesorhizobium sp. WSM1497 (II-124) - Rhizobium leguminosarum bv. phaseoli RG-B10 (II-125) - Rhizobium leguminosarum bv. phaseoli (II-126) - Rhizobium leguminosarum bv. trifolii 095 (II-127) - Rhizobium leguminosarum bv. trifolii CB782 (II-128) - Rhizobium leguminosarum bv. trifolii CC1099 (II-129) - Rhizobium leguminosarum bv. trifolii CC275e (II-130) - Rhizobium leguminosarum bv. trifolii CC283b (II-131) - Rhizobium leguminosarum bv. trifolii RP113-7 (II-132) - Rhizobium leguminosarum bv. trifolii TA1 (II-133) - Rhizobium leguminosarum bv. trifolii WSM1325 (II-134) - Rhizobium leguminosarum bv. trifolii WSM2304 (II-135) - Rhizobium leguminosarum bv. viciae P1NP3Cst também referido como 1435 (II-136) - Rhizobium leguminosarum bv. viciae RG-P2 também denominado P2 (II-137) - Rhizobium leguminosarum bv. viciae SU303 (II-138) - Rhizobium leguminosarum bv. viciae WSM1455 (II-140) - Rhizobium tropici CC511 (II-141) - Rhizobium tropici CIAT 899 (II-142) - Rhizobium tropici H12 (II-143) - Rhizobium tropici PRF 81 (II-144) - Sinorhizobium meliloti NRG185 (II-145) - Sinorhizobium meliloti RCR2011 também denominado 2011 ou SU47 (II-146) - Sinorhizobium meliloti RRI128 (II-147) - e o componente III é selecionado a partir de: - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 também denominado SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 também denominado GBO3 anteriormente B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 também referido como 1430, anteriormente B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, anteriormente B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, também denominado 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J também denominado BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 de outra maneira referido como BU F22 e BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 também denominado K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp, Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (também denominado P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (também denominado P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (também denominado P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203) [0270] In these three-component compositions, component I is selected from compounds I-1, I-2, I-3, I-4, I-5, I-6, I-7 I-8, I -9, I -10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and I-31, or any group of compounds I detailed above, component II is selected from: - Azospirillum amazonense SpY2 (II-91) - Azospirillum brasilense AZ39 also called Az 39 (II-92) - Azospirillum brasilense Cd (II-93) - Azospirillum brasilense Sp 245 (II-94) - Azospirillum brasilense Ab-V5 (II-95) - Azospirillum brasilense Ab-V6 (II-96) - Azospirillum brasilense XOH (II-97) - Azospirillum lipoferum Sp31 (II-98) - Bradyrhizobium elkanii SEMIA 5019 also called 29W (II-99) - Bradyrhizobium elkanii SEMIA 587 (II-100) - Bradyrhizobium elkanii U-1301 (II-101) - Bradyrhizobium elkanii U-1302 (II-102) - Bradyrhizobium elkanii USDA 3254 (II-103) - Bradyrhizobium elkanii USDA 76 (II-104) - Bradyrhizobium elkanii USDA 94 (II-105) - Bradyrhizobium japonicum 532c (II-106) - Bradyrhizobium japonicum E-109 (II-107) - Bradyrhizobium japonicum G49 (II-108) - Bradyrhizobium japonicum SEMIA 5079 (II-109) - Bradyrhizobium japonicum SEMIA 5080 (II-110) - Bradyrhizobium japonicum SEMIA 566 (II-111) - Bradyrhizobium japonicum SEMIA 586 (II-112) - Bradyrhizobium japonicum TA-11 (TA11 NOD +) (II-113) - Bradyrhizobium japonicum USDA 110 (II-114) - Bradyrhizobium japonicum USDA 121 (II-115) - Bradyrhizobium japonicum USDA 3 (II-116) - Bradyrhizobium japonicum USDA 31 (II-117) - Bradyrhizobium japonicum USDA 76 (II-118) - Bradyrhizobium sp. (Arachis) CB1015 (II-119) - Bradyrhizobium sp. (Arachis) SEMIA 6144 (II-120) - Bradyrhizobium sp. (Arachis) SEMIA 6462 (II-121) - Bradyrhizobium sp. (Arachis) SEMIA 6464 (II-122) - Bradyrhizobium sp. (Vigna) PNL1 (II-123) - Mesorhizobium sp. WSM1497 (II-124) - Rhizobium leguminosarum bv. phaseoli RG-B10 (II-125) - Rhizobium leguminosarum bv. phaseoli (II-126) - Rhizobium leguminosarum bv. trifolii 095 (II-127) - Rhizobium leguminosarum bv. trifolii CB782 (II-128) - Rhizobium leguminosarum bv. trifolii CC1099 (II-129) - Rhizobium leguminosarum bv. trifolii CC275e (II-130) - Rhizobium leguminosarum bv. trifolii CC283b (II-131) - Rhizobium leguminosarum bv. trifolii RP113-7 (II-132) - Rhizobium leguminosarum bv. trifolii TA1 (II-133) - Rhizobium leguminosarum bv. trifolii WSM1325 (II-134) - Rhizobium leguminosarum bv. trifolii WSM2304 (II-135) - Rhizobium leguminosarum bv. viciae P1NP3Cst also referred to as 1435 (II-136) - Rhizobium leguminosarum bv. viciae RG-P2 also known as P2 (II-137) - Rhizobium leguminosarum bv. viciae SU303 (II-138) - Rhizobium leguminosarum bv. viciae WSM1455 (II-140) - Rhizobium tropici CC511 (II-141) - Rhizobium tropici CIAT 899 (II-142) - Rhizobium tropici H12 (II-143) - Rhizobium tropici PRF 81 (II-144) - Sinorhizobium meliloti NRG185 (II-145) - Sinorhizobium meliloti RCR2011 also known as 2011 or SU47 (II-146) - Sinorhizobium meliloti RRI128 (II-147) - and component III is selected from: - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 also called SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 also called GBO3 formerly B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430, formerly B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, formerly B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, also called 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J also called BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 otherwise referred to as BU F22 and BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 also known as K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp, Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (also called P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (also called P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (also called P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (also called P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (also called P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203)
[0271] [0271] The three-component compositions from T1a-1 to T1a3.080 comprising compound I-3, a component II and a component III, in particular, the ternary compositions containing compound I-3, II and III, as the only active ingredients.
[0272] [0272] The three-component compositions from T2a-1 to T2a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-2 instead of I-3. Consequently, Table T2a contains the compositions from T2a-1 to T2a-3,080 which comprise compound I-2, component II and component III, in particular, the ternary compositions containing compound I-2, II and III, as only active ingredients. TABLE T3A
[0273] [0273] The three-component compositions from T3a-1 to T3a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-1, instead of I-3. Consequently, Table T3a contains the compositions from T3a-1 to T3a-3.080 which comprise compound I-3, component II and component III, in particular, the ternary compositions containing compound I-1, II and III, as only active ingredients. TABLE T4A
[0274] [0274] The three-component compositions from T4a-1 to T4a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-4, instead of I-3. Consequently, Table T4a contains the compositions T4a-1 to T4a-3,080 which comprise compound I-4, component II and component III, in particular, the ternary compositions containing compound I-4, II and III, as only active ingredients. TABLE T5A
[0275] [0275] The three-component compositions from T5A-1 to T5A-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-5 instead of I-3. Consequently, Table T5A contains compositions from T5A-1 to T5A-3,080 which comprise compound I-5, component II and component III, in particular, ternary compositions containing compound I-5, II and III, as only active ingredients. TABLE T6A
[0276] [0276] The three-component compositions from T6a-1 to T6a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-6, instead of I-3. Consequently, Table T6a contains the compositions T6a-1 to T6a-3,080 which comprise compound I-6, component II and component III, in particular, the ternary compositions containing compound I-6, II and III, as only active ingredients. TABLE T7A
[0277] [0277] The three-component compositions from T7a-1 to T7a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-7, instead of I-3. Consequently, Table T7a contains compositions from T7a-1 to T7a-3,080 which comprise compound I-7, component II and component III, in particular, ternary compositions containing compound I-7, II and III, as only active ingredients. TABLE T8A
[0278] [0278] The three-component compositions from T8A-1 to T8A-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-8 instead of I-3. Consequently, Table T8a contains compositions from T8a-1 to T8a-3,080 which comprise compound I-8, component II and component III, in particular, ternary compositions containing compound I-8, II and III, as only active ingredients. TABLE T9A
[0279] [0279] The three-component compositions from T9a-1 to T9a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-9, instead of I-3. Consequently, Table T9a contains the compositions T9a-1 to T9a-3,080 which comprise compound I-9, component II and component III, in particular, the ternary compositions containing compound I-9, II and III, as only active ingredients. TABLE T10A
[0280] [0280] The three-component compositions from T10a to T10A a-1-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-10, instead of I-3. Consequently, Table T10a contains compositions from T10a to T10a-1-3.080 which comprise compound I-10, component II and component III, in particular, ternary compositions containing compound I-10, II and III, as only active ingredients. TABLE T11A
[0281] [0281] The three-component compositions from T11a-1 to T11a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-11, instead of I-3. Consequently, Table T11a contains compositions from T11a-1 to T11a-3,080 which comprise compound I-11, component II and component III, in particular, ternary compositions containing compound I-11, II and III, as only active ingredients. TABLE T12A
[0282] [0282] The three-component compositions from T12a-1 to T12a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-12, instead of I-3. Consequently, Table T12a contains compositions from T12a-1 to T12a-3,080 which comprise compound I-12, component II and component III, in particular, ternary compositions containing compound I-12, II and III, as only active ingredients. TABLE T13A
[0283] [0283] The three-component compositions from T13a-1 to T13a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-13, instead of I-3. Consequently, Table T13a contains compositions from T13a-1 to T13a-3,080 which comprise compound I-13, component II and component III, in particular, ternary compositions containing compound I-13, II and III, as only active ingredients. TABLE T14A
[0284] [0284] The three-component compositions from T14a-1 to T14a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-14, instead of I-3. Consequently, Table T14a contains compositions from T14a-1 to T14a-3,080 which comprise compound I-14, component II and component III, in particular, ternary compositions containing compound I-14, II and III, as only active ingredients. TABLE T15A
[0285] [0285] The three-component compositions from T15a-1 to T15a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-15, instead of I-3. Consequently, Table T15a contains compositions from T15a-1 to T15a-3,080 which comprise compound I-15, component II and component III, in particular, ternary compositions containing compound I-15, II and III, as only active ingredients. TABLE T16A
[0286] [0286] The three-component compositions from T16a-1 to T16a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-16, instead of I-3. Consequently, Table T16a contains compositions from T16a-1 to T16a-3,080 which comprise compound I-16, component II and component III, in particular, ternary compositions containing compound I-16, II and III, as only active ingredients. TABLE T17A
[0287] [0287] The three-component compositions from T17a-1 to T17a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-17, instead of I-3. Consequently, Table T17a contains compositions from T17a-1 to T17a-3,080 which comprise compound I-17, component II and component III, in particular, ternary compositions containing compound I-17, II and III, as only active ingredients. TABLE T18A
[0288] [0288] The three-component compositions from T18a-1 to T18a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-18, instead of I-3. Consequently, Table T18a contains compositions from T18a-1 to T18a-3,080 which comprise compound I-18, component II and component III, in particular, the ternary compositions containing compound I-18, II and II as the only ingredients active. TABLE T19A
[0289] [0289] The three-component compositions from T19a-1 to T19a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-19, instead of I-3. Consequently, Table T19a contains compositions from T19a-1 to T19a-3,080 which comprise compound I-19, component II and component III, in particular, ternary compositions containing compound I-19, II and III, as only active ingredients. TABLE T20A
[0290] [0290] The three-component compositions from T20a-1 to T20a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-20, instead of I-3. Consequently, Table T20a contains compositions from T20a-1 to T20a-3.080 that comprise compound I-20, component II and component III, in particular, ternary compositions containing compound I-20, II and III, as only active ingredients. TABLE T21A
[0291] [0291] The three-component compositions from T21a-1 to T21a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-21, instead of I-3. Consequently, Table T21a contains compositions from T21a-1 to T21a-3,080 which comprise compound I-21, component II and component III, in particular, ternary compositions containing compound I-21, II and III, as only active ingredients. TABLE T22A
[0292] [0292] The three-component compositions from T22a-1 to T22a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-22, instead of I-3. Consequently, Table T22a contains compositions from T22a-1 to T22a-3,080 which comprise compound I-22, component II and component III, in particular, ternary compositions containing compound I-22, II and III, as only active ingredients. TABLE T23A
[0293] [0293] The three-component compositions from T23a-1 to T23a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-23, instead of I-3. Consequently, Table T23a contains compositions from T23a-1 to T23a-3,080 which comprise compound I-23, component II and component III, in particular, ternary compositions containing compound I-23, II and III, as only active ingredients. TABLE T24A
[0294] [0294] The three-component compositions from T24a-1 to T24a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-24, instead of I-3. Consequently, Table T24a contains compositions from T24a-1 to T24a-3,080 which comprise compound I-24, component II and component III, in particular, ternary compositions containing compound I-24, II and III, as only active ingredients. TABLE T25A
[0295] [0295] The three-component compositions from T25a-1 to T25a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-25, instead of I-3. Consequently, Table T25a contains compositions from T25a-1 to T25a-3,080 which comprise compound I-25, component II and component III, in particular, ternary compositions containing compound I-25, II and III, as only active ingredients. TABLE T26A
[0296] [0296] The three-component compositions from T26a-1 to T26a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-26, instead of I-3. Consequently, Table T26a contains the compositions from T26a-1 to T26a-3,080 which comprise compound I-26, component II and component III, in particular, the ternary compositions containing compound I-26, II and III, as only active ingredients. TABLE T27A
[0297] [0297] The three-component compositions from T27a-1 to T27a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-27, instead of I-3. Consequently, Table T27a contains compositions from T27a-1 to T27a-3,080 which comprise compound I-27, component II and component III, in particular, ternary compositions containing compound I-27, II and III, as only active ingredients. TABLE T28A
[0298] [0298] The three-component compositions from T28a-1 to T28a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-28, instead of I-3. Consequently, Table T28a contains compositions from T28a-1 to T28a-3,080 which comprise compound I-28, component II and component III, in particular, ternary compositions containing compound I-28, II and III, as only active ingredients. TABLE T29A
[0299] [0299] The three-component compositions from T29a-1 to T29a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-29, instead of I-3. Consequently, Table T29a contains compositions from T29a-1 to T29a-3,080 which comprise compound I-29, component II and component III, in particular, ternary compositions containing compound I-29, II and III, as only active ingredients. TABLE T30A
[0300] [0300] The three-component compositions from T30a-1 to T30a-3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-30, instead of I-3. Consequently, Table T30a contains compositions from T30a-1 to T30a-3,080 which comprise compound I-30, component II and component III, in particular, ternary compositions containing compound I-30, II and III, as only active ingredients. TABLE T31A
[0301] [0301] The three-component compositions from T31a-1 to T31a3.080 corresponding to the respective compositions from T1a-1 to T1a-3.080, where component I is I-31, instead of I-3. Consequently, Table T31a contains compositions from T31a-1 to T31a-3,080 which comprise compound I-31, component II and component III, in particular, ternary compositions containing compound I-31, II and III, as only active ingredients.
[0302] - Inibidores de complexo III no local Qo (por exemplo, as estrobilurinas): a azoxistrobina, coumetoxistrobina, coumoxistrobina, dimoxistrobina, enestroburina, fenaminstrobina, fenoxistrobina / flufenoxistrobina, fluoxastrobina, cresoxim-metila, metominostrobina, orisastrobina, picoxistrobina, piraclostrobina, piraclostrobina, piraoxistrobina, éster de metila do ácido 2-[2-(2,5-dimetil-fenoximetil)-fenil]-3-metoxi-acrilico, e 2-(2-(3-(2,6-di-clorofenil)-1-metil-alliliden-aminooxi-metil)-fenil)-2-metoxiimino-Nmetil-acetamida, piribencarb, triclopiricarb / clorodincarb, famoxadona, fenamidona; - Inibidores de complexo III no local Qi: a ciazofamida, amisulbroma, 2-metilpropanoato de [(3S,6S,7R,8R)-8-benzil-3-[(3-acetoxi-4- metoxi-piridina-2-carbonil)amino]-6-metil-4,9-dioxo-1,5-dioxonan-7-il], 2- metilpropanoato de [(3S,6S,7R,8R)-8-benzil-3-[[3-(acetoximetoxi)-4-metoxipiridina-2-carbonil]amino]-6-metil-4,9-dioxo-1,5-dioxonan-7-il], 2- metilpropanoato de [(3S,6S,7R,8R)-8-benzil-3-[(3-isobutoxicarboniloxi-4-metoxipiridin-2-carbonil)amino]-6-metil-4,9-dioxo-1,5-dioxonan-7-il, 2-metilpropanoato de [(3S,6S,7R,8R)-8-benzil-3-[[3-(1,3-benzodioxol-5-ilmetoxi)-4-metoxi-piridin-2- carbonil]amino]-6-metil-4,9-di-oxo-1,5-dioxonan-7-il], 2-metilpropanoato de 3S,6S,7R,8R)-3-[[(3-hidroxi-4-metoxi-2-piridinil)carbonil]amino]-6-metil-4,9- dioxo-8- (fenilmetil)-1,5-di-dioxonan-7-il; - Inibidores de complexo II (por exemplo, as carboxamidas): o benzovindiflupir, bixafeno, boscalid, cartoxina, fenfuram, fenexamida, fluopiram, flutolanil, fluxapiroxade, furametpir, isofetamida, isopirasame, mepronila, oxicarboxina, penflufen, pentiopirad, sedaxano, tecloftalam, tifluzamida, N-(4'- trifluorometilthiobifenil-2-il)-3-difluorometil-1-metil-1H-pirazol-4-carboxamida, N- (2-(1,3,3-trimetil-butil)-fenil)-1,3-dimetil-5-fluoro-1H-pirazol-4-carboxamida, 3- (difluorometil)-1-metil-N-(1,1,3-trimetilindan-4-il)pirazol-4-carboxamida, 3- (trifluorometil)-1-metil-N-(1,1,3-trimetilindan-4-il)pirazol-4-carboxamida, 1,3- dimetil-N-(1,1,3-trimetilindan-4-il)pirazol-4-carboxamida, 3-(trifluorometil)-1,5- dimetil-N-(1,1,3-trimetilindan-4-il)pirazol-4-carboxamida, 1,3,5- trimetil-N-(1,1,3-trimetilindan-4-il)pirazol-4-carboxamida, N-(7-fluoro-1,1,3-trimetil-indan-4-il)-1,3- dimetil-pirazol-4-carboxamida, N-[2-(2,4-diclorofenil)-2-metoxi-1-metil-etil]-3- (difluorometil)-1-metil-pirazol-4-carboxamida; - Outros inibidores da respiração (desacopladores do complexo I): o diflumetorim; (5,8-difluoro-quinazolin-4-il)-{2-[2-fluoro-4-(4-trifluorometilpiridin2-iloxi)-fenil]-etil}-amina; derivados de nitrofenila: o binapacril, dinobutona, dinocap, fluazinam; ferimzona; compostos organometálicos: os sais de fentina, tais como o acetato de fentina, cloreto de fentina ou hidróxido de fentina; ametoctradin; e siltiofame; (B') Inibidores da biossíntese de esteróis (fungicidas SBI) - inibidores da desmetilase de C14 (fungicidas DMI): triazóis: o azaconazol, bitertanol, bromuconazol, ciproconazol, difenoconazol, diniconazol, diniconazol-M, epoxiconazol, fenbuconazol, fluquinconazol, flusilazol, flutriafol, hexaconazol, imibenconazol, ipconazol, metconazol, miclobutanil, oxpoconazol, paclobutrazol, penconazol, propiconazol, protioconazol, simeconazol, tebuconazol, tetraconazol, triadimefona, triadimenol, triticonazol, uniconazol, 1- [rel-(2S,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)-oxiranilmetil]-5-tiocianato-1H- [1,2,4]triazol, 2-[rel-(2S,3R)-3-(2-clorofenil)-2-(2,4-difluorofenil)-oxiranil-metil]- 2H-[1,2,4]triazol-3-tiol, 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1- il)pentan-2-ol, 1-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-ciclopropil-2-(1,2,4- triazol-1-il)etanol, 2-[4-(4-clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazol-1- il)butan-2-ol, 2-[2-cloro-4-(4-clorofenoxi)fenil]-1-(1,2,4-triazol-1-il)butan-2-ol, 2- [4-(4-clorofenoxi)-2-(trifluorometil)-fenil]-3-metil-1-(1,2,4-triazol-1-il)butan-2-ol, 2- [4-(4-clorofenoxi)-2-(trifluorometil)-fenil]-1-(1,2,4-triazol-1-il)propan-2-ol, 2-[2- cloro-4-(4-clorofenoxi)fenil]-3-metil-1-(1,2,4-triazol-1-il)butan-2-ol, 2-[4-(4- clorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazol-1-il)pentan-2-ol, 2-[4-(4- fluorofenoxi)-2-(trifluorometil)fenil]-1-(1,2,4-triazol-1-il)-propan-2-ol; os imidazóis: o imazalil, pefurazoato, oxpoconazol, procloraz, triflumizol; as pirimidinas, piridinas e piperazinas: fenarimol, nuarimol, pirifenox, triforina, [3- (4-cloro-2-fluoro-fenil)-5-(2,4-difluorofenil)isoxazol-4-il]-(3-piridil)metanol; - Inibidores da reductase de Delta14: o aldimorf, dodemorf, acetato de dodemorf, fenepropimorf, tridemorf, fenpropidina, piperalina, espiroxamina; - Inibidores da reductase de 3-ceto: a fenexamida; (C’) Inibidores da síntese de ácidos nucleicos - os fungicidas das fenilamidas ou amino ácido de acila: o benalaxil, benalaxil-M, quiralaxil, metalaxil, metalaxil-M (mefenoxam), ofurace, oxadixil; - outros: himexazol, octilinona, ácido oxolínico, bupirimato, 5- fluorocitosina, 5-fluoro-2-(p-tolilmetoxil)pirimidin-4-amina, 5-fluoro-2-(4- fluorofenilmetoxi)pirimidin-4-amina; (D’) Inibidores da divisão celular e citoesqueleto - Inibidores da tubulina, tais como os benzimidazóis, tiofanatos: o benomil, carbendazim, fuberidazol, tiabendazol, tiofanato-metila; triazolopirimidinas: 5-cloro-7-(4-metil-piperidin-1-il)-6-(2,4,6-trifluorfenil)- [1,2,4]triazol[1,5-a]pirimidina; - outros inibidores da divisão celular: o dietofencarb, etaboxam, pencicurona, fluopicolida, zoxamida, metrafenona, piriofenona; (E’) Inibidores da síntese de amino ácidos e proteínas - inibidores da síntese de metionina (anilino-pirimidinas): o ciprodinil, mepanipirim, pirimetanil; - Inibidores da síntese de proteínas: o blasticidin-S, casugamicina, hidrato de cloridrato de casugamicina, mildiomicina, estreptomicina, oxitetraciclina, polioxina, validamicina A; (F’) Inibidores de transdução de sinal - Inibidores da quinase MAP / histidina: a fluoroimida, iprodiona, procimidona, vinclozolina, fenpiclonila, fludioxonila; - Inibidores da proteína G: a quinoxifena; (G’) Inibidores da síntese lipídeos e membrana - Inibidores da biossíntese de fosfolipídeos: os edifenfós, iprobenfós, pirazofó, isoprotiolana - Peroxidação de lipídeos: a diclorana, quintozena, tecnazeno, tolclofos-metila, bifenila, cloroneb, etridiazol; - Biossíntese de fosfolipídeos e deposição da parede celular: o dimetomorf, flumorf, mandiproamida, pirimorf, bentiavalicarb, iprovalicarb, valifenalato e éster de (4-fluorofenil) do ácido N-(1-(1-(4-ciano-fenil)- etanossulfonil)-but-2-il)-carbâmico; - Compostos que afetam a permeabilidade da membrana celular e dos ácidos graxos: o propamocarb, cloridrato de propamocarb - inibidores de hidrolase de amida de ácido graxo: a oxatiapiprolina, metanossulfonato 2-{3-[2-(1-{[3,5-bis(difluorometil-1H-pirazol-1- il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-diidro-1,2-oxazol-5-il}-fenila, metanossulfonato 2-{3-[2-(1-{[3,5-bis(difluorometil)-1H-pirazol-1- il]acetil}piperidin-4-il)-1,3-tiazol-4-il]-4,5-diidro-1,2-oxazol-5-il}-3clorofenila; (H’) Inibidores com ação multilocalizada - Substâncias ativas inorgânicas: a mistura Bordeaux, acetato de cobre, hidróxido de cobre, oxicloreto de cobre, sulfato básico de cobre, enxofre; - Tio- e ditiocarbamatos: o ferbam, mancozeb, maneb, metam, metiram, propineb, tiram, zineb, ziram; - Compostos organoclorados (por exemplo, as ftalimidas, sulfamidas, cloronitrilos): a anilazina, clorotalonil, captafol, captan, folpet, diclofluanida, diclorofeno, flusulfamida, hexaclorobenzeno, pentaclorfenol e seus sais, ftalida, tolilfluanida, N-(4-cloro-2-nitro-fenil)-N-etil-4-metilbenzenossulfonamida; - Guanidinas e outros: a guanidina, dodina, base livre de dodina, guazatina, acetato de guazatina, iminoctadina, triacetato de iminoctadina, tris(albesilato) de iminoctadina, ditianona, 2,6-dimetil-1H,5H-[1,4]ditiino[2,3- c:5,6-c’]dipirrol-1,3,5,7(2H,6H)-tetraona; (I’) Inibidores da biossíntese da parede celular - Inibidores da síntese de glucano: a validamicina, polioxina B, inibidores da síntese de melanina: piroquilona, triciclazol, carpropamida, diciclomet, fenoxanil; (J’) Indutores de defesa dos vegetais - a acibenzolar-S-metila, probenazola, isotianil, tiadinil, proexadiona-cálcio, os fosfatos: fosetil, fosetil-alumínio, ácido fosfórico e seus sais; (K’) Modo de ação desconhecido - o bronopol, quinometinato, ciflufenamida, cimoxanil, dazomet, debacarb, diclomezina, difenzoquat, metilssulfato de difenzoquat, difenilamina, fenepirazamina, flumetover, flusulfamida, flutianil, metassulfocarb, nitrapirina, nitrotal de isopropila, oxatiapiprolina, tolprocarb, 2-[3,5-bis(difluorometil)-1Hpirazol-1-il]-1-[4-(4-{5-[2-(prop-2-in-1-iloxi)fenil]-4,5-diidro-1,2-oxazol-3-il}-1,3- tiazol-2-il)piperidin-1-il]etanona, 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4- {5-[2-fluoro-6-(prop-2-in-1-iloxi)fenil]-4,5-diidro-1,2-oxazol-3-il}-1,3-tiazol-2- il)piperidin-1-il]etanona, 2-[3,5-bis(difluorometil)-1H-pirazol-1-il]-1-[4-(4-{5-[2- cloro-6-(prop-2-in-1-iloxi)fenil]-4,5-diidro-1,2-oxazol-3-il}-1,3-tiazol-2il)piperidin1-il]etanona, oxina de cobre, proquinazid, tebufloquina, tecloftalam, triazoxida, 2-butoxi-6-iodo-3-propilcromen-4-ona, 2-butoxi-6-iodo-3-propilcromen-4-ona, N- (ciclopropilmetoxiimino-(6-difluoro-metoxi-2,3-difluoro-fenil)-metil)-2-fenilacetamida, N'-(4-(4-cloro-3-trifluorometil-fenoxi)-2,5-dimetil-fenil)-N-etil-N-metilformamidina, N'-(4-(4-fluoro-3-trifluorometil-fenoxi)-2,5-dimetil-fenil)-N-etil-Nmetil-formamidina, N’-(2-metil-5-trifluorometil-4-(3-trimetil-silanil-propoxi)-fenil)-N-etil-N-metil formamidina, formamidina do N’-(5-difluorometil-2-metil-4-(3- trimetilsilanil-propoxi)-fenil)-N-etil-N-metila, éster do ácido metoxi-acético 6-tercbutil-8-fluoro-2,3-dimetil-quinolin-4-il, 3-[5-(4-metilfenil)-2,3-dimetil-isoxazolidin3-il]-piridina, 3-[5-(4-cloro-fenil)-2,3-dimetil-isoxazolidin-3-il]-piridina (pirisoxazol), amida do ácido N-(6-metoxi-piridin-3-il)ciclopropanocarboxílico, 5- cloro-1-(4,6-dimetoxi-pirimidin-2-il)-2-metil-1H-benzoimidazol, 2-(4-cloro-fenil)- N-[4-(3,4-dimetoxi-fenil)-isoxazol-5-il]-2-prop-2-iniloxi-acetamida, (Z)-3-amino-2- ciano-3-fenil-prop-2-enoato de etila, N-[6-[[(Z)-[(1-metiltetrazol-5-il)-fenilmetileno]amino ]oximetil]-2-piridil]carbamato de terc-butila (picarbutrazox), N-[6- [[(Z)-[(1-metiltetrazol-5-il)-fenil-metileno]oximetil]-2-piridil]carbamato de pentila, 2-[2-[(7,8-difluoro-2-metil-3-quinolil)oxi]-6-fluoro-fenil]propan-2-ol, 2-[2-fluoro-6- [(8-fluoro-2-metil-3-quinolil)oxi]fenil]propan-2-ol, 3-(5-fluoro-3,3,4,4-tetrametil3,4-diidroisoquinolin-1-il)-quinolina, 3-(4,4-difluoro-3,3-dimetil-3,4- diidroisoquinolin-1-il)quinolina, 3-(4,4,5-trifluoro-3,3-dimetil-3,4-diidroisoquinolin1-il)quinolona, 9-fluoro-2,2-dimetil-5-(3-quinolil)-3H-1,4-benzoxazepina; (M') Reguladores de crescimento - ácido abscísico, amidoclor, ancimidol, 6-benzilaminopurina, brassinolida, butralina, clormequato (cloreto de clormequato), cloreto de colina, ciclanilida, daminozida, diquegulac, dimetipina, 2,6-dimetilpuridina, etefona, flumetralina, flurprimidol, flutiaceto, forclorfenurona, giberelina, inabenfide, ácido indol-3-acético, hidrazida maleica, mefluidida, mepiquato (cloreto de mepiquato), ácido naftalenoacético, N-6-benziladenina, paclobutrazol, prohexadiona (prohexadiona de cálcio), proidrojasmona, tidiazurona, triapentenol, fosforotritioato de tributila, ácido 2,3,5-triiodobenzóico, trinexapacetila e uniconazol; (N') Herbicidas - acetamidas: acetoclor, alaclor, butaclor, dimetacloro, dimetenamida, flufenacete, mefenacet, metolacloro, metazacloro, napropamida, naproanilida, petoxamida, pretilaclor, propacloro, tenilcloro; - derivados de aminoácidos: os bilanafós, glifosato, glufosinato, sulfosato; - os ariloxifenoxipropionatos: o clodinafop, cihalofop-butila, fenoxaprop, fluazifop, haloxifop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefurila; - as bipiridilas: o diquat, paraquat; - os (tio)carbamatos: o asulam, butilato, carbetamida, desmedifam, dimepiperato, eptam (EPTC), esprocarb, molinato, orbencarb, fenemedifam, prosulfocarb, piributicarb, tiobencarb, trialato; - as cicloexanedionas: o butroxidim, cletodim, cicloxidim, profoxidim, setoxidim, tepraloxidim, tralcoxidim; - as dinitroanilinas: a benfluralina, etalfluralina, orizalin, pendimetalina, prodiamina, trifluralina; - os éteres difenílicos: o acifluorfeno, aclonifeno, bifenox, diclofop, etoxifen, fomesafeno, lactofeno, oxifluorfem; - as hidroxibenzonitrilas: a bromoxinila, diclobenila, ioxinil; - as imidazolinonas: o imazametabenz, imazamox, imazapic, imazapir, imazaquin, imazetapir; - os ácidos fenoxiacéticos: o clomeprop, ácido acético 2,4- diclorofenoxi (2,4-D), 2,4-DB, diclorprop, MCPA, MCPA-tioetila, MCPB, mecoprop; - as pirazinas: a cloridazona, flufenpir-etila, flutiacet, norflurazona, piridato; - as piridinas: o aminopiralid, clopiralida, diflufenican, ditiopir, fluridona, fluroxipir, picloram, picolinafeno, tiazopir; - as sulfonilureias: a amidosulfurona, azimsulfurona, benasulfurona, clorimuron-etila, clorassulfurona, cinossulfurona, ciclossulfamurona, etoxissulfurona, flazassulfurona, flucetossulfurona, flupirssulfurona, foramssulfurona, halossulfurona, imazossulfurona, iodossulfurona, mesossulfurona, mesoasulforona, mesoasulforona-metila, nicossulfurona, oxassulfurona, primissulfurona, prossulfurona, pirazossulfurona, rimsulfurona, sulfometurona, sulfossulfurona, tifenssulfurona, triassulfurona, tribenurona, trifloxissulfurona, triflussulfurona, tritossulfurona, 1-((2-cloro-6- propil-imidazo[1,2-b]piridazin-3-il)sulfonil)-3-(4,6-dimetoxipirimidin-2-il)ureia; - as triazinas: a ametrina, atrazina, cianazina, dimetametrina, etiozina, hexazinona, metamitron, metribuzin, prometrina, simazina, terbutilazina, terbutrina, triaziflam; - as ureias: a clorotolurona, daimurona, diurona, fluometurona, isoproturona, linurona, metabenzo-tiazurona, tebutiurona, trifludimoxazina; - outros inibidores da sintetase do acetolactato: o sódio de bispiribaco, cloransulam-metila, diclosulam, florasulam, flucarbazona, flumetsulam, metosulam, ortossulfamurona, penoxsulam, propoxicarbazona, piribambenz-propil, piribenzoxim, piriftalid, piriminobac-metila, pirimisulfana, piritiobac, piroxasulfona, piroxsulam; - outros: a amicarbazona, aminotriazol, anilofós, beflubutamida, benazolina, bencarbazona, benfluresato, benzofenap, bentazona, benzobiciclona, biciclopirona, bromacila, bromobutida, butafenacila, butamifós, cafenstrol, carfentrazona, cinidona-etila, clortal, cinmetilina, clomazona, cumilurona, ciprosulfamida, dicamba, difenzoquat, diflufenzopir, Drechslera monoceras, endotal, etofumesato, etobenzanida, fenoxassulfona, fentrazamida, flumiclorac-pentila, flumioxazina, flupoxam, fluorocloridona, flurtamona, indanofan, isoxaben, isoxaflutol, lenacil, propanil, propizamida, quinclorac, quinmeracmesotriona, ácido metilarsênico, naptalam, oxadiargil, oxadiazon, oxaziclomefona, pentoxazona, pinoxadeno, piraclonil, piraflufen-etila, pirasulfotol, pirazoxifen, pirazolinato, quinoclamina, saflufenacil, sulcotriona, sulfentrazona, terbacil, tefuriltriona, tembotriona, tiencarbazona, topramezona, éster de etila do ácido (3-[2-cloro-4-fluoro-5-(3-metil-2,6-dioxo-4-trifluorometil3,6-diidro-2H-pirimidin-1-il)fenoxi]piridin-2-iloxi)acético, éster de metila do ácido 6-amino-5-cloro-2-ciclopropilpirimidina-4-carboxílico, 6-cloro-3-(2-ciclopropil-6- metilfenoxi)-piridazin-4-ol, ácido 4-amino-3-cloro-6-(4-clorofenil)-5-fluoro-piridin2-carboxílico, éster de metila do ácido 4-amino-3-cloro-6-(4-cloro-2-fluoro-3- metoxi-fenil)-piridin-2-carboxílico e éster de metila do ácido 4-amino-3-cloro-6- (4-cloro-3-dimetilamino-2-fluoro-fenil)-piridin-2-carboxílico. (O’) Inseticidas - os organo(tio)fosfatos: o acefato, azametifós, azinfós-metila, clorpirifós, clorpirifós-metila, clorfenvinfós, diazinon, diclorvos, dicrotofos, dimetoato, dissulfoton, etiona, fenitrotiona, fentiona, isoxationa, malationa, metamidofós, metidationa, paration-metila, mevinfós, monocrotofós, oxidemeton-metila, paraoxon, parationa, fentoato, fosalona, fosmet, fosfamidona, forato, foxima, pirimifós-metila, profenofós, protiofós, sulprofós, tetraclorvinfós, terbufós, triazofós e triclorfona; - os carbamatos: o alanicarb, aldicarb, bendiocarb, benfuracarb, carbaril, carbofuran, carbosulfan, fenoxicarb, furatiocarb, metiocarb, metomila, oxamila, pirimicarb, propoxur, tiodicarb e triazamato; - os piretróides: a aletrina, bifentrina, ciflutrina, cialotrina, cifenotrina, cipermetrina, alfa-cipermetrina, beta-cipermetrina, zetacipermetrina, deltametrina, esfenvalerato, etofenprox, fenpropatrina, fenvalerato, imiprotrina, lambda-cialotrina, permetrina, praletrina, piretrina I e II, resmetrina, silafluofem, tau-fluvalinato, teflutrina, tetrametrina, tralometrina, transflutrina, proflutrina, dimeflutrina; - os reguladores do crescimento dos insetos: (a) os inibidores da síntese de quitina: as benzoilureias, clorfluazurona, ciramazina, diflubenzurona, flucicloxurona, flufenoxurona, hexaflumurona, lufenurona, novalurona, teflubenzurona, triflumurona; buprofezina, diofenolano, hexitiazox, etoxazol e clofentazina; (b) os antagonistas da ecdisona: a halofenozida, metoxifenozida, tebufenozida e azadiractina; (c) os juvenóides: o piriproxifeno, metopreno, fenoxicarbe e (d) os inibidores da biossíntese de lipídios: o espirodiclofeno, espiromesifeno, espirotetramato; - os compostos agonistas / antagonistas receptores nicotínicos: a clotianidina, dinotefuran, imidacloprida, tiametoxam, nitenpiram, acetamiprida, tiacloprida, 1-(2-cloro-tiazol-5-ilmetil)-2-nitrimino-3,5-dimetil-[1,3,5]triazinana; - os compostos antagonistas de GABA: o endosulfan, etiprol, fipronila, vaniliprol, pirafluprol, piriprol, amida do ácido 5-amino-1-(2,6-dicloro-4- metil-fenil)-4-sulfinamoil-1H-pirazol-3-carbotióico; - os inseticidas das lactonas macrocíclicas: a abamectina, emamectina, milbemectina, lepimectina, espirosad, espinetoram; - os acaricidas do inibidor de transporte de elétrons mitocondrial (METI) I: a fenazaquina, piridabeno, tebufenpirada, tolfenpirad, flufenerim; - os compostos METI Il e III: a acequinocila, fluaciprim, hidrametilnona; - os desacopladores: o clorfenapir; - os inibidores da fosforilação oxidativa: a cihexatina, diafentiuron, óxido de fenbutatin, propargita; - os compostos disruptores da troca de penas: a ciromazina; - os inibidores da oxidase de função mista: o butóxido de piperonila; - os compostos bloqueadores do canal de sódio: o indoxacarb e metaflumizona; - os inibidores do receptor de rianodina: o clorantraniliprol, ciantraniliprol, flubendiamida, N-[4,6-dicloro-2-[(dietil-lambda-4- sulfaniliden)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4-cloro-2-[(dietil-lambda-4-sulfaniliden)carbamoil]-6-metilfenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; N-[4-cloro-2- [(di-2-propil-lambda-4-sulfaniliden)carbamoil]-6-metil-fenil]-2-(3-cloro-2-piridil)-5- (trifluorometil)pirazol-3-carboxamida; N-[4,6-dicloro-2-[(di-2-propil-lambda-4- sulfaniliden)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3- carboxamida; N-[4,6-dicloro-2-[(dietil-lambda-4-sulfaniliden)carbamoil]-fenil]-2- (3-cloro-2-piridil)-5-(difluorometil)pirazol-3-carboxamida; N-[4,6-dibromo-2-[(di2-propil-lambda-4-sulfaniliden)carbamoil]-fenil]-2-(3-cloro-2-piridil)-5- (trifluorometil)pirazol-3-carboxamida; N-[4-cloro-2-[(di-2-propil-lambda-4- sulfaniliden)carbamoil]-6-ciano-fenil]-2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol3-carboxamida; N-[4,6-dibromo-2-[(dietil-lambda-4-sulfaniliden)carbamoil]-fenil]- 2-(3-cloro-2-piridil)-5-(trifluorometil)pirazol-3-carboxamida; - outros: o benclotiaz, bifenazato, cartap, flonicamida, piridalila, pimetrozina, enxôfre, tiociclam, cienopirafeno, flupirazofos, ciflumetofen, amidoflumet, imiciafós, bistrifluron, pirifluquinazon e éster de ácido ciclopropanacético 1,1'-[(3S,4R,4aR,6S,6aS,12R,12aS,12bS)-4-[[(2- ciclopropilacetil)oxi]metil]-1,3,4,4a,5,6,6a,12,12a,12b-decaidro-12-hidroxi4,6a,12b-trimetil-11-oxo-9-(3-piridinil)-2H,11H-nafto[2,1-b]piran[3,4-e]piran-3,6- diil]. [0302] In accordance with the present invention, it may be preferred that the three-component compositions comprise, in addition to component I and component II, a component III which is selected from an additional active compound, preferably in an amount synergistically effective. In particular, according to this realization, component III is selected from the following compounds of groups (A ') (A ') Breathing inhibitors - Qo site complex III inhibitors (for example, strobilurins): azoxystrobin, coumetoxistrobin, coumoxystrobin, dimoxystrobin, enestroburin, phenaminstrobin, phenoxystrobin / fluphenoxystrobin, methoxystrobin, pyrostrobin, pyrostrobin, pyrostrostrin, pyrostrobin, pyrostrobin, pyrinostrobin, pyridine, pyridine , 2- [2- (2,5-dimethyl-phenoxymethyl) -phenyl] -3-methoxy-acrylic acid methyl ester, and 2- (2- (3- (2,6-di-chlorophenyl) -1 -methyl-alliliden-aminooxy-methyl) -phenyl) -2-methoxyimino-Nmethyl-acetamide, pyribencarb, triclopyricarb / chlorodincarb, famoxadone, phenamidone; - Complex III inhibitors at the Qi site: [(3S, 6S, 7R, 8R) -8-benzyl-3 - [(3-acetoxy-4-methoxy-pyridine-2-carbonyl] 2-methylpropanoate ) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], [(3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (acetoxymethoxy) -4-methoxypyridine-2-carbonyl] amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl], [(3S, 6S, 7R, 8R) 2-methylpropanoate -8-benzyl-3 - [(((3-isobutoxycarbonyloxy-4-methoxypyridin-2-carbonyl) amino] -6-methyl-4,9-dioxo-1,5-dioxonan-7-yl, 2-methylpropanoate 3S, 6S, 7R, 8R) -8-benzyl-3 - [[3- (1,3-benzodioxol-5-ylmethoxy) -4-methoxy-pyridin-2-carbonyl] amino] -6-methyl-4, 9-di-oxo-1,5-dioxonan-7-yl], 3S, 6S, 7R, 8R 2-methylpropanoate -3 - [[((3-hydroxy-4-methoxy-2-pyridinyl) carbonyl] amino ] -6-methyl-4,9-dioxo-8- (phenylmethyl) -1,5-di-dioxonan-7-yl; - Complex II inhibitors (for example, carboxamides): benzovindiflupir, bixafen, boscalid, cartoxine, fenfuram, fenexamide, fluopiram, flutolanil, fluxpyroxade, furametpir, isofetamide, isopirasame, mepronil, oxycarboxine, penhofaden, pentufaden, pentufaden, pentufaden, pentufaden, pentufaden, pentufaden, pentufaden, pentufamenium tifluzamide, N- (4'-trifluoromethylthiobiphenyl-2-yl) -3-difluoromethyl-1-methyl-1H-pyrazol-4-carboxamide, N- (2- (1,3,3-trimethyl-butyl) -phenyl) -1,3-dimethyl-5-fluoro-1H-pyrazol-4-carboxamide, 3- (difluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazole-4-carboxamide, 3- (trifluoromethyl) -1-methyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3-dimethyl-N- (1,1,3-trimethylindan-4- il) pyrazol-4-carboxamide, 3- (trifluoromethyl) -1,5-dimethyl-N- (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, 1,3,5-trimethyl-N - (1,1,3-trimethylindan-4-yl) pyrazol-4-carboxamide, N- (7-fluoro-1,1,3-trimethyl-indan-4-yl) -1,3-dimethyl-pyrazole- 4-carboxamide, N- [2- (2,4-dichlorophenyl) -2-methoxy-1-methyl-ethyl] -3- (difluoromethyl) -1-methyl-pyrazole-4-carb oxamide; - Other respiration inhibitors (complex I uncouplers): diflumetorim; (5,8-difluoro-quinazolin-4-yl) - {2- [2-fluoro-4- (4-trifluoromethylpyridin2-yloxy) -phenyl] -ethyl} -amine; nitrophenyl derivatives: binapacril, dinobutone, dinocap, fluazinam; ferimzone; organometallic compounds: phentin salts, such as phentin acetate, fentin chloride or fentin hydroxide; ametoctradin; and siltiofam; (B ') Sterol biosynthesis inhibitors (SBI fungicides) - C14 demethylase inhibitors (DMI fungicides): triazoles: azaconazole, bitertanol, bromuconazole, cyproconazole, diphenoconazole, diniconazole, diniconazole-M, epoxiconazole, fenbuconazole, fluquinconazole, flusilazole, methanol, hexazolone, oxpoconazole, paclobutrazol, penconazole, propiconazole, protioconazole, simeconazole, tebuconazole, tetraconazole, triadimefone, triadimenol, triticonazole, uniconazole, 1- [rel- (2S, 3R) -3- (2-chlorophenyl) -2- (2,4- difluorophenyl) -oxyranylmethyl] -5-thiocyanate-1H- [1,2,4] triazole, 2- [rel- (2S, 3R) -3- (2-chlorophenyl) -2- (2,4-difluorophenyl) - oxiranyl-methyl] - 2H- [1,2,4] triazole-3-thiol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -1- (1,2,4-triazole-1- il) pentan-2-ol, 1- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1-cyclopropyl-2- (1,2,4-triazol-1-yl) ethanol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [2-chloro-4- (4- chlorophenoxy) phenyl] -1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluor omethyl) -phenyl] -3-methyl-1- (1,2,4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) -phenyl] -1- (1,2,4-triazol-1-yl) propan-2-ol, 2- [2-chloro-4- (4-chlorophenoxy) phenyl] -3-methyl-1- (1,2, 4-triazol-1-yl) butan-2-ol, 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) pentan- 2-ol, 2- [4- (4-fluorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) -propan-2-ol; imidazoles: imazalil, pefurazoate, oxpoconazole, prochloraz, triflumizole; pyrimidines, pyridines and piperazines: fenarimol, nuarimol, pyrifenox, triforin, [3- (4-chloro-2-fluoro-phenyl) -5- (2,4-difluorophenyl) isoxazol-4-yl] - (3-pyridyl )methanol; - Delta14 reductase inhibitors: aldimorf, dodemorf, dodemorf acetate, fenpropimorf, tridemorf, fenpropidina, piperalina, spiroxamina; - 3-keto reductase inhibitors: fenexamide; (C ') Inhibitors of nucleic acid synthesis - the fungicides of the phenylamides or acyl amino acid: benalaxyl, benalaxyl-M, chiralaxyl, metalaxyl, metalaxyl-M (mefenoxam), ofurace, oxadixil; - others: himexazole, octylinone, oxolinic acid, bupyrime, 5-fluoro-cytosine, 5-fluoro-2- (p-tolylmethoxy) pyrimidin-4-amine, 5-fluoro-2- (4-fluorophenylmethoxy) pyrimidin-4-amine; (D ') Cell division and cytoskeleton inhibitors - Tubulin inhibitors, such as benzimidazoles, thiophanates: benomyl, carbendazim, fuberidazole, thiabendazole, thiophanate-methyl; triazolopyrimidines: 5-chloro-7- (4-methyl-piperidin-1-yl) -6- (2,4,6-trifluorphenyl) - [1,2,4] triazole [1,5-a] pyrimidine; - other cell division inhibitors: dietofencarb, etaboxam, pencicurone, fluopicolide, zoxamide, metrafenone, pyriophenone; (E ') Inhibitors of the synthesis of amino acids and proteins - inhibitors of methionine synthesis (anilino-pyrimidines): cyprodinil, mepanipyrim, pyrimethanil; - Protein synthesis inhibitors: blasticidin-S, casugamycin, casugamycin hydrochloride hydrate, mildiomycin, streptomycin, oxytetracycline, polyoxin, validamycin A; (F ') Signal transduction inhibitors - MAP / histidine kinase inhibitors: fluoroimide, iprodione, procymidone, vinclozoline, fenpiclonil, fludioxonil; - Protein G inhibitors: quinoxyfen; (G ') Lipid and membrane synthesis inhibitors - Phospholipid biosynthesis inhibitors: the edifenfós, iprobenfós, pyrazofó, isoprothiolana - Peroxidation of lipids: dichloran, quintinto, tecnazene, tolclofos-methyl, biphenyl, cloroneb, etridiazole; - Phospholipid biosynthesis and cell wall deposition: dimetomorf, flumorf, mandiproamide, pyrimorf, bentiavalicarb, iprovalicarb, valifenalate and N- (1- (1- (1- (4-cyano-phenyl) acid - ester (4-fluorophenyl) - ethanesulfonyl) -but-2-yl) -carbamic; - Compounds that affect the permeability of the cell membrane and fatty acids: propamocarb, propamocarb hydrochloride - fatty acid amide hydrolase inhibitors: oxatiapiproline, methanesulfonate 2- {3- [2- (1 - {[3,5-bis (difluoromethyl-1H-pyrazol-1-yl] acetyl} piperidin-4-yl ) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} -phenyl, methanesulfonate 2- {3- [2- (1 - {[3,5- bis (difluoromethyl) -1H-pyrazol-1-yl] acetyl} piperidin-4-yl) -1,3-thiazol-4-yl] -4,5-dihydro-1,2-oxazol-5-yl} - 3 chlorophenyl; (H ') Inhibitors with multilocated action - Inorganic active substances: the Bordeaux mixture, copper acetate, copper hydroxide, copper oxychloride, basic copper sulfate, sulfur; - Uncle- and dithiocarbamates: ferbam, mancozeb, maneb, metam, metiram, propineb, tiram, zineb, ziram; - Organochlorine compounds (eg phthalimides, sulfamides, chloronitriles): anilazine, chlorotalonil, captafol, captan, folpet, diclofluanide, dichlorophene, flusulfamide, hexachlorobenzene, pentachlorphenol and their salts, phthalide, tolylfluanide, N 2-nitro-phenyl) -N-ethyl-4-methylbenzenesulfonamide; - Guanidines and others: guanidine, dodine, dodine free base, guazatin, guazatin acetate, iminoctadine, iminoctadine triacetate, iminoctadine tris (albesylate), dithianone, 2,6-dimethyl-1H, 5H- [1,4 ] dithinoine [2,3-c: 5,6-c '] dipyrrol-1,3,5,7 (2H, 6H) -tetraone; (I ') Inhibitors of cell wall biosynthesis - Glucan synthesis inhibitors: validamycin, polyoxin B, melanin synthesis inhibitors: pyrokylone, tricyclazole, carpropamide, dicyclomethane, phenoxanil; (J ') Vegetable defense inducers - acibenzolar-S-methyl, probenazole, isothianyl, thiadinyl, proexadione-calcium, phosphates: fosetil, fosetil-aluminum, phosphoric acid and its salts; (K ') Unknown mode of action - bronopol, quinomethinate, cyflufenamide, cymoxanil, dazomet, debacarb, diclomezine, difenzoquat, difenzoquat methylsulfate, diphenylamine, phenepyrazamine, flumetover, flusulfamide, flutyanil, metasulfocarb, nitrapirine, tolopropine, tolopropoline, tolopropine, tolopropine -bis (difluoromethyl) -1Hpyazol-1-yl] -1- [4- (4- {5- [2- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2 -oxazol-3-yl} -1,3-thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -1- [ 4- (4- {5- [2-fluoro-6- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3- thiazol-2-yl) piperidin-1-yl] ethanone, 2- [3,5-bis (difluoromethyl) -1H-pyrazol-1-yl] -1- [4- (4- {5- [2- chlorine -6- (prop-2-in-1-yloxy) phenyl] -4,5-dihydro-1,2-oxazol-3-yl} -1,3-thiazol-2yl) piperidin1-yl] ethanone, copper, proquinazid, tebufloquine, keyboardoftalam, triazoxide, 2-butoxy-6-iodo-3-propylchromen-4-one, 2-butoxy-6-iodo-3-propylchromen-4-one, N- (cyclopropylmethoxyimino- (6- difluoro-methoxy-2,3-difluoro-phenyl) -methyl) -2-phenylacetamide, N '- (4- (4-chloro- 3-trifluoromethyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl-N-methylformamidine, N '- (4- (4-fluoro-3-trifluoromethyl-phenoxy) -2,5-dimethyl-phenyl) -N-ethyl-Nmethyl-formamidine, N '- (2-methyl-5-trifluoromethyl-4- (3-trimethyl-silanyl-propoxy) -phenyl) -N-ethyl-N-methyl formamidine, N'- formamidine (5-difluoromethyl-2-methyl-4- (3-trimethylsilanyl-propoxy) -phenyl) -N-ethyl-N-methyl, methoxy-acetic acid ester 6-tert-butyl-8-fluoro-2,3-dimethyl- quinolin-4-yl, 3- [5- (4-methylphenyl) -2,3-dimethyl-isoxazolidin3-yl] -pyridine, 3- [5- (4-chloro-phenyl) -2,3-dimethyl-isoxazolidin -3-yl] -pyridine (pyrisoxazole), N- (6-methoxy-pyridin-3-yl) cyclopropanecarboxylic acid amide, 5-chloro-1- (4,6-dimethoxy-pyrimidin-2-yl) -2 -methyl-1H-benzoimidazole, 2- (4-chloro-phenyl) - N- [4- (3,4-dimethoxy-phenyl) -isoxazol-5-yl] -2-prop-2-inyloxy-acetamide, ( Z) -3-amino-2-cyano-3-phenyl-prop-2-enoate, ethyl N- [6 - [[((Z) - [(1-methyltetrazol-5-yl) -phenylmethylene] amino] oxymethyl ] -2-pyridyl] tert-butyl carbamate (picarbutrazox), N- [6- [[(Z) - [(1-methyltetrazol-5-yl) -phenyl-me tylene] oxymethyl] -2-pyridyl] pentyl carbamate, 2- [2 - [(7,8-difluoro-2-methyl-3-quinolyl) oxy] -6-fluoro-phenyl] propan-2-ol, 2 - [2-fluoro-6- [(8-fluoro-2-methyl-3-quinolyl) oxy] phenyl] propan-2-ol, 3- (5-fluoro-3,3,4,4-tetramethyl3,4 -dihydroisoquinolin-1-yl) -quinoline, 3- (4,4-difluoro-3,3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinoline, 3- (4,4,5-trifluoro-3, 3-dimethyl-3,4-dihydroisoquinolin-1-yl) quinolone, 9-fluoro-2,2-dimethyl-5- (3-quinolyl) -3H-1,4-benzoxazepine; (M ') Growth regulators - abscisic acid, amidochlor, ancimidol, 6-benzylaminopurine, brassinolid, butralin, clormequate (chlormequate chloride), choline chloride, cyclanilide, daminozide, diquegulac, dimethypine, 2,6-dimethylpuridine, etefone, flumetridine, flumetrine, flumetrine, flumetrine, flumetrine, flumetrine, flumetrine, flumetrine , gibberellin, inabenfide, indole-3-acetic acid, maleic hydrazide, mefluidide, mepiquate (mepiquate chloride), naphthalene acetic acid, N-6-benzyladenine, paclobutrazol, prohexadione (calcium prohexadione, tridyrosone, triazone, triazide, triazide, tridia tributyl, 2,3,5-triiodobenzoic acid, trinexapacetyl and uniconazole; (N ') Herbicides - acetamides: acetochlor, alachlor, butachlor, dimetachlor, dimethenamide, flufenacet, mefenacet, metolachlor, metazachlor, napropamide, naproanilide, petoxamide, pretilachlor, propachlor, tenilchlor; - amino acid derivatives: bilanafos, glyphosate, glufosinate, sulfosate; - aryloxyphenoxypropionates: clodinafop, cihalofop-butyl, fenoxaprop, fluazifop, haloxifop, metamifop, propaquizafop, quizalofop, quizalofop-P-tefuril; - bipyridyls: diquat, paraquat; - (thio) carbamates: o asulam, butylate, carbetamide, demedifam, dimepiperate, eptam (EPTC), esprocarb, molinate, orbencarb, fenemedifam, prosulfocarb, pyributicarb, thiobencarb, trialate; - cyclohexanediones: butroxidim, cletodim, cycloxidim, profoxidim, setoxidim, tepraloxidim, tralcoxidim; - dinitroanilines: benfluralin, etalfluralin, orizalin, pendimethalin, prodiamine, trifluralin; - diphenyl ethers: acifluorfen, aclonifene, bifenox, diclofop, ethoxyfen, fomesafen, lactofene, oxyfluorfen; - hydroxybenzonitriles: bromoxynil, diclobenyl, ioxynil; - imidazolinones: imazametabenz, imazamox, imazapic, imazapyr, imazaquin, imazetapyr; - phenoxyacetic acids: clomeprop, acetic acid 2,4-dichlorophenoxy (2,4-D), 2,4-DB, dichlorprop, MCPA, MCPA-thioethyl, MCPB, mecoprop; - pyrazines: chloridazone, flufenpirethyl, flutiacet, norflurazone, pyridate; - pyridines: aminopyralid, clopyralide, diflufenican, dithiopir, fluridone, fluroxypyr, picloram, picolinafen, thiazopyr; - sulfonylureas: a amidosulfurona, azimsulfurona, benasulfurona, chlorimuron-ethyl, clorassulfurona, cinossulfurona, ciclossulfamurona, etoxissulfurona, flazassulfurona, flucetossulfurona, flupirssulfurona, foramssulfurona, halossulfurona, imazossulfurona, iodossulfurona, mesossulfurona, mesoasulforona, mesoasulforona-methyl, nicossulfurona, oxassulfurona, primissulfurona , prosulfurone, pyrazosulfurone, rimsulfurone, sulfometurone, sulfosulfurone, thifensulfurone, triasulfurone, tribenurone, trifloxysulfurone, triflussulfurone, tritosulfurone, 1 - ((2-chloro-6-propyl-imidazo [1,2-b-3-pyron)-1,2-b-pyridine] 1,2 ) -3- (4,6-dimethoxypyrimidin-2-yl) urea; - triazines: ametrine, atrazine, cyanazine, dimetamethrin, ethiozine, hexazinone, metamitron, metribuzin, promethrin, simazine, terbuthylazine, terbutrin, triaziflam; - urea: chlorotolurone, daimurone, diurone, fluometurone, isoproturone, linurone, metabenzo-thiazurone, tebutiurone, trifludimoxazine; - other acetolactate synthase inhibitors: bispiribac sodium, chloransulam-methyl, diclosulam, florasulam, flucarbazone, flumetsulam, metosulam, orthosulfamurone, penoxsulam, propoxycarbazone, piribambenz-propyl, pyribenzoxim, pyribenzamine, pyribenzone , pyroxsulam; - others: amicarbazone, aminotriazole, anilofós, beflubutamide, benazolin, bencarbazone, benfluresate, benzofenap, bentazone, benzobicyclone, bicyclopyrone, bromacila, bromobutide, butafenacil, butamiphos, cinenstrone, cinenstrol, carthytrone, cinthyrone, carcinone, cyril, cyprosulfamide, dicamba, difenzoquat, diflufenzopyr, Drechslera monoceras, endotal, etofumesate, etobenzanide, phenoxasulfone, fentrazamide, flumichlorac-pentila, flumioxazin, flupoxam, fluorochloridone, flurtamone, quanofil, propanyl, isoxan, isoxan, islamaban, methylaryl, naptalam, oxadiargyl, oxadiazon, oxaziclomefone, pentoxazone, pinoxadene, piraclonil, piraflufen-ethyl, pirasulfotol, pyrazoxifen, pyrazolinate, quinoclamine, saflufenacil, sulcotrione, ethydrone, terbazone, terbazone, terbazone, terbazone 3- [2-chloro-4-fluoro-5- (3-methyl-2,6-dioxo-4-trifluoromethyl3,6-dihydro-2H-pyrimi din-1-yl) phenoxy] pyridin-2-yloxy) acetic, 6-amino-5-chloro-2-cyclopropylpyrimidine-4-carboxylic acid methyl ester, 6-chloro-3- (2-cyclopropyl-6- methylphenoxy) -pyridazin-4-ol, 4-amino-3-chloro-6- (4-chlorophenyl) -5-fluoro-pyridin2-carboxylic acid, 4-amino-3-chloro-6- acid methyl ester ( 4-chloro-2-fluoro-3-methoxy-phenyl) -pyridin-2-carboxylic acid and 4-amino-3-chloro-6- (4-chloro-3-dimethylamino-2-fluoro-phenyl) methyl ester ) -pyridin-2-carboxylic. (O ') Insecticides - the organo (uncle) phosphates: the asphate, azametiphos, azinphos-methyl, chlorpyrifos, chlorpyrifos-methyl, chlorfenviphos, diazinon, dichlorvos, dicrotophos, dimetoate, disulfoton, etione, fenitrotiona, fentiona, isoxathione, methalation, methalation, methalation -methyl, mevinfós, monocrotofós, oxidemeton-methyl, paraoxon, parathione, fentoate, fosalone, fosmet, phosphamidone, forato, foxima, pirimiphos-methyl, profenofós, protiofós, sulprofós, tetrachlorvinfós, terbufós, triazofós and trorfona; - carbamates: alanicarb, aldicarb, bendiocarb, benfuracarb, carbaryl, carbofuran, carbosulfan, phenoxycarb, furatiocarb, metiocarb, methomyl, oxamyl, pirimicarb, propoxur, tiodicarb and triazamate; - pyrethroids: alethrin, bifenthrin, cyflothrin, cyhalothrin, cyphenothrin, cypermethrin, alpha-cypermethrin, beta-cypermethrin, zetacipermethrin, deltamethrin, sphenopherrine, etofenprox, pyrethetrin, perminetrine, pretretrine, pyrethetrine, pyrethetrine, pyrethetrine, pretretrine, pyrethetrine, pretrine, pyrethetrine, pyrethetrine, pretretrine, pyrethetrine, pyrethetrine, pyrethetrine, pretretrine, pyrethetrine, pyrethetrine, pyrethetrine. II, resmethrin, silafluofem, tau-fluvalinate, teflutrin, tetramethrin, tralometrine, transflutrin, proflutrin, dimeflutrin; - insect growth regulators: (a) inhibitors of chitin synthesis: benzoylureas, chlorfluazurone, chiramazine, diflubenzurone, flucicloxurone, fluphenoxurone, hexaflumurone, lufenurone, novalurone, teflubenzurone, triflumurone; buprofezin, diophenolane, hexitiazox, ethoxazole and clofentazine; (b) ecdysone antagonists: halofenozide, methoxyfenozide, tebufenozide and azadiractin; (c) juvenoids: pyriproxifene, methoprene, phenoxycarb and (d) lipid biosynthesis inhibitors: spirodiclofen, spiromesifene, spirotetramate; - nicotinic receptor agonist / antagonist compounds: clothianidin, dinotefuran, imidacloprid, thiametoxam, nitenpiram, acetamipride, thiaclopride, 1- (2-chloro-thiazol-5-ylmethyl) -2-nitrimino-3,5-dimethyl- [1 , 3.5] triazinan; - GABA antagonist compounds: endosulfan, etiprol, fipronil, vaniliprol, pirafluprol, pyriprol, 5-amino-1- (2,6-dichloro-4-methyl-phenyl) -4-sulfinamoyl-1H-pyrazol acid amide -3-carbothioic; - the insecticides of macrocyclic lactones: abamectin, emamectin, milbemectin, lepimectin, spirosad, espinetoram; - mitochondrial electron transport inhibitor (METI) I acaricides: phenazaquin, pyridaben, tebufenpirate, tolfenpirad, flufenerim; - METI II and III compounds: acequinocyl, fluaciprim, hydramethylnone; - decouplers: chlorfenapyr; - inhibitors of oxidative phosphorylation: cyhexatin, diafentiuron, fenbutatin oxide, propargite; - feather-disrupting compounds: cyromazine; - mixed-function oxidase inhibitors: piperonyl butoxide; - sodium channel blocking compounds: indoxacarb and metaflumizone; - ryanodine receptor inhibitors: chlorantraniliprol, cyantraniliprol, flubendiamide, N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2 -pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide; N- [4-chloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -6-methylphenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide; N- [4-chloro-2- [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -6-methyl-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3-carboxamide; N- [4,6-dichloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole- 3-carboxamide; N- [4,6-dichloro-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (difluoromethyl) pyrazol-3-carboxamide; N- [4,6-dibromo-2 - [(di2-propyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole-3- carboxamide; N- [4-chloro-2 - [(di-2-propyl-lambda-4-sulfaniliden) carbamoyl] -6-cyano-phenyl] -2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazole3-carboxamide; N- [4,6-dibromo-2 - [(diethyl-lambda-4-sulfaniliden) carbamoyl] -phenyl] - 2- (3-chloro-2-pyridyl) -5- (trifluoromethyl) pyrazol-3-carboxamide; - others: benclothiaz, biphenazate, cartap, flonicamide, pyridalil, pimetrozine, sulfur, thiocyclam, cyienopyraphene, flupirazophos, ciflumetophen, amidoflumet, imiciafós, bistrifluron, pyrifluquinazon 4 and [ester] eRacetic, 4C , 6S, 6aS, 12R, 12aS, 12bS) -4 - [[((2-cyclopropylacetyl) oxy] methyl] -1,3,4,4a, 5,6,6a, 12,12a, 12b-decahydro-12- hydroxy4,6a, 12b-trimethyl-11-oxo-9- (3-pyridinyl) -2H, 11H-naphtho [2,1-b] pyran [3,4-e] pyran-3,6-diyl].
[0303] [0303] The compounds of the groups (A '), (B'), (C '), (D'), (E '), (F'), (G '), (H'), (I ' ), (J '), (K'), (L ')) M'), (N ') and (S'), their preparation and biological activity, for example against harmful fungi, pests or herbs weeds are known. The compounds with fungicidal activity II described by common names, their preparation and their activity against pathogenic fungi are known (cf .: http://www.alanwood.net/pesticides/); these substances are commercially available.
[0304] [0304] The compounds described by the IUPAC nomenclature, their preparation and their fungicidal activity are also known (Can J. Plant Sci 48 (6), 587-94, 1968; publications EP A 141.317; EP-A 152.031; EP- A 226,917; EP A 243,970; EP A 256,503; EP-A 428,941; EP-A 532,022; EP-A 1,028,125; EP-A 1,035,122; EP A 1,201,648; EP A 1,122,244, JP 2002 / 316,902 ; DE 1.9650.197; DE 10,021,412; DE 102,005,009,458; US 3,296,272; US 3,325,503; WO 1998/46608; WO 1999/14187; WO 1999/24413; WO 1999/27783; WO 2000/29404 ; WO 2000/46148; WO 2000/65913; WO 2001/54501; WO 2001/56358; WO 2002/22583; WO 2002/40431; WO 2003/10149; WO 2003/11853; WO 2003/14103; WO 2003/16286 ; WO 2003/53145; WO 2003/61388; WO 2003/66609; WO 2003/74491; WO 2004/49804; WO 2004/83193; WO 2005/120234; WO 2005/123689; WO 2005/123690; WO 2005/63721 ; WO 2005/87772; WO 2005/87773; WO 2006/15866; WO 2006/87325; WO 2006/87343; WO 2007/82098; WO 2007/90624, WO 2011/028657, WO 2012/168188, WO 2007/006670 , WO 2011/77514; WO 2013/047749, WO 20 10/069882, WO 2013/047441, WO 2003/16303, WO 2009/90181, WO 2013/007767, WO 2013/010862, WO 2013/024009 and WO 2013/024010).
[0305] - Azoxistrobina (C-1) - Trifloxistrobina (C-2) - Picoxistrobina (C-3) - Piraclostrobina (C-4) - Sedaxano (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopiram (C-8) - Fluxapiroxade (C-9) - Boscalide (C-10) - Oxatiapiprolina (C-49) - Metalaxila (C-11) - Metalaxil-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazol (C-15) - Difenoconazol (C-16) - Protioconazol (C-17) - Flutriafol (C-18) - Tiabendazol (C-19) - Ipconazol (C-20) - Tebuconazol (C-21) - Triadimenol (C-50) - Procloraz (C-22) - Fluquinconazol (C-23) - Ttriticonazol (C-24) - Fludioxinil (C-25) - Carboxina (C-26) - Siltiofame (C-27) - Ziram (C-28) - Tirame (C-29) - Carbendazim (C-30) - Tiofanato-metila (C-31) - Valifenaliato (C-32) - Inseticidas / Nematicidas - Fipronila (C-33) - Clotianidina (C-34) - Tiametoxam (C-35) - Acetamiprid (C-36) - Dinotefurano (C-37) - Imidacloprida (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrina (C-40) - Bifentrina (C-41) - Cipermetrina (C-53) - Alfa-cipermetrina (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Clorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoiônico) (C-55) - Acefato (C-46) - Clorpirifos (C-47) - Flupiradifurona (C-56) - Abamectina (C-48) [0305] According to one embodiment, component III is selected from the following compounds: - Azoxystrobin (C-1) - Trifloxystrobin (C-2) - Picoxystrobin (C-3) - Pyraclostrobin (C-4) - Sedaxane (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopyram (C-8) - Fluxapyroxade (C-9) - Boscalide (C-10) - Oxatiapiproline (C-49) - Metalaxyl (C-11) - Metalaxyl-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazole (C-15) - Diphenoconazole (C-16) - Protioconazole (C-17) - Flutriafol (C-18) - Thiabendazole (C-19) - Ipconazole (C-20) - Tebuconazole (C-21) - Triadimenol (C-50) - Prochloraz (C-22) - Fluquinconazole (C-23) - Ttriticonazole (C-24) - Fludioxinil (C-25) - Carboxine (C-26) - Siltiofame (C-27) - Ziram (C-28) - Thiram (C-29) - Carbendazim (C-30) - Thiophanate-methyl (C-31) - Valiphenalia (C-32) - Insecticides / Nematicides - Fipronil (C-33) - Clothianidin (C-34) - Thiamethoxam (C-35) - Acetamiprid (C-36) - Dinotefuran (C-37) - Imidacloprid (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrin (C-40) - Bifenthrin (C-41) - Cypermethrin (C-53) - Alpha-cypermethrin (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Chlorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoionic) (C-55) - Aphosphate (C-46) - Chlorpyrifos (C-47) - Flupiradifurone (C-56) - Abamectin (C-48)
[0306] [0306] Consequently, the especially preferred three-component compositions are compiled in Tables T1b to T31b, where each line corresponds to an embodiment of the compositions according to the present invention, i.e., a specific individualized composition. According to a specific aspect, these are the ternary compositions in which each one only contains these three components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention.
[0307] - Azoxistrobina (C-1) - Trifloxistrobina (C-2) - Picoxistrobina (C-3) - Piraclostrobina (C-4) - Sedaxano (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopiram (C-8) - Fluxapiroxade (C-9) - Boscalide (C-10) - Oxatiapiprolina (C-49) - Metalaxila (C-11) - Metalaxil-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazol (C-15) - Difenoconazol (C-16) - Protioconazol (C-17) - Flutriafol (C-18) - Tiabendazol (C-19) - Ipconazol (C-20) - Tebuconazol (C-21) - Triadimenol (C-50) - Procloraz (C-22) - Fluquinconazol (C-23) - Ttriticonazol (C-24) - Fludioxinil (C-25) - Carboxina (C-26) - Siltiofame (C-27) - Ziram (C-28) - Tirame (C-29) - Carbendazim (C-30) - Tiofanato-metila (C-31) - Valifenaliato (C-32) - Inseticidas / Nematicidas - Fipronila (C-33) - Clotianidina (C-34) - Tiametoxam (C-35) - Acetamiprid (C-36) - Dinotefurano (C-37) - Imidacloprida (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrina (C-40) - Bifentrina (C-41) - Cipermetrina (C-53) - Alfa-cipermetrina (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Clorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoiônico) (C-55) - Acefato (C-46) - Clorpirifos (C-47) - Flupiradifurona (C-56) - Abamectina (C-48) [0307] In these three-component compositions, component I is selected from compounds I-1, I-2, I-3, I-4, I-5, I-6, I-7 I-8, I -9, I -10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and I-31, or any group of compounds I detailed above, component II is selected from: - Azospirillum amazonense (II-56) - Azospirillum brasilense (II-48) - Azospirillum lipoferum (II-57) - Azospirillum irakense (II-58) - Azospirillum halopraeferens (II-59) - Bradyrhizobium spp. (II-49) - Bradyrhizobium sp. (Arachis) (II-60) - Bradyrhizobium sp. (Vigna) (II-61) - Bradyrhizobium elkanii (II-62) - Bradyrhizobium japonicum (II-50) - Bradyrhizobium liaoningense (II-63) - Bradyrhizobium lupini (II-64) - Delftia acidovorans (II-65) - Glomus intraradices (II-66) - Mesorhizobium spp. (II-51) - Mesorhizobium ciceri (II-67) - Mesorhizobium huakii (II-68) - Mesorhizobium loti (II-69) - Rhizobium leguminosarum bv. Phaseoli (II-53) - Rhizobium leguminosarum bv. Trifolii (II-70) - Rhizobium leguminosarum bv. Viciae (II-54) - Rhizobium tropici (II-71) - Sinorhizobium meliloti (II-55) - Bacillus altitudinis (II-72) - Bacillus amyloliquefaciens (II-73) - Bacillus amyloliquefaciens ssp. Plantarum (II-27) - Bacillus firmus (II-44) - Bacillus megaterium (II-74) - Bacillus mojavensis (II-28) - Bacillus mycoides (II-75) - Bacillus pumilus (II-29) - Bacillus simplex (II-30) - Bacillus solisalsi (II-31) - Bacillus subtilis (II-76) - Burkholderia sp. (II-77) - Coniothyrium minitans (II-78) - Paecilomyces lilacinus (II-79) - Paenibacillus alvei (II-80) - Paenibacillus polymyxa (II-34) - Paenibacillus popilliae (II-81) - Pasteuria nishizawae (II-82) - Pasteuria usgae (II-83) - Penicillium bilaiae (II-52) - Pseudomonas chloraphis (II-84) - Pseudomonas fluorescens (II-85) - Pseudomonas putida (II-86) - abscisic acid (II-87) - harpin protein (alpha-beta) (II-88) - jasmonic acid or its salts or derivatives (II-43) cis-jasmine (II-89); and - methyl jasmonate (II-90) - and component III is selected from: - Azoxystrobin (C-1) - Trifloxystrobin (C-2) - Picoxystrobin (C-3) - Pyraclostrobin (C-4) - Sedaxane (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopyram (C-8) - Fluxapyroxade (C-9) - Boscalide (C-10) - Oxatiapiproline (C-49) - Metalaxyl (C-11) - Metalaxyl-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazole (C-15) - Diphenoconazole (C-16) - Protioconazole (C-17) - Flutriafol (C-18) - Thiabendazole (C-19) - Ipconazole (C-20) - Tebuconazole (C-21) - Triadimenol (C-50) - Prochloraz (C-22) - Fluquinconazole (C-23) - Ttriticonazole (C-24) - Fludioxinil (C-25) - Carboxine (C-26) - Siltiofame (C-27) - Ziram (C-28) - Thiram (C-29) - Carbendazim (C-30) - Thiophanate-methyl (C-31) - Valiphenalia (C-32) - Insecticides / Nematicides - Fipronil (C-33) - Clothianidin (C-34) - Thiamethoxam (C-35) - Acetamiprid (C-36) - Dinotefuran (C-37) - Imidacloprid (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrin (C-40) - Bifenthrin (C-41) - Cypermethrin (C-53) - Alpha-cypermethrin (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Chlorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoionic) (C-55) - Aphosphate (C-46) - Chlorpyrifos (C-47) - Flupiradifurone (C-56) - Abamectin (C-48)
[0308] [0308] The three-component compositions from T1b-1 to T1b-2,856 comprising compound I-3 component II and component III, in particular, ternary compositions containing compound I-3, II and III, as the only ingredients active.
[0309] [0309] The three-component compositions from T2b-1 to T2b2-.856 corresponding to the respective compositions from T1b-1 to T1b-2,856, wherein component I is I-2 instead of I-3. Consequently, Table T2b contains the compositions from T2b-1 to T2b-2,856 which comprise compound I-2, component II and component III, in particular, the ternary compositions containing compound I-2, II and III, as only active ingredients. TABLE T3B
[0310] [0310] The three-component compositions from T3b-1 to T3b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-1, instead of I-3. Consequently, Table T3b contains the compositions from T3b-1 to T3b-2,856 which comprise compound I-1, component II and component III, in particular, the ternary compositions containing compound I-1, II and III, as only active ingredients. TABLE T4B
[0311] [0311] The three-component compositions from T4b-1 to T4b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-4 instead of I-3. Consequently, the Table contains the compositions of T4b T4b-1 to T4b-2,856 which comprise compound I-4, component II and component III, in particular, the ternary compositions containing compound I-4, II and III, as only active ingredients. TABLE T5B
[0312] [0312] The three-component compositions from T5b-1 to T5b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-5 instead of I-3. Consequently, Table T5b contains compositions from T5b-1 to T5b-2,856 which comprise compound I-5, component II and component III, in particular, ternary compositions containing compound I-5, II and III, as only active ingredients. TABLE T6B
[0313] [0313] The three-component compositions from T6b-1 to T6b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-6, instead of I-3. Consequently, Table T6b contains compositions from T6b-1 to T6b-2,856 which comprise compound I-6, component II and component III, in particular, ternary compositions containing compound I-6, II and III, as only active ingredients. TABLE T7B
[0314] [0314] The three-component compositions from T7b-1 to T7b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-7, instead of I-3. Consequently, Table T7b contains compositions from T7b-1 to T7b-2,856 which comprise compound I-7, component II and component III, in particular, ternary compositions containing compound I-7, II and III, as only active ingredients. TABLE T8B
[0315] [0315] The three-component compositions from T8b-1 to T8b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-8 instead of I-3. Consequently, Table T8B contains compositions from T8b-1 to T8b-2,856 which comprise compound I-8, component II and component III, in particular, ternary compositions containing compound I-8, II and III, as only active ingredients. TABLE T9B
[0316] [0316] The three-component compositions from T9b-1 to T9b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-9 instead of I-3. Consequently, Table T9B contains compositions from T9b-1 to T9b-2,856 which comprise compound I-9, component II and component III, in particular, ternary compositions containing compound I-9, II and III, as only active ingredients. TABLE T10B
[0317] [0317] The three-component compositions from T10b-1 to T10b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-10, instead of I-3. Consequently, Table T10b contains compositions from T10b-1 to T10b-2,856 which comprise compound I-10, component II and component III, in particular, ternary compositions containing compound I-10, II and III, as only active ingredients. TABLE T11B
[0318] [0318] The three-component compositions from T11b-1 to T11b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-11, instead of I-3. Consequently, Table T11b contains compositions from T11b-1 to T11b-2,856 which comprise compound I-11, component II and component III, in particular, ternary compositions containing compound I-11, II and III, as only active ingredients. TABLE T12B
[0319] [0319] The three-component compositions from T12b-1 to T12b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-12, instead of I-3. Consequently, Table T12b contains compositions from T12b-1 to T12b-2,856 which comprise compound I-12, component II and component III, in particular, ternary compositions containing compound I-12, II and III, as only active ingredients. TABLE T13B
[0320] [0320] The three-component compositions from T13b-1 to T13b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-13, instead of I-3. Consequently, Table T13b contains compositions from T13b-1 to T13b-2,856 which comprise compound I-13, component II and component III, in particular, ternary compositions containing compound I-13, II and III, as only active ingredients. TABLE T14B
[0321] [0321] The three-component compositions from T14b-1 to T14b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-14, instead of I-3. Consequently, Table T14b contains compositions from T14b-1 to T14b-2,856 which comprise compound I-14, component II and component III, in particular, ternary compositions containing compound I-14, II and III, as only active ingredients. TABLE T15B
[0322] [0322] The three-component compositions from T15b-1 to T15b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-15, instead of I-3. Consequently, Table T15b contains compositions from T15b-1 to T15b-2,856 which comprise compound I-15, component II and component III, in particular, ternary compositions containing compound I-15, II and III, as only active ingredients. TABLE T16B
[0323] [0323] The three-component compositions from T16b-1 to T16b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-16 instead of I-3. Consequently, Table T16b contains compositions from T16b-1 to T16b-2,856 which comprise compound I-16, component II and component III, in particular, ternary compositions containing compound I-16, II and III, as only active ingredients. TABLE T17B
[0324] [0324] The three-component compositions from T17b-1 to T17b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-17, instead of I-3. Consequently, Table T17b contains compositions from T17b-1 to T17b-2,856 which comprise compound I-17, component II and component III, in particular, ternary compositions containing compound I-17, II and III, as only active ingredients. TABLE T18B
[0325] [0325] The three-component compositions from T18b-1 to T18b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-18, instead of I-3. Consequently, Table T18b contains compositions from T18b-1 to T18b-2,856 which comprise compound I-18, component II and component III, in particular, the ternary compositions containing compound I-18, II and II as the only ingredients active. TABLE T19B
[0326] [0326] The three-component compositions from T19b-1 to T19b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-19, instead of I-3. Consequently, Table T19b contains compositions from T19b-1 to T19b-2,856 which comprise compound I-19, component II and component III, in particular, ternary compositions containing compound I-19, II and III, as only active ingredients. TABLE T20B
[0327] [0327] The three-component compositions from T20b-1 to T20b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-20, instead of I-3. Consequently, Table T20b contains compositions from T20b-1 to T20b-2,856 which comprise compound I-20, component II and component III, in particular, ternary compositions containing compound I-20, II and III, as only active ingredients. TABLE T21B
[0328] [0328] The three-component compositions from T21b-1 to T21b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-21, instead of I-3. Consequently, Table T21b contains compositions from T21b-1 to T21b-2,856 which comprise compound I-21, component II and component III, in particular, ternary compositions containing compound I-21, II and III, as only active ingredients. TABLE T22B
[0329] [0329] The three-component compositions from T22b-1 to T22b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-22, instead of I-3. Consequently, Table T22b contains compositions from T22b-1 to T22b-2,856 which comprise compound I-22, component II and component III, in particular, ternary compositions containing compound I-22, II and III, as only active ingredients. TABLE T23B
[0330] [0330] The three-component compositions from T23b-1 to T23b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-23, instead of I-3. Consequently, Table T23b contains compositions from T23b-1 to T23b-2,856 which comprise compound I-23, component II and component III, in particular, ternary compositions containing compound I-23, II and III, as only active ingredients. TABLE T24B
[0331] [0331] The three-component compositions from T24b-1 to T24b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-24, instead of I-3. Consequently, Table T24b contains compositions from T24b-1 to T24b-2,856 which comprise compound I-24, component II and component III, in particular, ternary compositions containing compound I-24, II and III, as only active ingredients. TABLE T25B
[0332] [0332] The three-component compositions from T25b-1 to T25b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-25, instead of I-3. Consequently, Table T25b contains compositions from T25b-1 to T25b-2,856 which comprise compound I-25, component II and component III, in particular, ternary compositions containing compound I-25, II and III, as only active ingredients. TABLE T26B
[0333] [0333] The three-component compositions from T26b-1 to T26b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-26, instead of I-3. Consequently, Table T26b contains the compositions T26b-1 to T26b-2,856 which comprise compound I-26, component II and component III, in particular, the ternary compositions containing compound I-26, II and III, as only active ingredients. TABLE T27B
[0334] [0334] The three-component compositions from T27b-1 to T27b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-27, instead of I-3. Consequently, Table T27b contains compositions from T27b-1 to T27b-2,856 which comprise compound I-27, component II and component III, in particular, ternary compositions containing compound I-27, II and III, as only active ingredients. TABLE T28B
[0335] [0335] The three-component compositions from T28b-1 to T28b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-28, instead of I-3. Consequently, Table T28b contains compositions from T28b-1 to T28b-2,856 which comprise compound I-28, component II and component III, in particular, ternary compositions containing compound I-28, II and III, as only active ingredients. TABLE T29B
[0336] [0336] The three-component compositions from T29b-1 to T29b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-29, instead of I-3. Consequently, Table T29b contains compositions from T29b-1 to T29b-2,856 which comprise compound I-29, component II and component III, in particular, ternary compositions containing compound I-29, II and III, as only active ingredients. TABLE T30B
[0337] [0337] The three-component compositions from T30b-1 to T30b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-30, instead of I-3. Consequently, Table T30b contains the compositions T30b-1 to T30b-2,856 which comprise compound I-30, component II and component III, in particular, the ternary compositions containing compound I-30, II and III, as only active ingredients. TABLE T31B
[0338] [0338] The three-component compositions from T31b-1 to T31b-2,856 corresponding to the respective compositions from T1b-1 to T1b-2,856, where component I is I-31, instead of I-3. Consequently, Table T31b contains compositions from T31b-1 to T31b-2,856 which comprise compound I-31, component II and component III, in particular, ternary compositions containing compound I-31, II and III, as only active ingredients.
[0339] - Azoxistrobina (C-1) - Trifloxistrobina (C-2) - Picoxistrobina (C-3) - Piraclostrobina (C-4) - Sedaxano (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopiram (C-8) - Fluxapiroxade (C-9) - Boscalide (C-10) - Oxatiapiprolina (C-49) - Metalaxila (C-11) - Metalaxil-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazol (C-15) - Difenoconazol (C-16) - Protioconazol (C-17) - Flutriafol (C-18) - Tiabendazol (C-19) - Ipconazol (C-20) - Tebuconazol (C-21) - Triadimenol (C-50) - Procloraz (C-22) - Fluquinconazol (C-23) - Ttriticonazol (C-24) - Fludioxinil (C-25) - Carboxina (C-26) - Siltiofame (C-27) - Ziram (C-28) - Tirame (C-29) - Carbendazim (C-30) - Tiofanato-metila (C-31) - Valifenaliato (C-32) - Inseticidas / Nematicidas - Fipronila (C-33) - Clotianidina (C-34) - Tiametoxam (C-35) - Acetamiprid (C-36) - Dinotefurano (C-37) - Imidacloprida (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrina (C-40) - Bifentrina (C-41) - Cipermetrina (C-53) - Alfa-cipermetrina (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Clorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoiônico) (C-55) - Acefato (C-46) - Clorpirifos (C-47) - Flupiradifurona (C-56) - Abamectina (C-48) [0339] In accordance with another embodiment of the present invention, component III is selected from the following compounds: - and component III is selected from: - Azoxystrobin (C-1) - Trifloxystrobin (C-2) - Picoxystrobin (C-3) - Pyraclostrobin (C-4) - Sedaxane (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopyram (C-8) - Fluxapyroxade (C-9) - Boscalide (C-10) - Oxatiapiproline (C-49) - Metalaxyl (C-11) - Metalaxyl-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazole (C-15) - Diphenoconazole (C-16) - Protioconazole (C-17) - Flutriafol (C-18) - Thiabendazole (C-19) - Ipconazole (C-20) - Tebuconazole (C-21) - Triadimenol (C-50) - Prochloraz (C-22) - Fluquinconazole (C-23) - Ttriticonazole (C-24) - Fludioxinil (C-25) - Carboxine (C-26) - Siltiofame (C-27) - Ziram (C-28) - Thiram (C-29) - Carbendazim (C-30) - Thiophanate-methyl (C-31) - Valiphenalia (C-32) - Insecticides / Nematicides - Fipronil (C-33) - Clothianidin (C-34) - Thiamethoxam (C-35) - Acetamiprid (C-36) - Dinotefuran (C-37) - Imidacloprid (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrin (C-40) - Bifenthrin (C-41) - Cypermethrin (C-53) - Alpha-cypermethrin (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Chlorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoionic) (C-55) - Aphosphate (C-46) - Chlorpyrifos (C-47) - Flupiradifurone (C-56) - Abamectin (C-48)
[0340] [0340] Consequently, the even more especially preferred three-component compositions are compiled in Table T1c, where each line corresponds to an embodiment of the compositions according to the present invention, that is, a specific individualized composition. According to a specific aspect, these are the ternary compositions in which each one only contains these three components, as active compounds. In addition, each combination of the individualized compositions in this Table also represents the embodiments of the present invention.
[0341] - Azoxistrobina (C-1) - Trifloxistrobin (C-2) - Picoxistrobina (C-3) - Piraclostrobina (C-4) - Sedaxano (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopiram (C-8) - Fluxapiroxade (C-9) - Boscalide (C-10) - Oxatiapiprolina (C-49) - Metalaxila (C-11) - Metalaxil-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazol (C-15) - Difenoconazol (C-16) - Protioconazol (C-17) - Flutriafol (C-18) - Tiabendazol (C-19) - Ipconazol (C-20) - Tebuconazol (C-21) - Triadimenol (C-50) - Procloraz (C-22) - Fluquinconazol (C-23) - Ttriticonazol (C-24) - Fludioxinil (C-25) - Carboxina (C-26) - Siltiofame (C-27) - Ziram (C-28) - Tirame (C-29) - Carbendazim (C-30) - Tiofanato-metila (C-31) - Valifenaliato (C-32) - Inseticidas / Nematicidas - Fipronila (C-33) - Clotianidina (C-34) - Tiametoxam (C-35) - Acetamiprid (C-36) - Dinotefurano (C-37) - Imidacloprida (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrina (C-40) - Bifentrina (C-41) - Cipermetrina (C-53) - Alfa-cipermetrina (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Clorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoiônico) (C-55) - Acefato (C-46) - Clorpirifos (C-47) - Flupiradifurona (C-56) - Abamectina (C-48) [0341] In these three-component compositions, component I is selected from compounds I-1, I-2, I-3, I-4, I-5, I-6, I-7 I-8, I -9, I -10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21 , I-22, I-23, I-24, I-25, I-26, I-27, I-28, I-29, I-30 and I-31, or any group of compounds I detailed above, component II is selected from: - Azospirillum amazonense SpY2 (II-91) - Azospirillum brasilense AZ39 also called Az 39 (II-92) - Azospirillum brasilense Cd (II-93) - Azospirillum brasilense Sp 245 (II-94) - Azospirillum brasilense Ab-V5 (II-95) - Azospirillum brasilense Ab-V6 (II-96) - Azospirillum brasilense XOH (II-97) - Azospirillum lipoferum Sp31 (II-98) - Bradyrhizobium elkanii SEMIA 5019 also called 29W (II-99) - Bradyrhizobium elkanii SEMIA 587 (II-100) - Bradyrhizobium elkanii U-1301 (II-101) - Bradyrhizobium elkanii U-1302 (II-102) - Bradyrhizobium elkanii USDA 3254 (II-103) - Bradyrhizobium elkanii USDA 76 (II-104) - Bradyrhizobium elkanii USDA 94 (II-105) - Bradyrhizobium japonicum 532c (II-106) - Bradyrhizobium japonicum E-109 (II-107) - Bradyrhizobium japonicum G49 (II-108) - Bradyrhizobium japonicum SEMIA 5079 (II-109) - Bradyrhizobium japonicum SEMIA 5080 (II-110) - Bradyrhizobium japonicum SEMIA 566 (II-111) - Bradyrhizobium japonicum SEMIA 586 (II-112) - Bradyrhizobium japonicum TA-11 (TA11 NOD +) (II-113) - Bradyrhizobium japonicum USDA 110 (II-114) - Bradyrhizobium japonicum USDA 121 (II-115) - Bradyrhizobium japonicum USDA 3 (II-116) - Bradyrhizobium japonicum USDA 31 (II-117) - Bradyrhizobium japonicum USDA 76 (II-118) - Bradyrhizobium sp. (Arachis) CB1015 (II-119) - Bradyrhizobium sp. (Arachis) SEMIA 6144 (II-120) - Bradyrhizobium sp. (Arachis) SEMIA 6462 (II-121) - Bradyrhizobium sp. (Arachis) SEMIA 6464 (II-122) - Bradyrhizobium sp. (Vigna) PNL1 (II-123) - Mesorhizobium sp. WSM1497 (II-124) - Rhizobium leguminosarum bv. phaseoli RG-B10 (II-125) - Rhizobium leguminosarum bv. phaseoli (II-126) - Rhizobium leguminosarum bv. trifolii 095 (II-127) - Rhizobium leguminosarum bv. trifolii CB782 (II-128) - Rhizobium leguminosarum bv. trifolii CC1099 (II-129) - Rhizobium leguminosarum bv. trifolii CC275e (II-130) - Rhizobium leguminosarum bv. trifolii CC283b (II-131) - Rhizobium leguminosarum bv. trifolii RP113-7 (II-132) - Rhizobium leguminosarum bv. trifolii TA1 (II-133) - Rhizobium leguminosarum bv. trifolii WSM1325 (II-134) - Rhizobium leguminosarum bv. trifolii WSM2304 (II-135) - Rhizobium leguminosarum bv. viciae P1NP3Cst also referred to as 1435 (II-136) - Rhizobium leguminosarum bv. viciae RG-P2 also known as P2 (II-137) - Rhizobium leguminosarum bv. viciae SU303 (II-138) - Rhizobium leguminosarum bv. viciae WSM1455 (II-140) - Rhizobium tropici CC511 (II-141) - Rhizobium tropici CIAT 899 (II-142) - Rhizobium tropici H12 (II-143) - Rhizobium tropici PRF 81 (II-144) - Sinorhizobium meliloti NRG185 (II-145) - Sinorhizobium meliloti RCR2011 also known as 2011 or SU47 (II-146) - Sinorhizobium meliloti RRI128 (II-147) - Bacillus altitudinis 41KF2b (II-148) - Bacillus amyloliquefaciens AP-136 (II-149) - Bacillus amyloliquefaciens AP-188 (II-150) - Bacillus amyloliquefaciens AP-218 (II-151) - Bacillus amyloliquefaciens AP-219 (II-152) - Bacillus amyloliquefaciens AP-295 (II-153) - Bacillus amyloliquefaciens ssp. plantarum D747 (II-154) - Bacillus amyloliquefaciens ssp. plantarum FZB24 also called SB3615 (II-155) - Bacillus amyloliquefaciens ssp. plantarum FZB42 (II-156) - Bacillus amyloliquefaciens ssp. plantarum GB03 also called GBO3 formerly B. subtilis (II-157) - Bacillus amyloliquefaciens ssp. plantarum MBI600 also referred to as 1430, formerly B. subtilis (II-158) - Bacillus amyloliquefaciens ssp. plantarum QST-713, formerly B. subtilis (II-159) - Bacillus amyloliquefaciens ssp. plantarum TJ1000, also called 1BE (II-160) - Bacillus firmus CNCM I-1582 (II-161) - Bacillus megaterium H491 (II-162) - Bacillus megaterium J142 (II-163) - Bacillus megaterium M018 (II-164) - Bacillus mojavensis AP-209 (II-165) - Bacillus mojavensis SR11 (II-166) - Bacillus mycoides AQ726 (II-167) - Bacillus mycoides J also called BMJ (II-168) - Bacillus pumilus GB34 (II-169) - Bacillus pumilus GHA 180 (II-170) - Bacillus pumilus INR-7 otherwise referred to as BU F22 and BU-F33 (II-171) - Bacillus pumilus KFP9F (II-172) - Bacillus pumilus QST 2808 (II-173) - Bacillus simplex ABU 288 (II-174) - Bacillus subtilis CX-9060 (II-175) - Bacillus subtilis FB17 (II-176) - Bacillus subtilis GB07 (II-177) - Burkholderia sp. A396 (II-178) - Coniothyrium minitans CON / M / 91-08 (II-179) - Paecilomyces lilacinus 251 (II-180) - Paecilomyces lilacinus BCP2 (II-181) - Paenibacillus alvei NAS6G6 (II-182) - Paenibacillus polymyxa PKB1 (II-183) - Paenibacilllus popilliae 14F-D80 also known as K14F0080 (II-184) - Paenibacilllus popilliae KLN 3 (II-185) - Pasteuria nishizawae PN1 (II-186) - Pasteuria sp, Ph3 (II-187) - Pasteuria sp. PR3 (II-188) - Pasteuria sp. ATCC PTA-9643 (II-189) - Pasteuria usgae BL1 (II-190) - Bilaiae Penicillium (also called P. bilaii) NRRL 50162 (II-191) - Bilaiae Penicillium (also called P. bilaii) NRRL 50169 (II-192) - Bilaiae Penicillium (also called P. bilaii) ATCC 18309 (= ATCC 74319) (II-193) - Bilaiae Penicillium (also called P. bilaii) ATCC 20851 (II-194) - Bilaiae Penicillium (also called P. bilaii) ATCC 22348 (= ATCC 74318) (II-195) - Pseudomonas fluorescens A506 (II-196) - Pseudomonas fluorescens ATCC 13525 (II-197) - Pseudomonas fluorescens CHA0 (II-198) - Pseudomonas fluorescens CL 145A (II-199) - Pseudomonas fluorescens NCIB 12089 (II-200) - Pseudomonas fluorescens Pf-5 (II-201) - Pseudomonas fluorescens WCS374 (II-202) - Pseudomonas putida ATCC 202153 (II-203) - and component III is selected from: - Azoxystrobin (C-1) - Trifloxystrobin (C-2) - Picoxystrobin (C-3) - Pyraclostrobin (C-4) - Sedaxane (C-5) - Pentiopirad (C-6) - Penflufen (C-7) - Fluopyram (C-8) - Fluxapyroxade (C-9) - Boscalide (C-10) - Oxatiapiproline (C-49) - Metalaxyl (C-11) - Metalaxyl-M (C-12) - Etaboxam (C-13) - DMM (C-14) - Ciproconazole (C-15) - Diphenoconazole (C-16) - Protioconazole (C-17) - Flutriafol (C-18) - Thiabendazole (C-19) - Ipconazole (C-20) - Tebuconazole (C-21) - Triadimenol (C-50) - Prochloraz (C-22) - Fluquinconazole (C-23) - Ttriticonazole (C-24) - Fludioxinil (C-25) - Carboxine (C-26) - Siltiofame (C-27) - Ziram (C-28) - Thiram (C-29) - Carbendazim (C-30) - Thiophanate-methyl (C-31) - Valiphenalia (C-32) - Insecticides / Nematicides - Fipronil (C-33) - Clothianidin (C-34) - Thiamethoxam (C-35) - Acetamiprid (C-36) - Dinotefuran (C-37) - Imidacloprid (C-38) - Tiacloprid (C-39) - Sulfoxaflor (C-51) - Metiocarb (C-52) - Teflutrin (C-40) - Bifenthrin (C-41) - Cypermethrin (C-53) - Alpha-cypermethrin (C-42) - Espinosad (C-43) - Ciantraniliprol (C-44) - Chlorantraniliprol (C-45) - Tiodicarb (C-54) - Triflumezopirim (mesoionic) (C-55) - Aphosphate (C-46) - Chlorpyrifos (C-47) - Flupiradifurone (C-56) - Abamectin (C-48)
[0342] [0342] The three-component compositions from T1c-1 to T1c-6,215 comprising compound I-3, a component II and a component III, in particular, the ternary compositions containing compound I-3, II and III, as the only active ingredients.
[0343] [0343] The three-component compositions from T2c-1 to T2c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-2 instead of I-3. Consequently, Table T2c contains the compositions from T2C-1 to T2c-6,215 which comprise compound I-2, component II and component III, in particular, the ternary compositions containing compound I-2, II and III, as only active ingredients. TABLE T3C
[0344] [0344] The three-component compositions from T3c-1 to T3c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-1, instead of I-3. Consequently, Table T3c contains compositions from T3c-1 to T3c-6,215 which comprise compound I-1, component II and component III, in particular, ternary compositions containing compound I-1, II and III, as only active ingredients. TABLE T4C
[0345] [0345] The three-component compositions from T4c-1 to T4c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-4, instead of I-3. Consequently, Table T4c contains the compositions T4c-1 to T4c-6,215 which comprise compound I-4, component II and component III, in particular, the ternary compositions containing compound I-4, II and III, as only active ingredients. TABLE T5C
[0346] [0346] The three-component compositions from T5c-11 to T5c-16215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-5 instead of I-3. Consequently, Table T5C contains the compositions T5c-11 to T5c-16215 which comprise compound I-5, component II and component III, in particular, the ternary compositions containing compound I-5, II and III, as only active ingredients. TABLE T6C
[0347] [0347] The three-component compositions from T6c-1 to T6c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-6, instead of I-3. Consequently, Table T6c contains compositions from T6c-1 to T6c-6,215 which comprise compound I-6, component II and component III, in particular, ternary compositions containing compound I-6, II and III, as only active ingredients. TABLE T7C
[0348] [0348] The three-component compositions from T7c-1 to T7c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-7, instead of I-3. Consequently, Table T7c contains compositions from T7c-1 to T7c-6,215 which comprise compound I-7, component II and component III, in particular, ternary compositions containing compound I-7, II and III, as only active ingredients. TABLE T8C
[0349] [0349] The three-component compositions from T8c-1 to T8c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-8 instead of I-3. Consequently, Table T8c contains compositions from T8c-1 to T8c-6,215 which comprise compound I-8, component II and component III, in particular, ternary compositions containing compound I-8, II and III, as only active ingredients. TABLE T9C
[0350] [0350] The three-component compositions from T9c-1 to T9c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-9, instead of I-3. Consequently, Table T9c contains compositions from T9c-1 to T9c-6,215 which comprise compound I-9, component II and component III, in particular, ternary compositions containing compound I-9, II and III, as only active ingredients. TABLE T10C
[0351] [0351] The three-component compositions from T10c-1 to T10c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-10, instead of I-3. Consequently, Table T10c contains compositions from T10c-1 to T10c-6,215 which comprise compound I-10, component II and component III, in particular, ternary compositions containing compound I-10, II and III, as only active ingredients. TABLE T11C
[0352] [0352] The three-component compositions from T11c-1 to T11c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-11, instead of I-3. Consequently, Table T11c contains compositions from T11c-1 to T11c-6,215 which comprise compound I-11, component II and component III, in particular, ternary compositions containing compound I-11, II and III, as only active ingredients. TABLE T12C
[0353] [0353] The three-component compositions from T12c-1 to T12c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-12, instead of I-3. Consequently, Table T12c contains compositions from T12c-1 to T12c-6,215 which comprise compound I-12, component II and component III, in particular, ternary compositions containing compound I-12, II and III, as only active ingredients. TABLE T13C
[0354] [0354] The three-component compositions from T13c-1 to T13c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-13, instead of I-3. Consequently, Table T13c contains compositions from T13c-1 to T13c-6,215 which comprise compound I-13, component II and component III, in particular, ternary compositions containing compound I-13, II and III, as only active ingredients. TABLE T14C
[0355] [0355] The three-component compositions from T14c-1 to T14c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-14, instead of I-3. Consequently, Table T14c contains compositions from T14c-1 to T14c-6,215 which comprise compound I-14, component II and component III, in particular, ternary compositions containing compound I-14, II and III, as only active ingredients. TABLE T15C
[0356] [0356] The three-component compositions from T15c-1 to T15c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-15, instead of I-3. Consequently, Table T15c contains compositions from T15c-1 to T15c-6,215 which comprise compound I-15, component II and component III, in particular, ternary compositions containing compound I-15, II and III, as only active ingredients. TABLE T16C
[0357] [0357] The three-component compositions from T16c-1 to T16c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-16, instead of I-3. Consequently, Table T16c contains compositions from T16c-1 to T16c-6,215 which comprise compound I-16, component II and component III, in particular, ternary compositions containing compound I-16, II and III, as only active ingredients. TABLE T17C
[0358] [0358] The three-component compositions from T17c-1 to T17c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-17, instead of I-3. Consequently, Table T17c contains compositions from T17c-1 to T17c-6,215 which comprise compound I-17, component II and component III, in particular, ternary compositions containing compound I-17, II and III, as only active ingredients. TABLE T18C
[0359] [0359] The three-component compositions from T18c-1 to T18c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-18, instead of I-3. Consequently, Table T18c contains compositions from T18c-1 to T18c-6,215 which comprise compound I-18, component II and component III, in particular, ternary compositions containing compound I-18, II and II as unique active ingredients. TABLE T19C
[0360] [0360] The three-component compositions from T19c-1 to T19c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-19, instead of I-3. Consequently, Table T19c contains compositions from T19c-1 to T19c-6,215 which comprise compound I-19, component II and component III, in particular, ternary compositions containing compound I-19, II and III, as only active ingredients. TABLE T20C
[0361] [0361] The three-component compositions from T20c-1 to T20c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-20, instead of I-3. Consequently, Table T20c contains compositions from T20c-1 to T20c-6,215 which comprise compound I-20, component II and component III, in particular, ternary compositions containing compound I-20, II and III, as only active ingredients. TABLE T21C
[0362] [0362] The three-component compositions from T21c-1 to T21c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-21, instead of I-3. Consequently, Table T21c contains compositions from T21c-1 to T21c-6,215 which comprise compound I-21, component II and component III, in particular, ternary compositions containing compound I-21, II and III, as only active ingredients. TABLE T22C
[0363] [0363] The three-component compositions from T22c-1 to T22c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-22, instead of I-3. Consequently, Table T22c contains compositions from T22c-1 to T22c-6,215 which comprise compound I-22, component II and component III, in particular, ternary compositions containing compound I-22, II and III, as only active ingredients. TABLE T23C
[0364] [0364] The three-component compositions from T23c-1 to T23c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-23, instead of I-3. Consequently, Table T23c contains compositions from T23c-1 to T23c-6,215 which comprise compound I-23, component II and component III, in particular, ternary compositions containing compound I-23, II and III, as only active ingredients. TABLE T24C
[0365] [0365] The three-component compositions from T24c-1 to T24c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-24, instead of I-3. Consequently, Table T24c contains compositions from T24c-1 to T24c-6,215 which comprise compound I-24, component II and component III, in particular, ternary compositions containing compound I-24, II and III, as only active ingredients. TABLE T25C
[0366] [0366] The three-component compositions from T25c-1 to T25c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-25, instead of I-3. Consequently, Table T25c contains compositions from T25c-1 to T25c-6,215 which comprise compound I-25, component II and component III, in particular, ternary compositions containing compound I-25, II and III, as only active ingredients. TABLE T26C
[0367] [0367] The three-component compositions from T26c-1 to T26c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-26, instead of I-3. Consequently, Table T26c contains compositions from T26c-1 to T26c-6,215 which comprise compound I-26, component II and component III, in particular, ternary compositions containing compound I-26, II and III, as only active ingredients. TABLE T27C
[0368] [0368] The three-component compositions from T27c-1 to T27c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-27, instead of I-3. Consequently, Table T27c contains compositions from T27c-1 to T27c-6,215 which comprise compound I-27, component II and component III, in particular, ternary compositions containing compound I-27, II and III, as only active ingredients. TABLE T28C
[0369] [0369] The three-component compositions from T28c-1 to T28c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-28, instead of I-3. Consequently, Table T28c contains compositions from T28c-1 to T28c-6,215 which comprise compound I-28, component II and component III, in particular, ternary compositions containing compound I-28, II and III, as only active ingredients. TABLE T29C
[0370] [0370] The three-component compositions from T29c-1 to T29c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-29, instead of I-3. Consequently, Table T29c contains compositions from T29c-1 to T29c-6,215 which comprise compound I-29, component II and component III, in particular, ternary compositions containing compound I-29, II and III, as only active ingredients. TABLE T30C
[0371] [0371] The three-component compositions from T30c-1 to T30c-6.215 corresponding to the respective compositions from T1c-1 to T1c-6.215, where component I is I-30, instead of I-3. Consequently, Table T30c contains compositions from T30c-1 to T30c-6,215 which comprise compound I-30, component II and component III, in particular, ternary compositions containing compound I-30, II and III, as only active ingredients. TABLE T31C
[0372] [0372] The three-component compositions from T31c-1 to T31c-6,215 corresponding to the respective compositions from T1c-1 to T1c-6,215, where component I is I-31, instead of I-3. Consequently, Table T31c contains compositions from T31c-1 to T31c-6,215 which comprise compound I-31, component II and component III, in particular, ternary compositions containing compound I-31, II and III, as only active ingredients.
[0373] [0373] According to another aspect, the present invention relates to compositions of four components, that is, compositions comprising component I, that is, a compound I, in particular a compound selected from compounds I- 1, I-2, I-3, I-4, I-5, I-6, 7-I, I-8, I-9, I-10, I-11, I-12, I-13, I-14, I-15, I-16, I-17, I-18, I-19, I-20, I-21, I-22, I-23, I-24, I-25, I- 26, I-27, I-28, I-29, I-30 and I-31, or any group of compounds I detailed above, a component II as defined herein, a component III as defined herein and a component IV.
[0374] [0374] Another aspect of the present invention is compositions that comprise more than four active ingredients, such as, in particular, five-component compositions. In addition to the four components I, II, III and IV, as described above, these compositions of the present invention comprise a component V.
[0375] [0375] Compositions comprising component I and biochemical pesticidal component II selected from groups (L2), (L4) and (L6), as defined herein, may be prepared in the form of compositions which comprise, in addition to active ingredients, at least one inert (auxiliary) ingredient by usual means, for example, by the means provided for the compositions of compounds I, as detailed below. Regarding the usual ingredients of such compositions, reference is made to the explanations provided for the compositions containing compounds I.
[0376] [0376] According to one embodiment, the microbial pesticides selected from groups (L1), (L3) and (L5) cover not only pure cultures isolated from the respective microorganism, as defined in the present, but also their free extract of cells, their suspensions in the culture broth or as a supernatant containing the metabolite or a purified metabolite obtained from a culture broth of the total micro-organism or strain of micro-organism.
[0377] [0377] According to another embodiment, the microbial pesticides selected from groups (L1), (L3), (L5), cover not only pure cultures isolated from the respective microorganism, as defined in the present, but also their cell-free extract or at least one of its metabolites, and / or a mutant of the respective micro-organism that has all its identification characteristics and also a cell-free extract or at least one mutant metabolite.
[0378] [0378] The term "total broth culture" refers to a liquid culture that contains cells and media. In particular, as used herein, the term "total culture broth" refers to a liquid culture of a micro-organism that contains the cells and / or vegetative spores suspended in the vegetable's culture medium and, optionally, the metabolites produced by the respective microorganism.
[0379] [0379] As used in the present, the term "culture medium", refers to a medium obtained by culturing the microorganism in said medium, preferably in a liquid broth, and maintaining itself when the cells cultured in the medium are removed, for example, the supernatant remaining when cells cultured in a liquid broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art; which comprises, for example, the metabolites produced by the respective microorganism and secreted in the culture medium. The term "culture medium", sometimes also referred to as "supernatant" can be obtained, for example, by centrifuging at temperatures of about 2 to 30 ° C (most preferably, at temperatures of 4 to 20 ° C C) for about 10 to 60 minutes (preferably, about 15 to 30 minutes) to about 5,000 to 20,000 xg (more preferably, about 15,000 xg).
[0380] [0380] As used herein, the term "supernatant" refers to the remaining liquid broth when cells grown in broth are removed by centrifugation, filtration, sedimentation, or other means well known in the art.
[0381] [0381] As used herein, the term "cell-free extract" refers to an extract of the vegetative cells, spores and / or total culture broth of a microorganism that comprises the cellular metabolites produced by the respective microorganism that can be obtained through cell disruption methods known in the art, such as solvent-based (for example, organic solvents such as alcohols, sometimes in combination with suitable salts), based on temperature, application of shear, disruption of the cell with an ultrasonicator. The desired extract can be concentrated using conventional concentration techniques, such as drying, evaporation, centrifugation and the like. Certain washing steps using organic solids and / or water-based media, can also be applied to the crude extract, preferably before use.
[0382] [0382] The term “metabolite” refers to any compound, substance or by-product produced by a microorganism (such as fungi and bacteria) that has the improved growth of vegetables, the efficiency of using vegetable water, the health of the vegetable, appearance of the plant, or population of beneficial soil microorganisms surrounding plant activity. In particular, as used herein, the term "metabolite" refers to any component, compound, substance or by-product (including, but not limited to, small molecule secondary metabolites, polyketides, fatty acid synthase products, non-ribosomal peptides, ribosomal peptides, proteins and enzymes) produced by a microorganism (such as fungi and bacteria, in particular, the strains of the present invention) which have some beneficial effect, as described in the present, such as the pesticidal or growth enhancing activity of plants, efficiency of the use of water from the plant, health of the plant, appearance of the plant, or population of beneficial microorganisms in the soil around the activity of the plant at present.
[0383] [0383] As used herein, the term "isolate" refers to a pure microbial culture separated from its natural origin, such an isolate obtained by culturing a single microbial colony. An isolate is a pure culture derived from a heterogeneous, wild population of microorganisms.
[0384] [0384] The term "mutant" refers to a microorganism obtained by direct mutant selection, but it also includes microorganisms that have still been mutagenized or otherwise manipulated (for example, through the introduction of a plasmid). Therefore, the embodiments include mutants, variants or and derivatives of the respective microorganism, naturally occurring and artificially induced mutants. For example, mutants can be induced by subjecting the microorganism to known mutagens, such as N-methyl-nitrosoguanidine, using conventional methods.
[0385] [0385] Compositions comprising cell-free extracts and / or metabolites from microbial pesticides selected from groups (L1), (L3) and (L5) as defined herein can be prepared in the form of compositions comprising, in addition to of the active ingredients, at least one ingredient inert by usual means, for example, by the means provided for the compositions of compounds I. With reference to the usual ingredients of such compositions, reference is made to the explanations provided for the compositions containing the compounds I.
[0386] [0386] Compositions comprising at least one compound I and cells, spores and / or total broth culture from at least one microbial pesticide selected from groups (L1), (L3) and (L5) as defined herein, can be prepared in the form of compositions that comprise, in addition to the active ingredients, at least one inert (auxiliary) ingredient by usual means (see, for example, HD Burges: Formulation of Microbial Biopesticides, Springer, 1998), for example, by the means provided for the compositions of compounds I. The usual suitable types of such compositions are suspensions, dust, powders, pastes, granules, capsules, presses, and mixtures thereof. Examples of the types of composition are suspensions (for example, SC, OD, FS), capsules (for example, CS, ZC), pastes, lozenges, dusts or wettable powders (for example, WP, SP, WS, DP, DS), pressed (for example, BR, TB, DT), granules (for example, WG, SG, GR, FG, GG, MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of plant propagation materials, such as seeds (GF), for example. At present, it must be taken into account that each type of formulation or the selection of the auxiliary must not influence the viability of the microorganism during the storage of the composition and, finally, when applied to the propagation material of the plant. Suitable formulations, for example, are mentioned in WO 2008/002371, US patents 6,955,912, US 5,422,107.
[0387] [0387] Examples of suitable auxiliaries are, in addition to those mentioned earlier in the present, UV stabilizers or nutrients. Examples of suitable auxiliaries are those mentioned earlier in the present, in which care must be taken that the selection and quantities of these auxiliaries should not influence the viability of microbial pesticides in the composition. Especially for bactericides and solvents, the compatibility with the respective microorganism of the respective microbial pesticide needs to be taken into account. In addition, compositions with microbial pesticides may still contain stabilizers or nutrients and UV protectors.
[0388] [0388] Suitable stabilizers or nutrients, for example, are alpha-tocopherol, trehalose, glutamate, potassium sorbate, various sugars such as glucose, sucrose, lactose, maltodextrin (HD Burges Formulaztion by Micobial Biopestcides, Springer, 1998) . Suitable UV protectors, for example, are inorganic compounds such as titanium dioxide, zinc oxide and iron oxide pigments or organic compounds such as benzophenones, benzotriazols, phenyltriazines. The compositions, in addition to the aids mentioned for the compositions comprising the compounds of Formula I of the present invention, may optionally contain from 0.1 to 80% of stabilizers or nutrients and from 0.1 to 10% of UV protectors.
[0389] [0389] According to the present invention, the solid material (dry matter) of biopesticides (with the exception of oils such as neem oil, Tagetes oil, and the like) is considered to be active components (for example, to be obtained after drying or evaporation of the extraction medium or the suspension medium in the case of liquid formulations of microbial pesticides).
[0390] [0390] According to the present invention, the weight ratios and percentages used in the present for the biological extract, such as Quillay extract are based on the total weight of the dry matter content (solid material) of the respective extract ( s).
[0391] [0391] The total weight proportions of the compositions comprising at least one microbial pesticide, in the form of viable microbial cells, including inactive forms, can be determined using the CFU amount of the respective micro-organism for the calculation of the total weight of the respective active component, with the following equation where 1 x 1010 CFU is equivalent to one gram in total weight of the respective active component. The colony-forming unit is measured by viable microbial cells, in particular, fungi and bacterial cells. In addition, at present the term "CFU" can also be understood as the number of individual (juvenile) nematodes in the case of nematode (entomopathogenic) biopesticides, such as Steinernema feltiae.
[0392] [0392] In binary compositions and compositions, according to the present invention, the weight ratio of component I to component II, in general, depends on the properties of the active components used, usually in the range from 1: 100 to 100: 1, regularly in the range from 1:50 to 50: 1, preferably in the range from 1:20 to 20: 1, most preferably, in the range from 1:10 to 10: 1 , even more preferably, in the range from 1: 4 to 4: 1 and, in particular, in the range from 1: 2 to 2: 1.
[0393] [0393] According to the additional realizations of the compositions and binary compositions, the weight ratio of component I to component II, in general, is in the range from 1,000: 1 to 1: 1, usually in the range from from 100: 1 to 1: 1, regularly, in the range from 50: 1 to 1: 1, preferably in the range from 20: 1 to 1: 1, most preferably, in the range from 10 : 1 to 1: 1, even more preferably, in the range from 4: 1 to 1: 1 and in particular, in the range from 2: 1 to 1: 1.
[0394] [0394] According to other realizations of binary compositions and compositions, the weight ratio of component I to component II, in general, is in the range from 1: 1 to 1: 1,000, it is usually in the range from from 1: 1 to 1: 100, regularly, in the range from 1: 1 to 1:50, preferably in the range from 1: 1 to 1:20, most preferably, in the range from 1 : 1 to 1:10, even more preferably, in the range from 1: 1 to 1: 4, in particular, in the range from 1: 1 to 1: 2.
[0395] [0395] According to the additional achievements of the compositions and compositions, the weight ratio of component I to component II usually depends on the properties of the active components used, it is usually in the range from 1: 10,000 to 10,000: 1, regularly in the range from 1: 100 to 10,000: 1, preferably in the range from 1: 100 to 5000: 1, most preferably, in the range from 1: 1 to 1,000: 1, most preferably , in the range from 1: 1 to 500: 1, and in particular, in the range from 10: 1 to 300: 1.
[0396] [0396] According to the additional achievements of the compositions and compositions, the weight ratio of component I to component II, is usually in the range from 20,000: 1 to 1:10, often in the range from 10,000: 1 1: 1, regularly in the range from 5,000: 1 to 5: 1, preferably in the range from 5,000: 1 to 10: 1, most preferably, in the range from 2,000: 1 to 30: 1, even more preferably, in the range from 2,000: 1 to 100: 1 and, in particular, in the range from 1,000: 1 to 100: 1.
[0397] [0397] According to the additional achievements of the compositions and compositions, the weight ratio of component I to component II, is usually in the range from 1: 20,000 to 10: 1, often in the range from 1: 10,000 to 1: 1, regularly in the range from 1: 5,000 to 1: 5, preferably in the range from 1: 5,000 to 1:10, most preferably, in the range from 1: 2,000 to 1: 30, even more preferably, in the range from 1: 2,000 to 1: 100 and, in particular, in the range from 1: 1,000 to 1: 100.
[0398] [0398] In ternary compositions, that is, compositions according to the present invention, comprising component I and component II and a component III, the weight ratio of component I to component II depends on the properties of the substances active used, normally, is in the range from 1: 100 to 100: 1, regularly, in the range from 1:50 to 50: 1, preferably in the range from 1:20 to 20: 1, most preferably, in the range from 1:10 and 10: 1, in particular, in the range from 1: 4 to 4: 1, and the weight ratio of component I to component III is usually in the range from 1: 100 to 100: 1, regularly, in the range from 1:50 to 50: 1, preferably in the range from 1:20 to 20: 1, more preferably, in the range from 1:10 and 10: 1, in particular, in the range from 1: 4 to 4: 1.
[0399] [0399] Any other additional active components, if appropriate, are added in a ratio of 20: 1 to 1:20 for componentI.
[0400] [0400] These proportions are also suitable for the compositions of the present invention applied through seed treatment.
[0401] [0401] For microbial pesticides II selected from groups (L1), (L3) and (L5), the proportions by weight and / or percentages refer to the total weight of a preparation of the respective biopesticide II with at least 1 x 106 CFU / g (“colony forming units per gram of total weight”), preferably with at least 1 x 108 CFU / g, more preferably from 1 x 108 to 1 x 1012 CFU / g of matter dry. The colony-forming unit is a measure of viable microbial cells, in particular, fungi and bacterial cells. In addition, at present, CFU can also be understood as the number of individual (juvenile) nematodes in the case of nematode (entomopathogenic) biopesticides, such as Steinernema feltiae.
[0402] [0402] At present, microbial pesticides II selected from groups (L1), (L3) and (L5) can be supplied in any physiological state such as active or inactive. Such inactive active component can be supplied, for example, frozen, dried, or lyophilized or partially dehydrated (procedures for the production of these partially dehydrated organisms are provided in publication WO 2008/002371) or in the form of spores.
[0403] [0403] The microbial pesticides II selected from groups (L1), (L3) and (L5) used as an organism in an active state can be delivered in a growth medium without any additional additives or materials or in combination with the compositions adequate nutrients.
[0404] [0404] According to another embodiment, microbial pesticides II selected from groups (L1), (L3) and (L5) are delivered and formulated in an inactive stage, most preferably in the form of spores.
[0405] [0405] The proportions in total weight of the compositions in which the component (3) is selected from the groups (L1), (L3) and (L5) can be determined based on the total weight of the solid material (dry matter) of the component (1) and using the amount of CFU of the component (2) to calculate the total weight of the component (2) with the following equation that 1 x 109 CFU equals one gram in total weight of the component (2).
[0406] [0406] According to one embodiment, the compositions, in which component (3) is selected from groups (L1), (L3) and (L5), comprise between 0.01 and 90% (w / w) dry matter (solid material), component (1) and 1 x 10 5 CFU to 1 x 1012 CFU of component (2) per gram of the total weight of the composition.
[0407] [0407] According to another embodiment, the compositions, in which component (3) is selected from groups (L1), (L3) and (L5), comprise between 5 and 70% (w / w) of dry matter (solid material), component (1) and from 1 x 106 CFU to 1 x 1010 CFU of component (2) per gram of the total weight of the composition.
[0408] [0408] According to another embodiment, the compositions, in which component (3) is selected from groups (L1), (L3) and (L5), comprise between 25 and 70% (w / w) of dry matter (solid material), component (1) and from 1 x 107 CFU to 1 x 109 CFU of component (2) per gram of the total weight of the composition.
[0409] [0409] In the case of compositions comprising microbial pesticides II selected from groups (L1), (L3) and (L5), application rates preferably range from about 1 x 106 to 5 x 1015 (or higher) CFU / ha. Preferably, the spore concentration is from about 1 x 10 7 to about 1 x 10 11 CFU / ha. In the case of nematodes (entomopathogenic) such as microbial pesticides (eg Steinernema feltiae), application rates preferably range from about 1 x 105 to 1 x 1012 (or higher), most preferably from from 1 x 108 to 1 x 1011, most preferably from 5 x 108 to 1 x 1010 individuals (for example, in the form of eggs, juvenile or any other live stage, preferably in an infective juvenile stage ) per ha.
[0410] [0410] In the case of compositions comprising microbial pesticides II selected from groups (L1), (L3) and (L5), application rates in relation to plant propagation material preferably vary from about 1 x 106 to 1 x 1012 (or greater) CFU / seed. Preferably, the concentration is from about 1 x 106 to about 1 x 1011 CFU / seed. In the case of microbial pesticides III, selected from groups (L1), (L3) and (L5), application rates in relation to plant propagation material, also, preferably, vary from about 1 x 107 to 1 x 1014 (or greater) CFU per 100 kg of seed, preferably from 1 x 109 to about 1 x 1011 CFU per 100 kg of seed.
[0411] [0411] In the case of mixtures comprising microbial pesticides selected from groups II (L1), (L3) and (L5), the microorganisms, as used in accordance with the present invention, can be grown continuously or batchwise in the batch process or in the repeated batch or batch feed process. A review of known cultivation methods will be found in the book by Chmiel (Bio-Prozesstechnik 1. Einführung in die Bioverfahrenstechnik (Gustav Fischer Verlag, Stuttgart, 1991)) or in the textbook by Storhas (Bioreaktoren und periphere Einrichtungen (Vieweg Verlag, Braunschweig / Wiesbaden, 1994)). The culture medium used must meet the requirements of the particular strains in an appropriate manner. Descriptions of the culture media for various microorganisms are provided in the "Manual of General Bacteriology Methods" manual of the American Society of Bacteriology (Washington DC, USA, 1981). These culture media that can be used according to the present invention, in general, comprise one or more carbon sources, nitrogen sources, inorganic salts, vitamins and / or trace elements. Preferred sources of carbon are sugars, such as mono-, di- or polysaccharides. Very good sources of carbon, for example, are glucose, fructose, mannose, galactose, ribose, sorbose, ribulose, lactose, maltose, sucrose, raffinose, starch or cellulose. Sugars can also be added to the media through complex compounds, such as molasses, or other by-products of sugar refining. It can also be advantageous to add mixtures from different carbon sources. Other possible sources of carbon are oils and fats such as soybean oil, sunflower oil, peanut oil and coconut oil, fatty acids such as palmitic acid, stearic acid or linoleic acid, alcohols such as glycerol , methanol or ethanol and organic acids such as acetic acid or lactic acid. Nitrogen sources, in general, are organic or inorganic nitrogen compounds or materials containing these compounds. Examples of nitrogen sources include ammonium salts or ammonia gas, such as ammonium sulfate, ammonium chloride, ammonium phosphate, ammonium carbonate or ammonium nitrate, nitrates, urea, amino acids or complex sources of nitrogen, such as corn liqueur, soy flour, soy protein, yeast extract, meat extract and others. The nitrogen sources can be used separately or as a mixture. The inorganic salt compounds that may be present in the media comprise the chloride, phosphate or salts of calcium, magnesium, sodium, cobalt, molybdenum, potassium, manganese, zinc, copper and iron. Sulfur-containing inorganic compounds, for example, sulphates, sulphites, dithionites, thiosulphates, tetrathionates, sulphides, but also organic sulfur compounds, such as mercaptans and thiols, can be used as sulfur sources. Phosphoric acid, potassium dihydrogen phosphate or dipotassium hydrogen phosphate or the corresponding sodium-containing salts can be used as sources of phosphorus. Chelating agents can be added to the medium in order to keep the metal ions in solution. Suitable chelating agents, especially dihydroxyphenols, such as catechol or protocatecoate, or organic acids, such as citric acid. The culture media used can also contain other growth factors, such as vitamins or growth promoters which include, for example, biotin, riboflavin, thiamine, folic acid, nicotinic acid, pantothenate and pyridoxine. Growth factors and salts often originate from complex components of the media, such as yeast extract, molasses, corn liquor and the like. In addition, suitable precursors can be added to the culture medium. The exact composition of the compounds in the medium is strongly dependent on the experience in particular and must be decided individually for each specific case. Information on medium optimization can be found in the book “Applied Microbiol. Physiology, A Practical Approach ”(Publ. P.M. Rhodes, P.F. Stanbury, IRL Press (1997) p. 53-73, ISBN 0 19 963577 3). The culture media can also be obtained from commercial suppliers, such as Standard 1 (Merck) or BHI (brain and heart infusion, DISCO), and the like. All the components of the medium are sterilized, by heating (20 min at 2.0 bar and 121º C) or by sterile filtration. The components can be sterilized together, or separately, if necessary. All components of the medium can be present at the beginning of the growth, or, optionally, they can be added by continuous or batch feeding. The culture temperature of the respective microorganism is usually between 15 ° C and 45 ° C, preferably 25 ° C to 40 ° C and can be kept constant or can be varied during the experiment. The pH value of the medium should be in the range of 5 to 8.5, preferably about 7.0. The pH value for growth can be controlled during its growth by adding basic compounds such as sodium hydroxide, potassium hydroxide, ammonia or ammonia water or acid compounds, such as phosphoric acid or sulfuric acid. Defoaming agents, for example, fatty acid polyglycol esters, can be used to control foaming. To maintain the stability of plasmids, suitable substances with selective action, for example, antibiotics, can be added to the medium. Oxygen or gas mixtures that contain oxygen, for example, ambient air, are fed into the culture to maintain aerobic conditions. The temperature of the culture is usually from 20 ° C to 45 ° C. The culture is continued until a maximum of the desired product is formed. This is usually achieved within 10 hours to 160 hours. To obtain cell-free extracts, cells can be optionally interrupted by high frequency ultrasound, by high pressure, for example, in a French pressure cell, by osmolisis, by the action of detergents, lytic enzymes or organic solvents, by means of homogenizers or a combination of several of the methods listed. The methodology of the present invention can further include a step of recovering individual compositions, such as cell-free extracts, metabolite supernatants, or the like. The term "recovery" includes the extraction, harvesting, isolation or purification of an extract, supernatant or metabolite, for example, from total culture broth. Recovery can be carried out in accordance with any isolation or purification of conventional methodology known to the person skilled in the art, including, but not limited to treatment with a conventional resin (eg anion or cation exchange resin, non-adsorption resin). ionic, and the like), treatment with a conventional adsorbent (for example, activated charcoal, silicic acid, silica gel, cellulose, alumina, and the like), pH change, solvent extraction (for example, with a conventional solvent , such as an alcohol, ethyl acetate, hexane and the like), distillation, dialysis, filtration, concentration, crystallization, recrystallization, pH adjustment, lyophilization and the like. For example, the agent can be recovered from culture media by first removing the microorganisms. The remaining broth is then passed through or over a cation exchange resin to remove unwanted cations and then through or over an anion exchange resin to remove unwanted inorganic anions and organic acids.
[0412] [0412] The compositions according to the present invention are suitable as fungicides. They are distinguished by an excellent efficacy against a wide spectrum of phytopathogenic fungi, including soil fungi, which are mainly derived from the classes of Plasmodiophoromycetes, Peronosporomycetes (syn. Oomycetes), Chytridiomycetes, Zygomycetes, Ascomycetes, Basidiomycetes and Deuteromy Fungi imperfecti). Some are systemically effective and can be used to protect crops, such as foliar fungicides, fungicides for seed treatment and soil fungicides. In addition, they are suitable for combating harmful fungi, which occur, inter alia, in wood or in the roots of vegetables.
[0413] [0413] The compositions according to the present invention are especially important for the control of a variety of pathogenic fungi in various crop vegetables, such as cereals, for example, wheat, rye, barley, triticale, oats or rice; beet, for example, sugar beet or fodder beet; fruits, such as apples, stone fruits or soft fruits, for example, apples, pears, plums, peaches, almonds, cherries, strawberries, raspberries, blackberries or currants; legumes, such as lentils, peas, alfalfa or soy; oilseed vegetables, such as rapeseed, mustard, olives, sunflowers, coconut, cocoa, castor oil vegetables, palm oil, peanuts or soybeans; cucurbits, such as pumpkins, cucumbers or melons; fiber vegetables, such as cotton, linen, hemp or jute; citrus fruits, such as oranges, lemons, grapefruits and tangerines; vegetables, such as spinach, lettuce, asparagus, cabbage, carrots, onions, tomatoes, potatoes, pumpkins or paprika; lauraceous vegetables, such as avocado, cinnamon or camphor; vegetables with raw materials and energy, such as corn, soybeans, rapeseed, sugar cane or palm oil; corn; tobacco; nuts; coffee; tea; the vineyards (table grapes and grape juice vines); hop; lawn; fennel (also called Stevia); natural rubber vegetables or ornamental and forestry vegetables, such as flowers, shrubs, broadleaf or evergreen trees, for example, conifers, and in the propagation material of vegetables, such as seeds, and growing material of these vegetables.
[0414] [0414] Preferably, the compositions of the present invention are used to control a wide variety of fungi in crops, such as potatoes, sugar beets, tobacco, wheat, rye, barley, oats, rice, corn, cotton, soybeans, rapeseed, vegetables, sunflower, coffee or sugar cane; fruits; vineyards; ornamental vegetables; or vegetables, such as cucumbers, tomatoes, beans or pumpkins.
[0415] [0415] The term “plant propagating material” should be understood as designating all the generative parts of the plant, such as seeds and vegetative plant material such as grafts and tubers (for example, potatoes), which can be used for the multiplication of the vegetable. This includes seeds, roots, fruits, tubers, bulbs, rhizomes, stems, shoots and other parts of plants, including seedlings and young plants, which will be transplanted after germination, or after emergence from the soil. These young vegetables can also be protected before transplantation by total or partial treatment by immersion or spillage.
[0416] [0416] Preferably, the treatment of plant propagation materials with the components of the compositions of the present invention and the compositions of the present invention, respectively, are used to control a multiplicity of fungi in cereals, such as wheat, rye, barley and oats; rice, corn, cotton and soy.
[0417] [0417] The term “cultivated vegetables” is to be understood as including plants that have been modified through reproduction, mutagenesis or genetic engineering, including, but not limited to, biotechnological agricultural products on the market or in development (cf. http: // cera -gmc.org/, see database of GM crops). Genetically modified vegetables are vegetables in which the genetic material has been modified in this way, through the use of recombinant DNA techniques that in natural circumstances cannot be easily obtained through cross-breeding, mutations or natural recombination. Typically, one or more genes have been integrated into the genetic material of a genetically modified plant, to enhance certain properties of the plant. These genetic modifications include, but are not limited to, the target post-transitional modification of protein (s), oligo- or polypeptide, for example, through glycosylation or addition of polymers, such as the prenylated, acetylated or farnesylated portions of PEG.
[0418] [0418] Vegetables that have been modified through reproduction, mutagenesis or genetic engineering, have become, for example, tolerant to applications of specific classes of herbicides, such as auxin herbicides, such as dicamba or 2,4-D; bleaching herbicides, such as 4-hydroxyphenylpyruvate (HPPD) dioxigenase inhibitors or phytoene desaturase (PDS) inhibitors; acetolactate synthase (ALS) inhibitors such as sulfonyl ureas or imidazolinones; enolpyruvyl chiquimate-3-phosphate synthase (EPSP) inhibitors, such as glyphosate; glutamine synthetase (GS) inhibitors such as glufosinate; protoporphyrinogen-IX oxidase inhibitors; inhibitors of lipid biosynthesis, such as acetylCoA carboxylase (ACCase) inhibitors; or oxynyl herbicides (i.e., bromoxynil or ioxynil), as a result of conventional methods of reproduction or genetic engineering; in addition, vegetables have been made resistant to various classes of herbicides through multiple genetic modifications, such as resistance to glyphosate and glufosinate or glyphosate and a herbicide, from another class such as ALS inhibitors, HPPD inhibitors, auxin herbicides, ACCase inhibitors. These herbicide resistance technologies, for example, are described in Pest Management Science 61, 2005, 246, 61, 2005, 258, 61, 2005, 277, 61, 2005, 269, 61, 2005, 286, 64, 2008, 326; 64, 2008, 332; Weed Science 57, 2009, 108; Australian Journal of Agricultural Research 58, 2007, 708; Science 316, 2007, 1,185, and references cited above. Cultivated vegetables have been made tolerant to herbicides through mutagenesis and conventional methods of reproduction, for example, rapeseed oil from Clearfield® (Canola, BASF SE, Germany) being tolerant to imidazolinones, for example, imazamox, or ExpressSun® sunflowers (DuPont, USA) being tolerant to sulfonyl ureas, for example, tribenurone. Genetic engineering methods have been used to make cultivated vegetables, such as soybeans, cotton, corn, beets and rapeseed, herbicide-tolerant, such as glyphosate and glufosinate, some of which are commercially available under the trade names RoundupReady® ( tolerant to glyphosate, Monsanto, USA), Cultivance® (tolerant to imidazolinones, BASF SE, Germany) and Libertilink® (tolerant to glufosinate, Bayer CropScience, Germany).
[0419] [0419] Furthermore, the vegetables also covered are those that, through the use of recombinant DNA techniques, are able to synthesize one or more insecticidal proteins, especially those known from bacteria of the genus Bacillus, especially from Bacillus thuringiensis, such as δ-endotoxins, for example, CryIA (b), CryIA (c), CrilF, CrilF (a2), CrillA (b), CrilllA, CrilllB (b1) or Cry9c; vegetative insecticidal proteins (VIP), for example, VIP1, VIP2, VIP3 or VIP3A; the insecticidal proteins of bacterial colonizing nematodes, for example, Photorhabdus spp. or Xenorhabdus spp., toxins produced by animals, such as scorpion toxins, arachnid toxins, wasp toxins, or other neurotoxins specific to other insects, toxins produced by fungi, such as Streptomycetes toxins, plant lectins, such such as pea or barley lectins; agglutinins; proteinase inhibitors, such as trypsin inhibitors, serine protease inhibitors, patatin, cystatin or papain inhibitors; ribosome inactivation proteins (RIP), such as ricin, corn RIP, abrina, lufin, saporin or briodine, steroid metabolism enzymes, such as 3-hydroxysteroid oxidase, ecdysteroid-IDP-glycosyl transferase , cholesterol oxidase, ecdysone or HMG-CoA reductase inhibitors; ion channel blockers, such as sodium or calcium channel blockers; juvenile hormonal esterase; diuretic hormone receptors (helicoquinine receptors); stilbene synthase, bibenzyl synthase, chitinases or glucanases. In the context of the present invention, these insecticidal proteins or toxins are also expressly understood as pre-toxins, truncated or hybrid proteins, proteins modified in another way. Hybrid proteins are characterized by a new combination of protein domains, (see, for example, publication WO 2002/015701). Other examples of such toxins or genetically modified plants, capable of synthesizing such toxins, for example, are described in EP-A 374.753, WO 1993/007278, WO 1995/34656, EP-A 427.529, EP-A 451.878, WO 2003 / 18810 and WO 2003/52073. The methods for producing such genetically modified vegetables are generally known to the person skilled in the art and are described, for example, in the publications mentioned above. These insecticidal proteins contained in genetically modified vegetables provide the plants that produce these proteins with tolerance to pests of all taxonomic groups of arthropods, especially beetles (Coeloptera), bialated insects (Diptera) and moths (Lepidoptera) and nematodes (Nematoda). Genetically modified vegetables capable of synthesizing one or more insecticidal proteins are, for example, described in the publications mentioned above, and some are commercially available, such as YieldGard® (corn cultivars that produce the Cry1Ab toxin), YieldGard® Plus ( corn cultivars that produce Cry1Ab and Cry3Bb1 toxins), Starlink® (corn cultivars that produce Cry9c toxin), Herculex® RW (corn cultivars that produce Cry34Ab1, Cry35Ab1 and the enzyme Fosfinotricina-N-acetyltransferase [PAT]); NuCOTN® 33B (cotton cultivars that produce the Cry1Ac toxin), Bollgard® I (cotton cultivars that produce the Cry1Ac toxin), Bollgard® II (cotton cultivars that produce the Cry1Ac and Cry2Ab2 toxins); VipCot® (cotton cultivars that produce the VIP toxin); Newleaf® (potato cultivars that produce the Cry3A toxin); Bt-Xtra®, NatureGard®, KnockOut®, BiteGard®, Protecta®, Bt11 (for example, Agrisure® CB) and Bt176 from Syngenta Seeds SAS, France, (corn cultivars that produce the Cry1Ab toxin and PAT enzyme), MIR604 from Syngenta Seeds SAS, France (corn cultivars that produce a modified version of the Cry3A toxin, cf publication WO 2003/018810), MON 863 from Monsanto Europe SA, Belgium (corn cultivars that produce the Cry3Bb1 toxin), IPC531 from Monsanto Europe SA, Belgium (cotton cultivars that produce a modified version of the Cry1Ac toxin) and 1,507 from Pioneer Overseas Corporation, Belgium (corn cultivars that produce the Cry1F toxin and PAT enzyme).
[0420] [0420] In addition, the vegetables also covered are those that, through the use of recombinant DNA techniques, are able to synthesize one or more proteins to increase the resistance or tolerance of said plants to bacterial, viral and fungal pathogens. Examples of such proteins are the so-called “pathogenesis-related proteins” (PR proteins, see, for example, EP-A 392,225), genes for resistance to plant diseases (for example, potato cultivars, which express resistance genes acting against Phytophthora infestans derived from Mexican wild potato Solanum bulbocastanum) or T4-Lysozyme (for example, potato cultivars capable of synthesizing these proteins, with increased resistance against bacteria, such as Erwinia amilvora). The methods for producing such genetically modified vegetables are generally known to the person skilled in the art and are described, for example, in the publications mentioned above.
[0421] [0421] In addition, the vegetables also covered are those that, through the use of recombinant DNA techniques, are able to synthesize one or more proteins to increase productivity (for example, biomass production, grain yield, content of starch, oil content or protein content), tolerance to aridity, salinity or other environmental limiting factors for growth or tolerance to pests and fungal, viral or bacterial pathogens of these vegetables.
[0422] [0422] In addition, the vegetables also covered are those that, through the use of recombinant DNA techniques, contain a modified amount of ingredients or new ingredients, specifically to improve human or animal nutrition, for example, oil cultures that produce long-chain omega-3 fatty acids or unsaturated omega-9 fatty acids that promote health (eg Nexera® rapeseed, DOW Agro Sciences, Canada).
[0423] [0423] In addition, the vegetables also covered are those that, through the use of recombinant DNA techniques, contain a modified amount of ingredients or new ingredients, specifically to improve the production of raw material, for example, potatoes that produce quantities increased amounts of amylopectin (eg Amflora® potato, BASF SE, Germany).
[0424] - Albugo spp. (ferrugem branca) nos vegetais ornamentais, legumes (por exemplo, A. Candida) e girassóis (por exemplo, A. tragopogonis); Alternaria spp. (mancha foliar Alternaria) nos vegetais, colza (A. brassicola ou brassicae), beterrabas de açúcar (A. tenuis), frutos, arroz, soja, batatas (por exemplo, A. solani ou A. alternata), tomates (por exemplo, A. solani ou A. alternata) e trigo; Aphanomyces spp. nas beterrabas de açúcar e legumes; Ascochyta spp. nos cereais e legumes, por exemplo, A. tritici (antracnose) no trigo e A. hordei na cevada; Bipolaris e Drechslera spp. (teleomorfo: Cochliobolus spp.), por exemplo, mancha foliar do sul (D. maydis) ou mancha foliar do norte (B. zeicola) no milho, por exemplo, mancha marrom (B. sorokiniana) nos cereais e, por exemplo, B. oryzae no arroz e relvados; Blumeria (anteriormente Erysiphe) graminis (oídio) nos cereais (por exemplo, trigo ou cevada); Botrytis cinerea (teleomorfo: Botryotinia fuckeliana: bolor cinzento) nas frutas e bagas (por exemplo, os morangos), legumes (por exemplo, a alface, cenoura, aipo e repolho), colza, flores, vinhas, vegetais florestais e trigo; Bremia lactucae (míldio) na alface; Ceratocystis (syn. Ophiostoma) spp. (apodrecimento ou murcha) nas árvores de folhas largas e sempre-vivas, por exemplo, C. ulmi (doença do olmo holandês) nos olmos; Cercospora spp. (manchas foliares Cercospora) no milho, arroz, beterrabas de açúcar (por exemplo, C. beticola), cana de açúcar, legumes, café, soja (por exemplo, C. sojina ou C. kikuchii) e arroz; Cladosporium spp. nos tomates (por exemplo, C. fulvum: o bolor da folha) e cereais, por exemplo, C. herbarum (ponto preto) no trigo; Claviceps purpurea (ergot) em cereais; Cochliobolus (anamorfo: Helminthosporium of Bipolaris) spp. (manchas foliares) no milho (C. carbonum), cereais (por exemplo, C. sativus, anamorfo: B. sorokiniana) e arroz (por exemplo, C. miyabeanus, anamorfo: H. oryzae); Colletotrichum (teleomorfo: Glomerella) spp. (anthracnose) no algodão (por exemplo, C. gossypii), milho (por exemplo, C. graminicola: apodrecimento do colmo antracnose), frutos vermelhos, batatas (por exemplo, C. coccodes: pontos pretos), feijão (por exemplo, C. Iindemuthianum) e soja (por exemplo, C. truncatum ou C. gloeosporioides); Corticium spp., por exemplo, C. sasakii (praga bainha) no arroz; Corynespora cassiicola (manchas foliares) na soja e vegetais ornamentais; Cicloconium spp., por exemplo, C. oleaginum nas oliveiras; Cilindrocarpon spp. (por exemplo, caroço das árvores de fruto ou declínio da videira jovem, teleomorfo: Nectria ou Neonectria spp.) nas árvores de frutos, vinheiras (por exemplo, C. liriodendri, teleomorfo: Neonectria liriodendri: doença Preta do pé) e vegetais ornamentais; Dematophora (teleomorfo: Rosellinia) necatrix (apodrecimento da raiz e caule) na soja; Diaporthe spp., por exemplo, D. phaseolorum (tombamento) na soja; Drechslera (syn. Helminthosporium, teleomorfo: Pyrenophora) spp. no milho, cereais, tal como a cevada (por exemplo, D. teres, mancha reticular) e trigo (por exemplo, D. triticirepentis: mancha marrom), arroz e turfa; Esca (perecimento, apoplexia) nas videiras, ocasionada por Formitiporia (syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (anteriormente Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum e/ou Botryosphaeria obtusa; Elsinoe spp. nas frutas de pomo (E. Piri.), frutos macios (E. veneta: antracnose) e videiras (E. ampelina: antracnose); Entiloma oryzae (carvão da folha) no arroz; Epicoccum spp. (bolor negro) no trigo; Erysiphe spp. (oídio) na beterraba de açúcar (E. betae.), vegetais (por exemplo, E. Pisi), tais como as cucurbitáceas (por exemplo, E. cichoracearum), couves, colza (por exemplo, E. cruciferarum); Eutypa lata (perecimento ou caroço Eutypa, anamorfo: Cytosporina lata, syn Libertella blepharis) nas árvores de fruto, vinhas e bosques ornamentais; Exserohilum (syn. Helminthosporium) spp. no milho (por exemplo, E. turcicum); Fusarium (teleomorfo: Gibberella) spp. (deteriorização, apodrecimento da raiz ou caule) em diversos vegetais, tal como F. graminaarum ou F. culmorum (apodrecimento da raiz, sarna ou copa) nos cereais (por exemplo, trigo ou cevada), F. oxysporum nos tomates, F. solani (f. sp glycines agora syn F. virguliforme.) e F. tucumaniae e F. brasiliense cada ocasionandoa síndrome da morte súbita na soja, e F. verticillioides no milho; Gaeumannomyces graminis (todos) nos cereais (por exemplo, trigo ou cevada) e milho; Gibberella spp. nos cereais (por exemplo, G. zeae) e arroz (por exemplo, G. fujikuroi: doença Bakanae); Glomerella cingulata nas videiras, frutas de pomo e outros vegetais e G. gossypii no algodão; complexo coloração dos grãos no arroz; Guignardia bidwellii (apodrecimento negra) nas videiras; Gymnosporangium spp. nos vegetais rosáceos e zimbros, por exemplo, G. sabinae (ferrugem) nas peras; Helminthosporium spp. (syn. Drechslera, teleomorfo: Cochliobolus) no milho, cereais e arroz; Hemileia spp., por exemplo, H. vastatrix (ferrugem foliar do café) no café; Isariopsis clavispora (syn. Cladosporium vitis) nas videiras; Macrophomina phaseolina (syn. phaseoli). (apodrecimento da raiz e caule) na soja e algodão; Microdochium (sin. Fusarium) nivale (mofo rosa neve) nos cereais (por exemplo, trigo ou cevada); Microsphaera diffusa (oídio) na soja; Monilinia spp., por exemplo, M. laxa, M. fructicola e M. fructigena (ferrugem da flor e galho, apodrecimento pardo) nas frutas de caroço e outros vegetais rosáceos; Mycosphaerella spp. nos cereais, bananas, frutas macias e nozes moídas, tal como, por exemplo, M. graminicola (anamorfo: Septoria tritici, mancha Septoria) no trigo ou M. fijiensis (doença Sigatoka negra) nas bananas; Peronospora spp. (Míldio) no repolho (por exemplo, P. brassicae), colza (por exemplo, P. parasitica), cebola (por exemplo, P. destructor), tabaco (P. tabacina) e soja (por exemplo, P. manshurica); Phakopsora pachyrhizi e P. meibomiae (ferrugem da soja) na soja; Phialophora spp., por exemplo, nas videiras (por exemplo, P. tracheiphila e P. tetraspora) e soja (por exemplo, P. gregata: apodrecimento); Phoma lingam (apodrecimento da raiz e caule) na colza e repolho e P. betae (apodrecimento das raízes, mancha foliar e tombamento) na beterraba de açúcar; Phomopsis spp. nos girassóis, vinheiras (por exemplo, P. viticola: ponto da folha) e soja (por exemplo, apodrecimento do caule: P. phaseoli, teleomorfo: Diaporthe phaseolorum); Physoderma maydis (manchas marrons) no milho; Phytophthora spp. (deteriorização, apodrecimento das raízes, folhas, frutos e caule) em diversos vegetais, tais como a páprica e cucurbitáceas (por exemplo, P. capsici), soja (por exemplo, P. megasperma, syn. P. sojae), batatas e tomates (por exemplo, P. infestans: requeima) e árvores de folhas largas (por exemplo, P. ramorum: morte repentina do carvalho); Plasmodiophora brassicae (raiz do tronco) no repolho, colza, rabanete e outros vegetais; Plasmopara spp., por exemplo, P. viticola (míldio da videira) nas videiras e P. halstedii nos girassóis; Podosphaera spp. (oídio) nos vegetais rosáceos, lúpulo, frutas de pomo e macias, por exemplo, P. leucotricha nas maçãs, Polymyxa spp., por exemplo, nos cereais, tais como a cevada e o trigo (P. graminis) e beterraba de açúcar (P. betae) e, por conseguinte, as doenças virais transmissíveis; Pseudocercosporella herpotrichoides (ocelo, teleomorfo: Tapesia yallundae) nos cereais, por exemplo, o trigo ou cevada; Pseudoperonospora (míldio) em diversos vegetais, por exemplo, P. cubensis nas cucurbitáceas ou P. humili no lúpulo; Pseudopezicula tracheiphila (doença do fogo vermelho ou apodrecimento do brenner, anamorfo: Phialophora) nas videiras; Puccinia spp. (ferrugens) em diversos vegetais, por exemplo, P. triticina (ferrugem marrom ou da folha), P. striiformis (tarja ou ferrugem amarela), P. hordei (ferrugem anã), P. graminis (ferrugem preta ou do caule) ou P. recondita (ferrugem marrom ou da folha) nos cereais, tal como, por exemplo, o trigo, cevada ou centeio, P. kuehnii (ferrugem alaranjada) na cana de açúcar e P. asparagi nos aspargos; Pyrenophora (anamorfo: Drechslera) tritici-repentis (ponto marrom) no trigo ou P. Feres (mancha reticular) na cevada; Piricularia spp., por exemplo, P. oryzae (teleomorfo: Magnaporthe grisea, brusone) no arroz e P. grisea no gramado e cereais; Pythium spp. (lombamento) no gramado, arroz, milho, trigo, algodão, colza, girassol, soja, beterraba de açúcar, legumes e outros vegetais (por exemplo, P. ultimum ou P. aphanidermatum), Ramularia spp., por exemplo, R. collocygni (manchas foliares Ramularia, manchas foliares fisiológicas na cevada) e R. beticola na beterraba de açúcara Rhizoctonia spp. no algodão, arroz, batata, grama, milho, colza, batata, beterraba de açúcar, legumes e diversos outros vegetais, por exemplo, R. solani (apodrecimento da raiz e caule) na soja, R. solani (praga bainha) no arroz ou R. cerealis (praga primavera Rhizoctonia) no trigo ou de cevada, Rhizopus stolonifer (mofo negro, apodrecimento mole) nos morangos, cenouras, couve, vinheiras e tomates, Rhynchosporium secalis (escaldadura) na cevada, centeio e triticale; Sarocladium oryzae e S. attenuatum (apodrecimento da bainha) no arroz; Sclerotinia spp. (apodrecimento ou bolor branco) nos legumes e culturas de campo, tais como a colza, girassóis (por exemplo, S. sclerotiorum) e soja (por exemplo, S. rolfsii ou S. sclerotiorum); Septoria spp. em diversos vegetais, por exemplo, S. glycines (mancha marrom) na soja, S. tritici (mancha Septoria) no trigo e S. (syn. Stagonospora) nodorum (mancha Stagonospora) nos cereais; Uncinula (syn. Erysiphe) necator (oídio, anamorfo: Oidium tuckeri) nas videiras; Setospaeria spp. (praga das folhas) no milho (por exemplo, S. turcicum, syn Helminthosporium turcicum.) e gramado; Sphacelotheca spp. (fuligem) no milho, (por exemplo, S. reiliana: fuligem da copa), sorgo e cana de açúcar; Sphaerotheca fuliginea (oídio) nas cucurbitáceas; Spongospora subterranea (pó de sarna) nas batatas e doenças virais transmissíveis; Stagonospora spp. nos cereais, por exemplo, S. nodorum (mancha Stagonospora, teleomorfo: Leptosphaeria [syn Phaeosphaeria.] nodorum) no trigo; Synchytrium endobioticum nas batatas (doença da verruga da batata); Taphrina spp., por exemplo, T. deformans (doença do enrugamento foliar) nos pêssegos e T. pruni (bolso da ameixa) nas ameixas; Thielaviopsis spp. (apodrecimento da raiz preta) no tabaco, frutas de pomo, legumes, soja e algodão, por exemplo, T. basicola (syn. Chalara elegans); Tilletia spp. (gorgulho comum ou comum ou fuligem fedorenta) nos cereais, tais como, por exemplo, T. tritici (syn. T. caries, bojo de trigo) e T. controversa (bojo anão) no trigo; Typhula incarnata (bolor cinza neve) na cevada ou trigo; Urocystis. spp., por exemplo, U. occulta (fuligem do caule) no centeio; Uromyces spp. (ferrugem) nos vegetais, tal como o feijão (por exemplo, U. appendiculatus, syn U. phaseoli.) na beterraba de açúcar (por exemplo, U. betae); Ustilago spp. (fuligem solta) nos cereais (por exemplo, U. nuda e U. avaenae), no milho (por exemplo, U. maydis: fuligem do milho) e cana de açúcar; Venturia spp. (sarna) nas maçãs (por exemplo, V. inaequalis) e peras; e Verticillium spp. (Murcha) em diversos vegetais, tais como as frutas e vegetais ornamentais, vinheiras, frutos macios, legumes e culturas, por exemplo, V. dahliae nos morangos, colza, batatas e tomates. [0424] The compositions are especially suitable for controlling the following plant diseases: - Albugo spp. (white rust) in ornamental vegetables, legumes (for example, A. Candida) and sunflowers (for example, A. tragopogonis); Alternaria spp. (Alternaria leaf spot) on vegetables, rapeseed (A. brassicola or brassicae), sugar beets (A. tenuis), fruits, rice, soy, potatoes (for example, A. solani or A. alternata), tomatoes (for example , A. solani or A. alternata) and wheat; Aphanomyces spp. sugar beets and vegetables; Ascochyta spp. in cereals and vegetables, for example, A. tritici (anthracnose) in wheat and A. hordei in barley; Bipolaris and Drechslera spp. (teleomorph: Cochliobolus spp.), for example, southern leaf spot (D. maydis) or northern leaf spot (B. zeicola) on corn, for example, brown spot (B. sorokiniana) on cereals and, for example, B. oryzae on rice and lawns; Blumeria (formerly Erysiphe) graminis (powdery mildew) in cereals (for example, wheat or barley); Botrytis cinerea (teleomorph: Botryotinia fuckeliana: gray mold) in fruits and berries (for example, strawberries), vegetables (for example, lettuce, carrots, celery and cabbage), rapeseed, flowers, vines, forest vegetables and wheat; Bremia lactucae (downy mildew) on lettuce; Ceratocystis (syn. Ophiostoma) spp. (rotting or wilting) in broad-leaved and evergreen trees, for example, C. ulmi (Dutch elm disease) in elm trees; Cercospora spp. (Cercospora leaf spots) on maize, rice, sugar beets (for example, C. beticola), sugar cane, vegetables, coffee, soy (for example, C. sojina or C. kikuchii) and rice; Cladosporium spp. in tomatoes (for example, C. fulvum: the mold of the leaf) and cereals, for example, C. herbarum (black spot) in wheat; Claviceps purpurea (ergot) in cereals; Cochliobolus (anamorph: Helminthosporium of Bipolaris) spp. (leaf spots) in corn (C. carbonum), cereals (for example, C. sativus, anamorph: B. sorokiniana) and rice (for example, C. miyabeanus, anamorph: H. oryzae); Colletotrichum (teleomorph: Glomerella) spp. (anthracnose) on cotton (for example, C. gossypii), corn (for example, C. graminicola: anthracnose stem rot), red fruits, potatoes (for example, C. coccodes: black dots), beans (for example, C. Iindemuthianum) and soy (for example, C. truncatum or C. gloeosporioides); Corticium spp., For example, C. sasakii (sheath pest) in rice; Corynespora cassiicola (leaf spots) in soybeans and ornamental vegetables; Cicloconium spp., For example, C. oleaginum in olive trees; Cilindrocarpon spp. (for example, fruit tree core or young vine decline, teleomorph: Nectria or Neonectria spp.) on fruit trees, vineyards (for example, C. liriodendri, teleomorph: Neonectria liriodendri: Black foot disease) and ornamental plants ; Dematophora (teleomorph: Rosellinia) necatrix (root and stem rot) in soybeans; Diaporthe spp., For example, D. phaseolorum (tipping) on soybeans; Drechslera (syn. Helminthosporium, teleomorph: Pyrenophora) spp. in corn, cereals, such as barley (for example, D. teres, reticular spot) and wheat (for example, D. triticirepentis: brown spot), rice and peat; Esca (perishing, apoplexy) on vines, caused by Formitiporia (syn. Phellinus) punctata, F. mediterranea, Phaeomoniella chlamydospora (formerly Phaeoacremonium chlamydosporum), Phaeoacremonium aleophilum and / or Botryosphaeria obtusa; Elsinoe spp. in pommel fruits (E. Piri.), soft fruits (E. veneta: anthracnose) and vines (E. ampelina: anthracnose); Entiloma oryzae (leaf charcoal) in rice; Epicoccum spp. (black mold) in wheat; Erysiphe spp. (powdery mildew) on sugar beet (E. betae.), vegetables (for example, E. Pisi), such as cucurbits (for example, E. cichoracearum), cabbages, rapeseed (for example, E. cruciferarum); Eutypa lata (perishing or Eutypa seed, anamorph: Cytosporina lata, syn Libertella blepharis) in fruit trees, vineyards and ornamental forests; Exserohilum (syn. Helminthosporium) spp. in corn (for example, E. turcicum); Fusarium (teleomorph: Gibberella) spp. (deterioration, root rot or stem) in various vegetables, such as F. graminaarum or F. culmorum (root rot, scab or crown) in cereals (for example, wheat or barley), F. oxysporum in tomatoes, F. solani (f. sp glycines now syn F. virguliforme.) and F. tucumaniae and F. brasiliense each causing the sudden death syndrome in soy, and F. verticillioides in corn; Gaeumannomyces graminis (all) in cereals (for example, wheat or barley) and corn; Gibberella spp. in cereals (for example, G. zeae) and rice (for example, G. fujikuroi: Bakanae disease); Glomerella cingulata on vines, pommel fruits and other vegetables and G. gossypii on cotton; complex coloring of grains in rice; Guignardia bidwellii (black rot) on the vines; Gymnosporangium spp. in pink vegetables and junipers, for example, G. sabinae (rust) in pears; Helminthosporium spp. (syn. Drechslera, teleomorph: Cochliobolus) in corn, cereals and rice; Hemileia spp., For example, H. vastatrix (coffee leaf rust) in coffee; Isariopsis clavispora (syn. Cladosporium vitis) on the vines; Macrophomina phaseolina (syn. Phaseoli). (root and stem rot) in soybeans and cotton; Microdochium (sin. Fusarium) nivale (snow-pink mold) in cereals (for example, wheat or barley); Microsphaera diffusa (powdery mildew) in soybean; Monilinia spp., For example, M. laxa, M. fructicola and M. fructigena (flower and branch rust, brown rot) in stone fruits and other rosy vegetables; Mycosphaerella spp. in cereals, bananas, soft fruits and ground nuts, such as, for example, M. graminicola (anamorph: Septoria tritici, Septoria spot) in wheat or M. fijiensis (black Sigatoka disease) in bananas; Peronospora spp. (Downy mildew) on cabbage (for example, P. brassicae), rapeseed (for example, P. parasitica), onion (for example, P. destructor), tobacco (P. tabacina) and soy (for example, P. manshurica) ; Phakopsora pachyrhizi and P. meibomiae (soybean rust) in soybean; Phialophora spp., For example, on vines (for example, P. tracheiphila and P. tetraspora) and soy (for example, P. gregata: rot); Phoma lingam (root and stem rot) in rapeseed and cabbage and P. betae (root rot, leaf spot and tipping) in sugar beet; Phomopsis spp. in sunflowers, vines (for example, P. viticola: leaf point) and soy (for example, stem rot: P. phaseoli, teleomorph: Diaporthe phaseolorum); Physoderma maydis (brown spots) in corn; Phytophthora spp. (deterioration, rotting of roots, leaves, fruits and stems) in various vegetables, such as paprika and cucurbits (for example, P. capsici), soy (for example, P. megasperma, syn. P. soye), potatoes and tomatoes (for example, P. infestans: late blight) and broadleaf trees (for example, P. ramorum: sudden death of the oak); Plasmodiophora brassicae (stem root) in cabbage, rapeseed, radish and other vegetables; Plasmopara spp., For example, P. viticola (grape downy mildew) on vines and P. halstedii on sunflowers; Podosphaera spp. (powdery mildew) in rosy vegetables, hops, pommel and soft fruits, for example, P. leucotricha in apples, Polymyxa spp., for example, in cereals, such as barley and wheat (P. graminis) and sugar beet (P. betae) and, therefore, communicable viral diseases; Pseudocercosporella herpotrichoides (ocelo, teleomorph: Tapesia yallundae) in cereals, for example, wheat or barley; Pseudoperonospora (downy mildew) on various vegetables, for example, P. cubensis on cucurbits or P. humili on hops; Pseudopezicula tracheiphila (red fire disease or brenner rot, anamorph: Phialophora) on the vines; Puccinia spp. (rust) in various vegetables, for example, P. triticina (brown or leaf rust), P. striiformis (yellow stripe or rust), P. hordei (dwarf rust), P. graminis (black or stem rust) or P. recondita (brown or leaf rust) in cereals, such as, for example, wheat, barley or rye, P. kuehnii (orange rust) in sugar cane and P. asparagi in asparagus; Pyrenophora (anamorph: Drechslera) tritici-repentis (brown spot) in wheat or P. Feres (reticular spot) in barley; Piricularia spp., For example, P. oryzae (teleomorph: Magnaporthe grisea, blast) in rice and P. grisea in lawn and cereals; Pythium spp. (spine) on the lawn, rice, corn, wheat, cotton, rapeseed, sunflower, soy, sugar beet, vegetables and other vegetables (for example, P. ultimum or P. aphanidermatum), Ramularia spp., for example, R. collocygni (Ramularia leaf spots, physiological leaf spots in barley) and R. beticola in the sugar beet Rhizoctonia spp. in cotton, rice, potatoes, grass, corn, rapeseed, potatoes, sugar beet, vegetables and various other vegetables, for example, R. solani (root and stem rot) in soybeans, R. solani (sheath pest) in rice or R. cerealis (spring pest Rhizoctonia) in wheat or barley, Rhizopus stolonifer (black mold, soft rot) in strawberries, carrots, cabbage, vineyards and tomatoes, Rhynchosporium secalis (scald) in barley, rye and triticale; Sarocladium oryzae and S. attenuatum (sheath rot) in rice; Sclerotinia spp. (rotting or white mold) in vegetables and field crops, such as rapeseed, sunflowers (for example, S. sclerotiorum) and soy (for example, S. rolfsii or S. sclerotiorum); Septoria spp. in various vegetables, for example, S. glycines (brown spot) in soy, S. tritici (Septoria spot) in wheat and S. (syn. Stagonospora) nodorum (Stagonospora spot) in cereals; Uncinula (syn. Erysiphe) necator (powdery mildew, anamorph: Oidium tuckeri) on the vines; Setospaeria spp. (leaf pest) in maize (for example, S. turcicum, syn Helminthosporium turcicum.) and lawn; Sphacelotheca spp. (soot) in corn, (for example, S. reiliana: canopy soot), sorghum and sugar cane; Sphaerotheca fuliginea (powdery mildew) in cucurbits; Spongospora subterranea (scabies powder) in potatoes and communicable viral diseases; Stagonospora spp. in cereals, for example, S. nodorum (Stagonospora spot, teleomorph: Leptosphaeria [syn Phaeosphaeria.] nodorum) in wheat; Synchytrium endobioticum in potatoes (potato wart disease); Taphrina spp., For example, T. deformans (leaf wrinkling disease) in peaches and T. pruni (plum pocket) in plums; Thielaviopsis spp. (black root rot) in tobacco, pommel fruit, vegetables, soybeans and cotton, for example, T. basicola (syn. Chalara elegans); Tilletia spp. (common or common weevil or stinking soot) in cereals, such as, for example, T. tritici (syn. T. caries, wheat bowl) and T. controversa (dwarf bowl) in wheat; Typhula incarnata (snow gray mold) in barley or wheat; Urocystis. spp., for example, U. occult (stem soot) in rye; Uromyces spp. (rust) in vegetables, such as beans (for example, U. appendiculatus, syn U. phaseoli.) in sugar beet (for example, U. betae); Ustilago spp. (loose soot) in cereals (for example, U. nuda and U. avaenae), in corn (for example, U. maydis: corn soot) and sugar cane; Venturia spp. (scabies) in apples (for example, V. inaequalis) and pears; and Verticillium spp. (Wilt) in various vegetables, such as ornamental fruits and vegetables, vineyards, soft fruits, vegetables and crops, for example, V. dahliae in strawberries, rapeseed, potatoes and tomatoes.
[0425] [0425] The compositions are also suitable for combating harmful fungi in protecting stored products or crops and in protecting materials. The term “protection of materials” should be understood to indicate the protection of technical and non-living materials, such as adhesives, glues, wood, paper and cardboard, textiles, leather, paint dispersions, plastics, cooling lubricants, fiber or against infestation and destruction by harmful microorganisms, such as fungi and bacteria. Regarding the protection of wood and other materials, special attention is paid to the following harmful fungi: Ascomycetes, such as Ophiostoma spp., Ceratocystis spp., Aureobasidium pullulans., Sclerophoma spp., Chaetomium spp., Humicola spp., Petriella spp. , Trichurus spp., Basidiomycetes, such as Coniophora spp., Coriolus spp., Gloeophillum spp., Lentinus spp., Pleurotus spp., Poria spp., Serpula spp. and Tyromyces spp., Deuteromycetes, such as Aspergillus spp., Cladosporium spp., Penicillium spp., Trichoderma spp., Alternaria spp., Paecilomyces spp. and Zygomycetes, such as Mucor spp., and in addition, in protecting stored products and crops, the following yeast fungi are noteworthy: Candida spp. and Saccharomyces cerevisiae.
[0426] [0426] The compositions can be used to improve the health of a vegetable. The present invention also relates to a method to improve the health of the plant by treating a plant, its propagation material and / or the place where the plant grows or must grow with an effective amount of compounds I and their compositions, respectively .
[0427] [0427] The term “plant health” should be understood to indicate a condition of the plant and / or its products, which is determined by several indicators alone or in combination with each other, such as yield (eg increase in biomass) and / or increase in the content of valuable ingredients), vigor of the vegetable (for example, the improved growth of the vegetable and / or greener leaves (“green effect”)), quality (for example, the improved content or composition of certain ingredients ) and tolerance to abiotic and / or biotic stress. The indicators identified above for a plant's health condition may be interdependent or may work together.
[0428] [0428] The compounds of Formula I may be present in different crystalline modifications, whose biological activity may be different. Compositions comprising such modifications to compounds I are also the subject of the present invention.
[0429] [0429] The compositions are used through the treatment of fungi or vegetables, plant propagation material, such as seeds, soils, surfaces, materials or places to be protected from fungi attack with an effective fungicidal amount of the active substances. The application can be carried out before and after the infection of the plants, propagation materials of the plant, such as seeds, soils, surfaces, materials or places by fungi.
[0430] [0430] Plant propagation materials can be treated with the components of the compositions of the present invention and the compositions of the present invention, respectively, prophylactically before or during planting or transplantation.
[0431] [0431] The present invention also relates to agrochemical compositions comprising an auxiliary and the components of the respective composition of the present invention or the composition of the present invention, respectively.
[0432] [0432] Agrochemical composition comprises a fungicidal amount of the components of the compositions of the present invention or of the composition of the present invention, respectively. The term "effective amount" means an amount of the composition or components, which is sufficient to control harmful fungi in cultivated vegetables or to protect materials and which do not result in significant damage to the treated vegetables. This amount can vary over a wide range and depends on several factors, such as the species of the fungus to be controlled, the plant or treated material grown, the climatic conditions and the specific compound used.
[0433] [0433] The components of the compositions of the present invention or the compositions of the present invention, respectively, their N-oxides and salts can be converted to the usual types of agrochemical compositions, for example, solutions, emulsions, suspensions, dust, powders, pastes, granules, pressed, capsules, and mixtures thereof. Examples of types of composition are suspensions (for example, SC, OD, FS), emulsifiable concentrates (for example, EC), emulsions (for example, EW, EO, ES, ME), capsules (for example, CS, ZC), pastes, lozenges, dusts or wettable powders (for example, WP, SP, WS, DP, DS), pressed (for example, BR, TB, DT), granules (for example, WG, SG, GR, FG , GG, MG), insecticidal articles (for example, LN), as well as gel formulations for the treatment of plant propagation materials, such as seeds (GF). These and other types of compositions are defined in the “Catalog of pesticide formulation types and international coding system”, Technical Monograph n ° 2, 6th ed. May 2008, CropLife International.
[0434] [0434] The compositions are prepared in a known manner, as described by Mollet and Grubemann, Formulation technology, Wiley VCH, Weinheim, 2001; or Knowles, New developments in crop protection product formulation, Agrow Reports DS243, T&F Informa, London, 2005.
[0435] [0435] Suitable auxiliaries are solvents, liquid vehicles, solid vehicles or excipients, surfactants, dispersants, emulsifiers, wetting agents, adjuvants, solubilizers, penetration promoters, protective colloids, adhesion agents, thickeners, humectants, repellents, attractions, stimulants food, compatibilizers, bactericides, antifreeze agents, antifoaming agents, dyes, adhesives and binders.
[0436] [0436] Suitable solvents and liquid vehicles are water and organic solvents, such as fractions of medium to high boiling mineral oil, for example kerosene or diesel oil; oils of vegetable or animal origin, aliphatic, cyclic and aromatic hydrocarbons, for example, toluene, paraffins, tetrahydronaphthalene, alkylated naphthalenes; alcohols, for example, ethanol, propanol, butanol, benzyl alcohol, cyclohexanol; glycols; DMSO; ketones, for example, cyclohexanone; esters, for example, lactates, carbonates, fatty acid esters, gamma-butyrolactone; fatty acids; phosphonates; amines; amides, for example, N-methylpyrrolidone, fatty acid dimethylamides; and their compositions.
[0437] [0437] Suitable solid vehicles or excipients are earthy minerals, such as silicates, silica gels, talc, kaolin, limestone, lime, chalk, clays, dolomite, diatomaceous earth, bentonite, calcium sulfate and magnesium sulfate, magnesium oxide; polysaccharides, for example, cellulose, starch; fertilizers, such as, for example, ammonium sulfate, ammonium phosphate, ammonium nitrate, ureas; products of plant origin, for example, cereal flour, tree bark flour, wood flour, nutshell flour, and their compositions.
[0438] [0438] Suitable surfactants are surfactant compounds, such as anionic, cationic, non-ionic and amphoteric surfactants, block polymers, polyelectrolytes, and mixtures thereof. These surfactants can be used as an emulsifier, dispersant, solubilizer, wetting agent, penetration promoter, protective colloid, or adjuvant. Examples of surfactants are listed in McCutcheon, Vol.1: Emulsifiers & Detergents, McCutcheon's Directories, Glen Rock, USA, 2008 (International Edition or North American Edition).
[0439] [0439] Suitable anionic surfactants are the alkaline, alkaline earth or ammonium salts of the sulfonates, sulfates, phosphates, carboxylates, and mixtures thereof. Examples of sulphonates are alkylarylsulphonates, diphenylsulphonates, alpha-olefinsulphonates sulphonates, lignin sulphonates, fatty acid sulphonates and oils, ethoxylated alkylphenol sulphonates, alkoxylated arylphenyl sulphonates, and sulphonyl sulphonates sulphonates, hydrochloride and hydrocarbonate naphthalenes and alkylnaphthalenes, sulfosuccinates or sulfosuccinates. Examples of sulfates are fatty acid sulfates and oils, ethoxylated alkylphenols, alcohols, ethoxylated alcohols, or fatty acid esters. Examples of phosphates are phosphate esters. Examples of carboxylates are alkyl carboxylates of carboxylated alcohol or alkylphenol ethoxylates.
[0440] [0440] Suitable non-ionic surfactants are alkoxylated, N-substituted fatty acid amides, amine oxides, sugar-based esters or surfactants, polymeric surfactants and their mixtures. Examples of alkoxylates are compounds, such as alcohols, alkylphenols, amines, amides, arylphenols, fatty acids or fatty acid esters that have been alkoxylated with from 1 to 50 equivalents. Ethylene oxide and / or propylene oxide can be used for alkoxylation, preferably ethylene oxide. Examples of N-substituted fatty acid starches are fatty acid glucamides or fatty acid alkanolamides. Examples of esters are fatty acid esters, glycerol esters or monoglycerides. Examples of sugar-based surfactants are sorbitans, ethoxylated sorbitans, sucrose and glucose esters or alkyl polyglucosides. Examples of polymeric surfactants are vinylpyrrolidone homo- or copolymers, vinylalcohols or vinylacetate.
[0441] [0441] Examples of suitable cationic surfactants are quaternary surfactants, for example, quaternary ammonium compounds with one or two hydrophobic groups, or salts of long chain primary amines. Suitable amphoteric surfactants are alkylbetaines and imidazolines. Suitable block polymers are block polymers of type A-B or A-B-A which comprise blocks of polyethylene oxide and polypropylene oxide or type A-B-C which comprise alkanol, polyethylene oxide and polypropylene oxide. Suitable polyelectrolytes are polyacids or polybases. Examples of polyacids are the alkaline salts of polyacrylic acid. Examples of polybases are polyvinylamines or polyethyleneamines.
[0442] [0442] Suitable adjuvants are compounds, which have negligible pesticidal activity or even no pesticidal activity, and which enhance the biological performance of compound I with the target. Examples are surfactants, mineral or vegetable oils, and other auxiliaries. Other examples are listed by Knowles, Adjuvants and additives, Agrow Reports DS256, T&F Informa United Kingdom, 2006, chapter 5.
[0443] [0443] Suitable thickeners are polysaccharides (eg, xanthan gum, carboxymethylcellulose), inorganic clays (organically modified or not), polycarboxylates, and silicates.
[0444] [0444] Suitable bactericides are bronopol and isothiazolinone derivatives, such as alkylisothiazolinones and benzisothiazolinones.
[0445] [0445] Suitable antifreeze agents are ethylene glycol, propylene glycol, urea and glycerin.
[0446] [0446] Suitable antifoaming agents are silicones, long-chain alcohols and fatty acid salts.
[0447] [0447] Suitable dyes are pigments (eg red, blue or green) with low water solubility and water-soluble dyes. Examples are inorganic dyes (for example, iron oxide, titanium oxide, iron hexacyanoferrate) and organic dyes (for example, alizarin-, azo- and phthalocyanine dyes).
[0448] [0448] Examples of suitable adhesives or binders are polyvinylpyrrolidones, polyvinylacetates, polyvinyl alcohols, polyacrylates, biological or synthetic waxes, and cellulose ethers.
[0449] - De 10 a 60% em peso da substância ativa e de 5 a 15% em peso de agente molhante (por exemplo, os alcóxilatos de álcool) são dissolvidos em água e/ou em um solvente hidrossolúvel (por exemplo, os álcoois) até 100% em peso. A substância ativa se dissolve após a diluição em água. (II) CONCENTRADOS DISPERSÍVEIS (DC) - De 5 a 25% em peso da substância ativa e de 1 a 10% em peso de dispersante (por exemplo, a polivinilpirrolidona) são dissolvidos em até 100% em peso de solvente orgânico (por exemplo, a cicloexanona). A diluição em água fornece uma dispersão. (III) CONCENTRADOS EMULSIONÁVEIS (EC) - De 15 a 70% em peso da substância ativa e de 5 a 10% em peso de emulsionantes (por exemplo, o dodecilbenzenossulfonato de cálcio e etoxilado de óleo de rícino) são dissolvidos em solvente orgânico insolúvel em água (por exemplo, os hidrocarbonetos aromáticos) a 100% em peso. A diluição em água fornece uma emulsão. (IV) EMULSÕES (EW, EO, ES) - De 5 a 40% em peso da substância ativa e de 1 a 10% em peso de emulsionantes (por exemplo, o dodecilbenzenossulfonato de cálcio e etoxilato de óleo de rícino) são dissolvidos em de 20 a 40% em peso de solvente orgânico não hidrossolúvel (por exemplo, os hidrocarbonetos aromáticos). Esta mistura é introduzida em até 100% em peso de água por meio de uma máquina emulsionante e em uma emulsão homogênea. A diluição em água fornece uma emulsão. (V) SUSPENSÕES (SC, OD, FS) - Em um moinho de esferas agitadas, de 20 a 60% em peso da substância ativa são triturados com a adição de 2 a 10% em peso de dispersantes e agentes molhantes (por exemplo, o lignossulfonato de sódio e álcool etoxilado), de 0,1 a 2% em peso de espessante (por exemplo, a goma xantana) e até 100% em peso de água para fornecer uma suspensão fina de substância ativa. A diluição em água fornece uma suspensão estável da substância ativa. Para a composição do tipo FS são adicionados até 40% em peso do ligante (por exemplo, o álcool polivinílico). (VI) GRÂNULOS DISPERSÍVEIS EM ÁGUA E GRÂNULOS HIDROSSOLÚVEIS (WG, SG) - De 50 a 80% em peso da substância ativa são finamente moídos com a adição de até 100% em peso de dispersantes e agentes molhantes (por exemplo, o lignossulfonato de sódio e álcoois etoxilados) e preparados na forma de grânulos dispersíveis em água ou hidrossolúveis, por meio de aparelhos técnicos (por exemplo, a extrusão, torre de pulverização, leito fluidizado). A diluição em água fornece uma dispersão estável ou uma solução da substância ativa. (VII) PÓS DISPERSÍVEIS EM ÁGUA E PÓS HIDROSSOLÚVEIS (WP, SP, WS) - De 50 a 80% em peso da substância ativa são moídos em um moinho de rotor estator com a adição de 1 a 5% em peso de dispersantes (por exemplo, o lignossulfonato de sódio), de 1 a 3% em peso de agentes molhantes (por exemplo, o etoxilato de álcool) e até 100% em peso de veículo sólido, por exemplo, o gel de sílica. A diluição em água fornece uma dispersão estável ou uma solução da substância ativa. (VIII) GEL (GW, GF) - Em um moinho de esferas agitado, de 5 a 25% em peso da substância ativa são triturados com a adição de 3 a 10% em peso de dispersantes (por exemplo, o lignossulfonato de sódio), de 1 a 5% em peso de espessante (por exemplo, carboximetilcelulose) e água até 100% em peso, para fornecer uma suspensão fina da substância ativa. A diluição com água fornece uma suspensão estável da substância ativa. (IV) MICROEMULSÃO (ME) - De 5 a 20% em peso da substância ativa são adicionados a de 5 a 30% em peso da mistura de solvente orgânico (por exemplo, a dimetilamida de ácido graxo e cicloexanona), de 10 a 25% em peso da mistura de tensoativo (por exemplo, o álcool etoxilado e arilfenol etoxilado), e água até 100%. Esta mistura é agitada durante 1 hora para espontaneamente produzir uma microemulsão termodinamicamente estável. (IV) MICROCÁPSULAS (CS) - Uma fase de óleo que compreende de 5 a 50% em peso da substância ativa, de 0 a 40% em peso de solvente orgânico não hidrossolúvel (por exemplo, os hidrocarbonetos aromáticos), de 2 a 15% em peso de monômeros acrílicos (por exemplo, o metilmetacrilato, ácido metacrílico e um di- ou triacrilato) são dispersos em uma solução aquosa de um colóide protetor (por exemplo, o álcool polivinílico). A polimerização radical iniciada através de um iniciador radical resulta na formação de microcápsulas de poli(met)acrilato. De maneira alternativa, uma fase de óleo que compreende de 5 a 50% em peso de um composto I, de acordo com a presente invenção, de 0 a 40% em peso de solvente orgânico não hidrossolúvel (por exemplo, os hidrocarbonetos aromáticos), e um monômero de isocianato (por exemplo, o difenilmeten-4,4'- diisocianatae) são dispersos em uma solução aquosa de um colóide protetor (por exemplo, o álcool polivinílico). A adição de uma poliamina (por exemplo, a hexametilenodiamina) resulta na formação de microcápsulas de poliureia. A quantidade de monômeros é de 1 a 10% em peso. A porcentagem (%) em peso se refere à composição CS total. (IX) PÓS EMPOEIRÁVEIS (DP, DS) - De 1 a 10% em peso da substância ativa são finamente triturados e intimamente misturados com o veículo sólido (por exemplo, o caulim finamente dividido) a 100% em peso. (X) GRÂNULOS (GR, FG) - De 0,5 a 30% em peso da substância ativa são finamente moidos e associados com o veículo sólido (por exemplo, o silicato) a 100% em peso. A granulação é alcançada por extrusão, secagem por pulverização ou leito fluidizado. (XI) LÍQUIDOS DE VOLUME ULTRA BAIXO (UL) - De 1 a 50% em peso da substância ativa são dissolvidos em solvente orgânico (por exemplo, os hidrocarbonetos aromáticos) a 100% em peso. [0449] Examples of general types of composition and their preparation are (where the active substances designate the respective components (= active ingredients) of the composition of the present invention): (I) WATER-SOLUBLE CONCENTRATES (SL, LS) - From 10 to 60% by weight of the active substance and from 5 to 15% by weight of wetting agent (for example, alcohol alkoxylates) are dissolved in water and / or in a water-soluble solvent (for example, alcohols) to 100% by weight. The active substance dissolves after dilution with water. (II) DISPERSIBLE CONCENTRATES (DC) - From 5 to 25% by weight of the active substance and from 1 to 10% by weight of dispersant (for example, polyvinylpyrrolidone) are dissolved in up to 100% by weight of organic solvent (for example, cyclohexanone). Dilution in water provides a dispersion. (III) EMULSIONABLE CONCENTRATES (EC) - From 15 to 70% by weight of the active substance and from 5 to 10% by weight of emulsifiers (eg calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in a water-insoluble organic solvent (for example, hydrocarbons aromatics) to 100% by weight. Dilution in water provides an emulsion. (IV) EMULSIONS (EW, EO, ES) - 5 to 40% by weight of the active substance and 1 to 10% by weight of emulsifiers (eg calcium dodecylbenzenesulfonate and castor oil ethoxylate) are dissolved in 20 to 40% by weight of non-organic solvent water-soluble (eg aromatic hydrocarbons). This mixture is introduced in up to 100% by weight of water by means of an emulsifying machine and in a homogeneous emulsion. Dilution in water provides an emulsion. (V) SUSPENSIONS (SC, OD, FS) - In an agitated ball mill, 20 to 60% by weight of the active substance are crushed with the addition of 2 to 10% by weight of dispersants and wetting agents (eg sodium lignosulfonate and ethoxylated alcohol), from 0 , 1 to 2% by weight of thickener (eg xanthan gum) and up to 100% by weight of water to provide a fine suspension of active substance. Dilution in water provides a stable suspension of the active substance. For the type FS composition, up to 40% by weight of the binder (eg polyvinyl alcohol) is added. (VI) WATER-DISPERSIBLE BEADS AND WATER-SOLUBLE BEADS (WG, SG) - From 50 to 80% by weight of the active substance are finely ground with the addition of up to 100% by weight of dispersants and wetting agents (for example, sodium lignosulfonate and ethoxylated alcohols) and prepared in the form of granules dispersible in water or water-soluble, by means of technical devices (for example, extrusion, spraying tower, fluidized bed). Dilution in water provides a stable dispersion or solution of the active substance. (VII) POWERS DISPERSIBLE IN WATER AND WATER-SOLUBLE POWERS (WP, SP, WS) - From 50 to 80% by weight of the active substance are ground in a rotor stator mill with the addition of 1 to 5% by weight of dispersants (eg sodium lignosulfonate), from 1 to 3% by weight of agents wetting agents (for example, alcohol ethoxylate) and up to 100% by weight of solid vehicle, for example, silica gel. Dilution in water provides a stable dispersion or solution of the active substance. (VIII) GEL (GW, GF) - In a stirred ball mill, 5 to 25% by weight of the active substance are crushed with the addition of 3 to 10% by weight of dispersants (eg sodium lignosulfonate), from 1 to 5% by weight of thickener (eg carboxymethylcellulose) and water up to 100% by weight, to provide a fine suspension of the active substance. Dilution with water provides a stable suspension of the active substance. (IV) MICROEMULSION (ME) - From 5 to 20% by weight of the active substance are added to from 5 to 30% by weight of the organic solvent mixture (for example, fatty acid dimethylamide and cyclohexanone), from 10 to 25% by weight of the surfactant mixture (for example, ethoxylated alcohol and ethoxylated arylphenol), and water up to 100%. This mixture is stirred for 1 hour to spontaneously produce a thermodynamically stable microemulsion. (IV) MICROCapsules (CS) - An oil phase comprising from 5 to 50% by weight of the active substance, from 0 to 40% by weight of non-water-soluble organic solvent (for example, aromatic hydrocarbons), from 2 to 15% by weight of acrylic monomers ( for example, methyl methacrylate, methacrylic acid and a di- or triacrylate) are dispersed in an aqueous solution of a protective colloid (for example, polyvinyl alcohol). The radical polymerization initiated by means of a radical initiator results in the formation of poly (meth) acrylate microcapsules. Alternatively, an oil phase comprising from 5 to 50% by weight of a compound I, according to the present invention, from 0 to 40% by weight of non-water-soluble organic solvent (for example, aromatic hydrocarbons), and an isocyanate monomer (for example, diphenylmethen-4,4'-diisocyanatae) are dispersed in an aqueous solution of a protective colloid (for example, polyvinyl alcohol). The addition of a polyamine (for example, hexamethylenediamine) results in the formation of polyurea microcapsules. The amount of monomers is 1 to 10% by weight. The percentage (%) by weight refers to the total CS composition. (IX) DUSTY POWDER (DP, DS) - From 1 to 10% by weight of the active substance are finely crushed and intimately mixed with the solid vehicle (for example, finely divided kaolin) to 100% by weight. (X) GRANULES (GR, FG) - From 0.5 to 30% by weight of the active substance are finely ground and associated with the solid vehicle (for example, silicate) to 100% by weight. Granulation is achieved by extrusion, spray drying or fluidized bed. (XI) ULTRA LOW VOLUME LIQUIDS (UL) - From 1 to 50% by weight of the active substance are dissolved in 100% by weight in organic solvent (for example, aromatic hydrocarbons).
[0450] [0450] The types of compositions from (i) to (xi) may optionally comprise other auxiliaries, such as from 0.1 to 1% by weight of bactericides, from 5 to 15% by weight of antifreeze agents, from 0, 1 to 1% by weight of defoaming agents, and 0.1 to 1% by weight of colorants.
[0451] [0451] Agrochemical compositions, in general, comprise between 0.01 and 95%, preferably between 0.1 and 90%, and in particular, between 0.5 and 75%, more preferably, by weight of the substances active. The active substances are used in a purity of 90% to 100%, preferably from 95% to 100% (according to the NMR spectrum).
[0452] [0452] Solutions for seed treatment (LS), suspoemulsions (SE), fluid concentrates (FS), treatment of dusty powders (DS), water dispersible powders for the treatment of mud (WS), water-soluble powders (SS), emulsifiable (ES) emulsions (EC) and gels (GF) are usually used for the purposes of treating plant propagation materials, especially seeds. The compositions in question, after being diluted by a factor of two to ten, provide the concentrations of the active substance from 0.01 to 60% by weight, preferably from 0.1 to 40% by weight, in the ready preparations for use. The application can be carried out before or during sowing. Methods for applying Compound I and its compositions, respectively, to plant propagation materials, especially seeds, include methods of application by covering, coating, pelletizing, dusting, dipping and furrowing the propagation material. Preferably, compound I or its compositions, respectively, are applied to the propagating material of the plants using a method in such a way that germination is not induced, for example, through the segment by covering, pelletizing, coating and sprinkling the plants. seeds.
[0453] [0453] When used to protect plants, the amounts of active substances used are, depending on the type of effect desired, from 0.001 to 2 kg per hectare, preferably from 0.005 to 2 kg per hectare, most preferably , from 0.05 to 0.9 kg per hectare, and in particular, from 0.1 to 0.75 kg per ha, from 0.1 to 10 kg of active ingredients per 100 kg of seeds .
[0454] [0454] In the treatment of plant propagating material, such as seeds, for example, by sprinkling, coating or soaking the seeds, the amounts of the active substance from 0.1 to 10 kg of active substance per 100 kg of seed, in particular, from 0.1 to 1,000 g, preferably from 1 to 1,000 g, more preferably from 1 to 100 g and most preferably from 5 to 100 g , per 100 kg of plant propagating material (preferably seeds) are usually required.
[0455] [0455] When used to protect stored materials or products, the amount of active substance applied depends on the type of application area and the desired effect. The amounts normally applied in the protection of the materials are from 0.001 g to 2 kg, preferably from 0.005 g to 1 kg, of the active substance per cubic meter of treated material.
[0456] [0456] Various types of oils, wetting agents, adjuvants, fertilizers, or micronutrients and other pesticides (for example, herbicides, insecticides, fungicides, growth regulators, protective agents) can be added to the active substances, or to the compositions that comprise as a pre-mix or, if appropriate, not even immediately before use (tank mix). These agents can be mixed with the compositions according to the present invention, in a weight ratio of 1: 100 to 100: 1, preferably from 1:10 to 10: 1.
[0457] [0457] The user applies the composition according to the present invention, usually from a pre-dosing device, a backpack sprayer, a spray tank, a spray airplane, or an irrigation system. Usually, the agrochemical composition is made with water, buffer, and / or other auxiliary agents for the desired application concentration and the ready-to-use spray solution or agrochemical composition, according to the present invention, is therefore obtained . Normally, from 20 to 2,000 liters, preferably from 50 to 400 liters, of the ready-to-use spray solution are applied per hectare of the useful agricultural area.
[0458] [0458] According to one embodiment, the individual components of the composition according to the present invention, such as parts of a set or parts of a binary or ternary mixture can be mixed by the user himself, in a spray tank or any other type of container used for applications (for example, the seed treatment battery, seed granulating machines, backpack sprayer) and other auxiliaries can be added, if appropriate.
[0459] [0459] When living microorganisms, such as pesticides in groups (L1), (L3) and (L5), are part of this set, care must be taken that the selection and quantities of components (for example, agents chemical pesticides) and other auxiliaries do not influence the viability of microbial pesticides in the composition mixed by the user. Especially for bactericides and solvents, compatibility with the respective microbial pesticide needs to be taken into account.
[0460] [0460] Consequently, an embodiment of the present invention is a kit for the preparation of a useful pesticidal composition, the kit comprises (a) a composition comprising a component (1) as defined herein and at least one auxiliary; and (b) a composition comprising component (2), as defined herein and at least one auxiliary; and optionally, (c) a composition comprising at least one auxiliary and optionally, another active component (3), as defined herein.
[0461] [0461] In the compositions, the proportions of the components are often advantageously selected to produce a synergistic effect.
[0462] [0462] The term “synergistic effect”, in particular, must refer to the Formula defined by Colby (Colby, S.R., “Calculating synergistic and antagonistic responses of herbicide combinations”, Weeds, 15, pages 20-22, 1967).
[0463] [0463] The term “synergistic effect” must also refer to that defined by the application of the Tammes method, (Tammes, PML, “Isoboles, the graphic representation of synergism in pesticides”, The Netherlands. J. Plant Pathol. 70, 1964) .
[0464] [0464] The components can be used individually or partially or completely mixed together for the preparation of the composition, according to the present invention. It is also possible to be packaged and later used as the combination composition, such as a set of parts.
[0465] [0465] The fungicidal action of the compositions, according to the present invention, can be demonstrated by the tests described below.
[0466] [0466] The active compounds, isolated or combined, are prepared as a stock solution comprising 25 mg of active compound which consists of up to 10 ml using a composition of acetone and / or DMSO and the emulsifier Uniperol® EL (wetting agent which has an emulsifying and dispersing action based on ethoxylated alkylphenols) in a 99: 1 volume / solvent ratio. The composition is then made up to 100 mL with water. This stock solution is diluted with the described emulsifier / solvent / water composition to provide the concentration of active compound indicated below.
[0467] [0467] The visually determined percentages of infected leaf area are converted into efficacies as a percentage (%) of the untreated control.
[0468] - α corresponde à infecção fúngica dos vegetais tratados em porcentagem (%) e - β corresponde à infecção fúngica dos vegetais (de controle) não tratados em porcentagem (%). [0468] The effectiveness (E) using the Abbot Formula is calculated as follows: E = (1 - α / β) 100 - α corresponds to the fungal infection of the treated vegetables in percentage (%) and - β corresponds to the fungal infection of untreated (control) vegetables in percentage (%).
[0469] [0469] An efficacy of 0 means that the level of infection of the treated vegetables corresponds to that of untreated control vegetables, an efficacy of 100 means that the treated vegetables have not been infected.
[0470] - Fórmula de Colby: E = x + y - x ∙ y/100 - E significa a eficácia esperada, expressa em porcentagem (%) do controle não tratado, quando se utiliza a mistura dos compostos ativos (A) e (B) nas concentrações a e b - x significa a eficácia, expressa em porcentagem (%) do controle não tratado, quando se utiliza um ingrediente ativo (A) na concentração a - y significa a eficácia, expressa em porcentagem (%) do controle não tratado, quando se utiliza um ingrediente ativo (B) na concentração. [0470] The expected efficacies of the active substance combinations were determined using the Colby Formula [RS Colby, '' Calculating synergistic and antagonistic responses of herbicide combinations', Weeds 15, 20-22 (1967)] and compared with the observed efficacies . - Colby formula: E = x + y - x ∙ y / 100 - E means the expected efficacy, expressed as a percentage (%) of the untreated control, when using the mixture of active compounds (A) and (B) in concentrations a and b - x means the effectiveness, expressed as a percentage (%) of the untreated control, when an active ingredient (A) is used in the concentration at - y means the effectiveness, expressed as a percentage (%) of the untreated control, when an active ingredient (B) is used in the concentration.
[0471] [0471] The active compounds were formulated separately as a stock solution that has a concentration of 10,000 ppm in dimethyl sulfoxide.
[0472] [0472] The product of orisastrobina was used as finished commercial formulation and diluted with water until the indicated concentration of the active compound.
[0473] [0473] The stock solutions were mixed according to the proportion, pipetted into a microtiter plate (MTP) and diluted with water to the indicated concentrations. Then, a spore suspension of the respective pathogen was added to the respective nutrient medium. The plates were placed in a chamber saturated with water vapor at a temperature of 18º C. Using an absorption photometer, MTPs were measured at 405 nm 7 days after inoculation.
[0474] [0474] The measured parameters were compared with the growth of the active control variant free of compost (100%) and the blank value free of active compound and free of fungus to determine the relative growth in percentage (%) of the pathogens in the respective active compounds. These percentages have been converted into efficiencies.
[0475] [0475] The expected efficacies of mixtures of active compounds were determined using Colby's Formula [R.S. Colby, '' Calculating synergistic and antagonistic responses of herbicide combinations ”, Weeds 15, 20-22 (1967)] and compared with the observed efficacy.
权利要求:
Claims (8)
[0001]
COMPOSITIONS, characterized by comprising, as active ingredients: (1) component I - compound I.3: 2- [4- (4-chlorophenoxy) -2- (trifluoromethyl) phenyl] -1- (1,2,4-triazol-1-yl) propan-2- ol; and (2) component II - a biopesticide selected from Bacillus amyloliquefaciens ssp. plantarum MBI 600 (II-27), Bacillus pumilus INR-7 (II-29) and Bacillus subtilis FB17 (II-176).
[0002]
COMPOSITIONS, according to claim 1, characterized in that compound I and biopesticide II are present in a synergistically effective amount.
[0003]
COMPOSITIONS according to any one of claims 1 to 2, characterized in that component I and component II are present in a total weight ratio from 100: 1 to 1: 100, wherein the total weight of component II is with based on the amount of solid material (dry matter) of component II.
[0004]
COMPOSITIONS according to any one of claims 1 to 3, characterized in that component I and component II are present in a total weight ratio from 100: 1 to 1: 100, wherein the total weight of component II is calculated based on the amount of CFU of component II, where 1 x 109 CFU equals one gram in total weight of component II.
[0005]
COMPOSITIONS according to any one of claims 1 to 4, characterized in that they also comprise an agrochemical aid.
[0006]
USE OF A COMPOSITION, as defined in any one of claims 1 to 5, characterized by combating phytopathogenic fungi.
[0007]
METHOD FOR COMBATING PHYTOPATHOGENIC FUNGI, characterized by the treatment of fungi or materials, vegetables, soil or seeds to be protected from fungal attack with an effective amount of a composition, as defined in any one of the claims 1 to 5.
[0008]
USE OF COMPONENTS I and II of the compositions as defined in any one of claims 1 to 5, characterized in that they are used to coat a vegetable propagating material with an amount of 0.1 to 10 kg of active substance per 100 kg of seed.
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同族专利:
公开号 | 公开日
RU2669997C2|2018-10-17|
CA2916777A1|2015-01-15|
CN106028817A|2016-10-12|
US10512267B2|2019-12-24|
US20160150786A1|2016-06-02|
UA118265C2|2018-12-26|
PL3019013T3|2021-10-25|
EP3019013A1|2016-05-18|
BR112016000299A8|2019-12-31|
BR112016000299B8|2021-04-20|
EP3019013B1|2020-12-23|
RU2016103791A|2017-08-11|
WO2015003908A1|2015-01-15|
ES2860941T3|2021-10-05|
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法律状态:
2018-02-27| B06F| Objections, documents and/or translations needed after an examination request according [chapter 6.6 patent gazette]|
2019-05-21| B06T| Formal requirements before examination [chapter 6.20 patent gazette]|
2020-08-11| B07A| Application suspended after technical examination (opinion) [chapter 7.1 patent gazette]|
2021-01-05| B09A| Decision: intention to grant [chapter 9.1 patent gazette]|
2021-02-17| B16A| Patent or certificate of addition of invention granted [chapter 16.1 patent gazette]|Free format text: PRAZO DE VALIDADE: 20 (VINTE) ANOS CONTADOS A PARTIR DE 25/06/2014, OBSERVADAS AS CONDICOES LEGAIS. |
2021-04-20| B16C| Correction of notification of the grant [chapter 16.3 patent gazette]|Free format text: REF. RPI 2615 DE 17/02/2021 QUANTO AO ENDERECO. |
优先权:
申请号 | 申请日 | 专利标题
EP13175463|2013-07-08|
EP13175463.2|2013-07-08|
PCT/EP2014/063412|WO2015003908A1|2013-07-08|2014-06-25|Compositions comprising a triazole compound and a biopesticide|
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